H. Fogler

Elements of Chemical Reaction Engineering, Global Edition

• Broschiertes Buch

Produktbeschreibung

Fordecades, H. Scott FoglerGÇÖs Elements of Chemical Reaction Engineering hasbeen the worldGÇÖs dominant chemical reaction engineering text. Usingsliders and interactive examples in Wolfram, Python, POLYMATH, and MATLAB,students can explore reactions and reactors by running realistic simulationexperiments. Writing for todayGÇÖs students, Fogler provides instant access to information,avoids extraneous details, and presents novel problems linking theory topractice. Faculty can flexibly define their courses, drawing on updatedchapters, problems, and extensive Professional Reference Shelf web content atdiverse levels of difficulty. The book thoroughly prepares undergraduates to apply chemical reaction kineticsand physics to the design of chemical reactors. And four advanced chaptersaddress graduate-level topics, including effectiveness factors. To support thefieldGÇÖs growing emphasis on chemical reactor safety, each chapter now ends witha practical safety lesson. * Updates throughout the book reflect current theory and practice and emphasize safety * New discussions of molecular simulations and stochastic modeling * Increased emphasis on alternative energy sources such as solar and biofuels * Thorough reworking of three chapters on heat effects * Full chapters on nonideal reactors, diffusion limitations, and residence time distribution Courses Appropriate for undergraduate courses on chemical reactionengineering, though four advanced chapters do address graduate-level topics.

Produktdetails

• Verlag: Pearson / Pearson Education Limited
• 6. Auflage
• Seitenzahl: 1080
• Erscheinungstermin: 28. Januar 2022
• Englisch
• Abmessung: 252mm x 203mm x 39mm
• Gewicht: 1962g
• ISBN-13: 9781292416663
• ISBN-10: 1292416661
• Artikelnr.: 63266136

Autorenporträt

H. Scott Fogler is the Ame and Catherine Vennema Professor of Chemical Engineering and the Arthur F. Thurnau Professor at the University of Michigan. He has been research advisor to forty-five Ph.D. students, and has more than two hundred thirty-five refereed publications. He was 2009 President of the American Institute of Chemical Engineers. Fogler has chaired ASEE's Chemical Engineering Division, served as director of the American Institute of Chemical Engineers, and earned the Warren K. Lewis Award from AIChE for contributions to chemical engineering education. He has received the Chemical Manufacturers Association's National Catalyst Award and the 2010 Malcom E. Pruitt Award from the Council for Chemical Research.

Inhaltsangabe

1. Mole Balances 1
o The Rate of Reaction, r_A
o The General Mole Balance Equation (GMBE)
o Batch Reactors (BRs)
o Continuous-Flow Reactors
o Industrial Reactors
o And Now . . . A Word from Our SponsorSafety 1 (AWFOS - S1
Safety)
2. Conversion and Reactor Sizing
o Definition of Conversion
o Batch Reactor Design Equations
o Design Equations for Flow Reactors
o Sizing Continuous-Flow Reactors
o Reactors in Series
o Some Further Definitions
o And Now . . . A Word from Our SponsorSafety 2
3. Rate Laws 75
o Basic Definitions
o The Rate Law
o The Reaction-Rate Constant
o Molecular Simulations
o Present Status of Our Approach to Reactor Sizing and Design
o And Now . . . A Word from Our SponsorSafety 3 (AWFOS - S3 The
GHS Diamond)
4. Stoichiometry
o Batch Reactors (BRs)
o Flow Systems
o Reversible Reactions and Equilibrium Conversion
o And Now . . . A Word from Our SponsorSafety 4 (AWFOS - S4 The
Swiss Cheese Model
5. Isothermal Reactor Design: Conversion
o Design Structure for Isothermal Reactors
o Batch Reactors (BRs)
o Continuous-Stirred Tank Reactors (CSTRs)
o Tubular Reactors
o Pressure Drop in Reactors
o Synthesizing the Design of a Chemical Plant
o And Now . . . A Word from Our SponsorSafety 5 (AWFOS - S5 A
Safety Analysis of the Incident Algorithm)
6. Isothermal Reactor Design: Moles and Molar Flow Rates
o The Moles and Molar Flow Rate Balance Algorithms
o Mole Balances on CSTRs, PFRs, PBRs, and Batch Reactors
o Application of the PFR Molar Flow Rate Algorithm to a
Microreactor
o Membrane Reactors
o Unsteady-State Operation of Stirred Reactors
o Semibatch Reactors
o And Now . . . A Word from Our SponsorSafety 6 (AWFOS - S6 The
BowTie Diagram)
7. Collection and Analysis of Rate Data
o The Algorithm for Data Analysis
o Determining the Reaction Order for Each of Two Reactants Using
the Method of Excess
o Integral Method
o Differential Method of Analysis
o Nonlinear Regression
o Reaction-Rate Data from Differential Reactors
o Experimental Planning
o And Now . . . A Word from Our SponsorSafety 7 (AWFOS - S7
Laboratory Safety)
8. Multiple Reactions
o Definitions
o Algorithm for Multiple Reactions
o Parallel Reactions
o Reactions in Series
o Complex Reactions
o Membrane Reactors to Improve Selectivity in Multiple Reactions
o Sorting It All Out
o The Fun Part
o And Now . . . A Word from Our SponsorSafety 8 (AWFOS - S8 The
Fire Triangle)
9. Reaction Mechanisms, Pathways, Bioreactions, and Bioreactors
o Active Intermediates and Nonelementary Rate Laws
o Enzymatic Reaction Fundamentals
o Inhibition of Enzyme Reactions
o Bioreactors and Biosynthesis
o And Now . . . A Word from Our SponsorSafety 9 (AWFOS - S9
Process Safety Triangle)
10. Catalysis and Catalytic Reactors
o Catalysts
o Steps in a Catalytic Reaction
o Synthesizing a Rate Law, Mechanism, and Rate-Limiting Step
o Heterogeneous Data Analysis for Reactor Design
o Reaction Engineering in Microelectronic Fabrication
o Model Discrimination
o Catalyst Deactivation
o Reactors That Can Be Used to Help Offset Catalyst Decay
o And Now . . . A Word from Our SponsorSafety 10 (AWFOS - S10
Exxon Mobil Torrance Refinery Explosion Involving a
Straight-Through Transport Reactor [STTR])
11. Nonisothermal Reactor Design: The Steady-State Energy Balance and
Adiabatic PFR Applications
o Rationale
o The Energy Balance
o The User-Friendly Energy Balance Equations
o Adiabatic Operation
o Adiabatic Equilibrium Conversion
o Reactor Staging with Interstage Cooling or Heating
o Optimum Feed Temperature
o And Now . . . A Word from Our SponsorSafety 11 (AWFOS - S11
Acronyms)
12. Steady-State Nonisothermal Reactor Design: Flow Reactors with Heat
Exchange
o Steady-State Tubular Reactor with Heat Exchange
o Balance on the Heat-Transfer Fluid
o Examples of the Algorithm for PFR/PBR Design with Heat Effects
o CSTR with Heat Effects
o Multiple Steady States (MSS)
o Nonisothermal Multiple Chemical Reactions
o Radial and Axial Temperature Variations in a Tubular Reactor
o And Now . . . A Word from Our SponsorSafety 12 (AWFOS - S12
Safety Statistics)
13. Unsteady-State Nonisothermal Reactor Design
o The Unsteady-State Energy Balance
o Energy Balance on Batch Reactors (BRs)
o Batch and Semibatch Reactors with a Heat Exchanger
o Nonisothermal Multiple Reactions
o And Now . . . A Word from Our SponsorSafety 13 (AWFOS - S13
Safety Analysis of the T2 Laboratories Incident)
14. Mass Transfer Limitations in Reacting Systems
o Diffusion Fundamentals
o Binary Diffusion
o Modeling Diffusion with Chemical Reaction
o The Mass Transfer Coefficient
o Mass Transfer to a Single Particle
o The Shrinking Core Model
o Mass Transfer-Limited Reactions in Packed Beds
o Robert the Worrier
o What If . . . ? (Parameter Sensitivity)
o And Now . . . A Word from Our SponsorSafety 14 (AWFOS - S14
Sugar Dust Explosion)
15. Diffusion and Reaction
o Diffusion and Reactions in Homogeneous Systems
o Diffusion and Reactions in Spherical Catalyst Pellets
o The Internal Effectiveness Factor
o Falsified Kinetics
o Overall Effectiveness Factor
o Estimation of Diffusion- and Reaction-Limited Regimes
o Mass Transfer and Reaction in a Packed Bed
o Determination of Limiting Situations from Reaction-Rate Data
o Multiphase Reactors in the Professional Reference Shelf
o Fluidized Bed Reactors
o Chemical Vapor Deposition (CVD)
o And Now . . . A Word from Our SponsorSafety 15 (AWFOS - S15
Critical Thinking Questions Applied to Safety)
16. Residence Time Distributions of Chemical Reactors
o General Considerations
o Measurement of the RTD
o Characteristics of the RTD
o RTD in Ideal Reactors
o PFR/CSTR Series RTD
o Diagnostics and TroubleshootingAnd Now . . . A Word from Our
SponsorSafety 16 (AWFOS - S16 Critical Thinking Actions)
17. Predicting Conversion Directly from the Residence Time Distribution
o Modeling Nonideal Reactors Using the RTD
o Zero Adjustable Parameter Models
o Using Software Packages Such as Polymath to Find Maximum
Mixedness Conversion
o Tanks-in-Series One Parameter Model, n
o RTD and Multiple Reactions
o And Now . . . A Word from Our SponsorSafety 17 (AWFOS - S17
Brief Case History on an Air Preheater)
18. Models for Nonideal Reactors
o Some Guidelines for Developing Models
o Flow and Axial Dispersion of Inert Tracers in Isothermal
Reactors
o Flow, Reaction, and Axial Dispersion
o Flow, Reaction, and Axial Dispersion in Isothermal Laminar-Flow
Reactors and Finding Meno
o Tanks-in-Series Model versus Dispersion Model
o Numerical Solutions to Flows with Dispersion and Reaction
o Nonisothermal Flow with Radial and Axial Variations in a
Tubular Reactor
o Two-Parameter ModelsModeling Real Reactors with Combinations of
Ideal Reactors
o And Now . . . A Word from Our SponsorSafety 18 (AWFOS - S18 An
Algorithm for Management of Change (MoC))
Appendix A: Numerical Techniques
* A.1 Useful Integrals in Chemical Reactor Design
* A.2 Equal-Area Graphical Differentiation
* A.3 Solutions to Differential Equations
* A.4 Numerical Evaluation of Integrals
* A.5 Semi-Log Graphs
* A.6 Software Packages
Appendix B: Ideal Gas Constant and Conversion Factors
Appendix C: Thermodynamic Relationships Involving the Equilibrium Constant
Appendix D: Software Packages
* D.1 Polymath
* D.2 Wolfram
* D.3 Python
* D.4 MATLAB
* D.5 Excel
* D.6 COMSOL (http://www.umich.edu/~elements/6e/12chap/comsol.html)
* D.7 Aspen
* D.8 Visual Encyclopedia of Equipment: Reactors Section
* D.9 Reactor Lab
Appendix E: Rate-Law Data
Appendix F: Nomenclature
Appendix G: Open-Ended Problems
* G.1 Chem-E-Car
* G.2 Effective Lubricant Design
* G.3 Peach Bottom Nuclear Reactor
* G.4 Underground Wet Oxidation
* G.5 Hydrodesulfurization Reactor Design
* G.6 Continuous Bioprocessing
* G.7 Methanol Synthesis
* G.8 Cajun Seafood Gumbo
* G.9 Alcohol Metabolism
* G.10 Methanol Poisoning
* G.11 Safety
Appendix H: Use of Computational Chemistry Software Packages
* H.1 Computational Chemical Reaction Engineering
Appendix I: How to Use the CRE Web Resources
* I.1 CRE Web Resources Components
* Index