Paulo Costa, Ronaldo Pilli, Sergio Pinheiro, Peter Bakuzis

The Chemistry of Carbonyl Compounds and Derivatives (eBook, ePUB)

• Format: ePub

Produktbeschreibung

Originally published in Portuguese, this book is divided into three sections: the chemistry of aldehydes, ketones, nitriles, imines and derivatives; the chemistry of carboxylic and carbonic acids and derivatives; and the chemistry of alpha, beta-unsaturated carbonyls. The authors have merged aspects of valence bond and molecular orbital theories in order to discuss structural and physico-chemical properties and reactivity and stereochemical outcomes of the most relevant reactions for these functional groups.

The book provides representative experimental procedures for key reactions; highlights to contextualize the concepts; properties (industrial applications, biochemical significance and catalytic developments in order to cope with the major tenets of the green chemistry approach) and includes some biographical notes for the scientists who contributed to this field. It will help advanced level undergraduate and graduate students to understand and become well acquainted with the reactions of carbonyl compounds and derivatives. The integrated approach is considered an attractive feature of this book since students receive relatively little exposure to molecular orbital theory at the undergraduate level. The juxtaposition of conventional valence bond theory with molecular orbital theory fills a largely unmet pedagogical niche.

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Produktdetails

• Verlag: RSC
• Seitenzahl: 814
• Erscheinungstermin: 15. Juni 2022
• Englisch
• ISBN-13: 9781788019323
• Artikelnr.: 64189621

Inhaltsangabe

Introduction; Structure
Sources
Uses and Properties of Aldehydes
Ketones
Imines and Nitriles; Chemical Reactivity of Aldehydes
Ketones
Imines and Nitriles; Addition Reactions to the Carbonyl Group of Aldehydes
Ketones
Imines and Nitriles; Substitution Reaction at C-a of the Carbonyl Group of Aldehydes
Ketones
Imines and Nitriles; Structure
Sources
Uses and Properties of Carboxylic and Carbonic Acids and Their Derivatives; Chemical Reactivity of Carboxylic and Carbonic Acids and Their Derivatives; Addition-Elimination Reactions in Carboxylic and Carbonic Acids and Their Derivatives; Substitution Reactions at C-a of Carboxylic and Carbonic Acids and Their Derivatives; Structure
Sources
Uses and Properties of a
ß-Unsaturated Carbonyl Compounds; Chemical Reactivity of a
ß-Unsaturated Carbonyl Compounds; Reactions of a
ß-Unsaturated Carbonyl Compounds; Diels-Alder Reactions; Reduction and Oxidation Reactions of Carbonyl Compounds