Iodine and its important role in functional materials, reagents, and compounds Iodine is essential for life and has a variety of forms that are useful for an even wider array of applications. This book acts a useful guide about iodine, its chemistry, fundamentals and advances. Using illustrative examples and detailed discussion, the examples in this book help readers gain a better understanding of the reactions, requirements, and industry potential of iodine. Chapters are divided into seven parts covering characteristics, production, synthesis, biological applications, industrial applications,…mehr
Iodine and its important role in functional materials, reagents, and compounds Iodine is essential for life and has a variety of forms that are useful for an even wider array of applications. This book acts a useful guide about iodine, its chemistry, fundamentals and advances. Using illustrative examples and detailed discussion, the examples in this book help readers gain a better understanding of the reactions, requirements, and industry potential of iodine. Chapters are divided into seven parts covering characteristics, production, synthesis, biological applications, industrial applications, bioorganic chemistry and environmental chemistry aspects, and radioisotopes. The areas covered include: * An up-to-date overview of iodine chemistry with discussion on elemental aspects: characteristics, structures, properties and halogen bonding * Traditional and modern techniques, such as such as starch, copper, blowing out, and ion exchange resin methods * Comprehensive tips for readers learning how to synthesize complex compounds using iodine reagents or intermediates * Popular applications and novel uses of iodine in pharmaceuticals, agrochemicals, films, solar cells, hypervalent iodine-mediated cross coupling reactions, and therapeutic agents The concepts in this book apply to organic chemistry as well as related fields in organometallics, materials, medicinal chemistry, and natural products. With broad coverage on both the chemistry and application of iodine, fundamentals, and advances in the field, this book is a useful tool for chemists and professionals.
Tatsuo Kaiho is the Director of Nihon Tennen Gas Co., Ltd. (Chiba, Japan), one of the most well-known iodine manufacturing companies in the world. The Director of the Society of Iodine Science, Dr. Kaiho developed novel iodine-containing materials and processes and presented independent research at many conferences, including the International Conference of Hypervalent Iodine Chemistry (2010) and the Symposium of Iodine Science (2011). Dr. Kaiho has received several awards, such as the Distinguished Chemist Award from Chiba Prefectural Government (2001) and the Society of Iodine Science Award (2012).
Inhaltsangabe
LIST OF CONTRIBUTORS ix
Preface xiii
1 Overview 1 Tatsuo Kaiho
Part I Characteristics, elemental of iodine 7
2 Physical Properties of Iodine 9 Tatsuo Kaiho
3 A nalytical Methods for Iodine and Iodides 15 Hirofumi Kanoh and Takehisa Konishi
4 Ion Chromatography 25 Anna Blazewicz
5 Inorganic Iodides 55 Tatsuo Kaiho
6 Organic Iodides 75 Tsugio Kitamura
7 H ypervalent Iodine 103 Toshifumi Dohi and Yasuyuki Kita
8 Iodine and Halogen Bonding 159 Giancarlo Terraneo, Giuseppe Resnati, and PierangeloMetrangolo
Part II Pro duction of iodine 195
9 H istory of Iodine 197 James L. Marshall and Virginia R. Marshall
10 Production Process in the Past 207 Tatsuo Kaiho
11 Iodine Production from Caliche 213 Armin Lauterbach
12 Iodine Production from Oilfield Brine 221 Stanley T. Krukowski
13 Iodine Production from Natural Gas Brine 231 Nobuyuki Kaneko and Tatsuo Kaiho
14 Recycling of Iodine 243 Tatsuo Kaiho
Part III Synthesis of iodine compounds 249
15 Iodinating Reagents 251 Haruhiko Taguchi
16 Oxidizing Agents 277 Toshifumi Dohi and Yasuyuki Kita
17 Reaction of Iodo Compounds 303 Toshifumi Dohi and Yasuyuki Kita
18 Metal Iodides-Mediated Reaction 329 Makoto Shimizu, Iwao Hachiya and Junji Inanaga
Part IV Biological Application of iodine 353
19 Iodinated X-Ray Contrast Agents 355 Werner Krause
20 Iodine as Disinfectant 375 Waldemar Gottardi
21 Synthetic Thyroid Hormone 411 Steven E. Rokita
22 Iodine Deficiency Disorders and Their Correction UsingIodized Salt and/or Iodine Supplements 421 Michael B. Zimmermann