Rubber Nanocomposites (eBook, PDF)
Preparation, Properties, and Applications
Redaktion: Thomas, Sabu; Stephen, Ranimol
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Rubber Nanocomposites (eBook, PDF)
Preparation, Properties, and Applications
Redaktion: Thomas, Sabu; Stephen, Ranimol
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Rubber Nanocomposites: Preparation, Properties and Applications focuses on the preparation, characterization and properties of natural and synthetic rubber nanocomposites. The book carefully debates the preparation of unmodified and modified nanofillers, various manufacturing techniques of rubber nanocomposites, structure, morphology and properties of nanocomposites. The text reviews the processing; characterization and properties of 0-, 1D and 2D nanofiller reinforced rubber nanocomposites. It examines the polymer/filler interaction, i.e., the compatibility between matrix and filler using…mehr
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- Produktdetails
- Verlag: John Wiley & Sons
- Seitenzahl: 728
- Erscheinungstermin: 9. April 2010
- Englisch
- ISBN-13: 9780470823460
- Artikelnr.: 37299440
- Verlag: John Wiley & Sons
- Seitenzahl: 728
- Erscheinungstermin: 9. April 2010
- Englisch
- ISBN-13: 9780470823460
- Artikelnr.: 37299440
of the Art, New Challenges and Opportunities (Ranimol Stephen and Sabu
Thomas). 1.1 Introduction. 1.2 Various Nanofillers. 1.3 Rubber
Nanocomposites. 1.4 Future Outlook, Challenges and Opportunities.
References. 2 Manufacturing Techniques of Rubber Nanocomposites (Jun Ma,
Li-Qun Zhang and Li Geng). 2.1 Introduction. 2.2 Melt Compounding. 2.3
Solution Blending. 2.4 Latex Compounding. 2.5 Summary. Acknowledgments.
References. 3 Reinforcement of Silicone Rubbers by Sol-Gel In Situ
Generated Filler Particles (Liliane Bokobza and Amadou Lamine Diop). 3.1
Introduction. 3.2 Synthetic Aspects. 3.3 Properties of the Hybrid
Materials. 3.4 Conclusions. References. 4 Interface Modification and
Characterization (Jun Ma, Li-Qun Zhang and Jiabin Dai). 4.1 Introduction.
4.2 Rubber Nanocomposites Without Interface Modification. 4.3 Interface
Modification by Nonreactive Routes. 4.4 Interface Modification by Reactive
Routes. 4.5 Characterization of Interface Modification. 4.6 Conclusion.
List of Abbreviations. Acknowledgments. References. 5 Natural Rubber Green
Nanocomposites (Alain Dufresne) 5.1 Introduction. 5.2 Preparation of
Polysaccharide Nanocrystals. 5.3 Processing of Polysaccharide
Nanocrystal-Reinforced Rubber Nanocomposites. 5.4 Morphological
Investigation. 5.5 Swelling Behavior. 5.6 Dynamic Mechanical Analysis. 5.7
Tensile Tests. 5.8 Successive Tensile Tests. 5.9 Barrier Properties. 5.10
Conclusions. References. 6 Carbon Nanotube Reinforced Rubber Composites (R.
Verdejo, M.A. Lopez-Manchado, L. Valentini and J.M. Kenny). 6.1
Introduction. 6.2 Functionalized Carbon Nanotubes. 6.3 Elastomeric
Nanocomposites. 6.4 Outlook. References. 7 Rubber/Clay Nanocomposites:
Preparation, Properties and Applications (K.G. Gatos and J. Karger-Kocsis).
7.1 Introduction. 7.2 Clays and Their Organophilic Modification. 7.3
Preparation of Rubber/Clay Nanocomposites. 7.4 Properties of Rubber/Clay
Nanocomposites. 7.5 Applications. 7.6 Outlook. Acknowledgments. References.
8 Cellulosic Fibril-Rubber Nanocomposites (Maya Jacob John and Sabu
Thomas). 8.1 Introduction. 8.2 Cellulose. 8.3 Cellulosic
Nanoreinforcements. 8.4 Studies on Cellulosic/Latex Nanocomposites. 8.5
Conclusions. References. 9 Nanofillers In Rubber-Rubber Blends (Rosamma
Alex). 9.1 Introduction. 9.2 Types of Nanofillers. 9.3 Role of Nanofillers
in Reinforcement. 9.4 Methods to Enhance Polymer-Filler Interaction and
Reinforcement. 9.5 Role of Nanofiller as Compatibilizer. 9.6 Structure
Compatibility Concept of NR-Based Latex Blends. 9.7 Solubility Parameter
and Mixing of Latices. 9.8 Preparation of Nanocomposites. 9.9 Rubber Blend
Nanocomposites Based on Skim NR Latex and Fresh NR Latex: Preparation,
Characterization and Mechanical Properties. 9.10 Advantages of
Nanocomposites and Application of Rubber Nanocomposites. References. 10
Thermoplastic Polyurethane Nanocomposites (S.K. Smart, G.A. Edwards and
D.J. Martin). 10.1 Introduction. 10.2 Market. 10.3 TPU Chemistry,
Morphology and Properties. 10.4 TPU Nanocomposites. 10.5 Layered
Silicate/TPU Nanocomposites. 10.6 Carbon Nanotube/TPU Nanocomposites. 10.7
Future Perspectives. References. 11 Microscope Evaluation of the Morphology
of Rubber Nanocomposites (Hiroaki Miyagawa). 11.1 Introduction. 11.2
Optical Microscopy. 11.3 Scanning Electron Microscopy. 11.4 Transmission
Electron Microscopy. 11.5 Scanning Probe Microscopy. 11.6 Summary.
References. 12 Mechanical Properties of Rubber Nanocomposites: How, Why . .
. and Then? (L. Chazeau, C. Gauthier and J.M. Chenal). 12.1 Introduction.
12.2 Typical Mechanical Behavior of Rubber Nanocomposites. 12.3 How to
Explain Reinforcement in Rubber Nanocomposite? 12.4 Modeling Attempts. 12.5
General Conclusions. References. 13 Nonlinear Viscoelastic Behavior of
Rubbery Bionanocomposites (Alireza S. Sarvestani and Esmaiel Jabbari). 13.1
Introduction. 13.2 Rubbery Bionanocomposites. 13.3 Nonlinear
Viscoelasticity of Hydrogel Nanocomposites. 13.4 Conclusions.
Acknowledgments. References. 14 Rheological Behavior of Rubber
Nanocomposites (Philippe Cassagnau and Claire Barres). 14.1 Introduction.
14.2 Linear Viscoelasticity. 14.3 Payne Effect. 14.4 Flow Properties of
Rubber Nanocomposites. 14.5 Conclusions. References. 15 Electron Spin
Resonance in Studying Nanocomposite Rubber Materials (S. Valic). 15.1 An
Approach to the Study of Polymer Systems. 15.2 ESR - Spin Probe Study of
Nanocomposite Rubber Materials. 15.3 Summary. References. 16 Studies on
Solid-State NMR and Surface Energetics of Silicas for Improving
Filler-Elastomer Interactions in Nanocomposites (Soo-Jin Park and Byung-Joo
Kim). 16.1 Introduction. 16.2 Surface Modification of Silicas. 16.3
Solid-State NMR Analyses of Silicas. 16.4 Surface Energetics of Silicas.
16.5 Other Surface Analyses of Modified Silicas. 16.6 Mechanical
Interfacial Properties of the Compounds. 16.7 Conclusions. References. 17
Wide-Angle X-ray Diffraction and Small-Angle X-ray Scattering Studies of
Rubber Nanocomposites (Valerio Causin). 17.1 Introduction. 17.2 WAXD: An
Overview. 17.3 SAXS: An Overview. 17.4 Lamellar Fillers. 17.5 Nonlamellar
Fillers. 17.6 Characterization of the Matrix in Polymer-Based
Nanocomposites. References. 18 Barrier Properties of Rubber Nanocomposites
(Changwoon Nah and M. Abdul Kader). 18.1 Introduction. 18.2 Theoretical
Consideration. 18.3 Experimental Studies. 18.4 Applications. 18.5
Conclusions. Acknowledgments. References. 19 Rubber/Graphite Nanocomposites
(Guohua Chen and Weifeng Zhao). 19.1 Introduction and Background. 19.2
Graphite and its Nanostructure. 19.3 Rubber/Graphite Nanocomposites. 19.4
Future Outlook. Acknowledgments. References. 20 Aging and Degradation
Behavior of Rubber Nanocomposites (Suneel Kumar Srivastava and Himadri
Acharya). 20.1 Introduction. 20.2 Types of Fillers Used in Rubber
Nanocomposites. 20.3 Aging of Rubber Nanocomposites. 20.4 Degradation of
Rubber Nanocomposites. 20.5 Summary. References. 21 Positron Annihilation
Lifetime Spectroscopy (PALS) and Nanoindentation (NI) (Dariusz M. Bielinski
and Ludomir Slusarski). 21.1 Introduction. 21.2 Positron Annihilation
Lifetime Spectroscopy. 21.3 Nanoindentation 621 22 Thermoelasticity and
Stress Relaxation Behavior of Synthetic Rubber/ Organoclay Nanocomposites
(K.M. Sukhyy, E.G. Privalko, V.P. Privalko and M.V. Burmistr). 22.1
Introduction. 22.2 Experimental. 22.3 Polychloroprene/Organoclay
Nanocomposites. 22.4 Styrene-co-Butadiene Rubber/Organoclay Nanocomposites.
23 Theoretical Modeling and Simulation of Rubber Nanocomposites (Jan Kalfus
and Josef Jancar). 23.1 Introduction. 23.2 Brief Theory of Conformation
Statistics and Chain Dynamics. 23.3 Basic Aspects of Rubber Elasticity.
23.4 Mechanisms of Nanocomposite Reinforcement. 23.5 Chains at
Rubber-Filler Interfaces. 23.6 Structural Peculiarities of Rubbery
Nanocomposites. 23.7 Concluding Remarks. Acknowledgments. References. 24
Application of Rubber Nanocomposites (Miroslawa El Fray and Lloyd A.
Goettler). 24.1 Introduction. 24.2 Rubber Nanocomposites in Tire
Engineering Applications. 24.3 Rubber Nanocomposite Membranes. 24.4
Applications of Rubber Nanocomposites in Sporting Goods. 24.5 Advanced
Nanocomposites for Airspace Applications. 24.6 Nanorubbers in Medicine and
Healthcare. 24.7 Conclusions. References. Index.
of the Art, New Challenges and Opportunities (Ranimol Stephen and Sabu
Thomas). 1.1 Introduction. 1.2 Various Nanofillers. 1.3 Rubber
Nanocomposites. 1.4 Future Outlook, Challenges and Opportunities.
References. 2 Manufacturing Techniques of Rubber Nanocomposites (Jun Ma,
Li-Qun Zhang and Li Geng). 2.1 Introduction. 2.2 Melt Compounding. 2.3
Solution Blending. 2.4 Latex Compounding. 2.5 Summary. Acknowledgments.
References. 3 Reinforcement of Silicone Rubbers by Sol-Gel In Situ
Generated Filler Particles (Liliane Bokobza and Amadou Lamine Diop). 3.1
Introduction. 3.2 Synthetic Aspects. 3.3 Properties of the Hybrid
Materials. 3.4 Conclusions. References. 4 Interface Modification and
Characterization (Jun Ma, Li-Qun Zhang and Jiabin Dai). 4.1 Introduction.
4.2 Rubber Nanocomposites Without Interface Modification. 4.3 Interface
Modification by Nonreactive Routes. 4.4 Interface Modification by Reactive
Routes. 4.5 Characterization of Interface Modification. 4.6 Conclusion.
List of Abbreviations. Acknowledgments. References. 5 Natural Rubber Green
Nanocomposites (Alain Dufresne) 5.1 Introduction. 5.2 Preparation of
Polysaccharide Nanocrystals. 5.3 Processing of Polysaccharide
Nanocrystal-Reinforced Rubber Nanocomposites. 5.4 Morphological
Investigation. 5.5 Swelling Behavior. 5.6 Dynamic Mechanical Analysis. 5.7
Tensile Tests. 5.8 Successive Tensile Tests. 5.9 Barrier Properties. 5.10
Conclusions. References. 6 Carbon Nanotube Reinforced Rubber Composites (R.
Verdejo, M.A. Lopez-Manchado, L. Valentini and J.M. Kenny). 6.1
Introduction. 6.2 Functionalized Carbon Nanotubes. 6.3 Elastomeric
Nanocomposites. 6.4 Outlook. References. 7 Rubber/Clay Nanocomposites:
Preparation, Properties and Applications (K.G. Gatos and J. Karger-Kocsis).
7.1 Introduction. 7.2 Clays and Their Organophilic Modification. 7.3
Preparation of Rubber/Clay Nanocomposites. 7.4 Properties of Rubber/Clay
Nanocomposites. 7.5 Applications. 7.6 Outlook. Acknowledgments. References.
8 Cellulosic Fibril-Rubber Nanocomposites (Maya Jacob John and Sabu
Thomas). 8.1 Introduction. 8.2 Cellulose. 8.3 Cellulosic
Nanoreinforcements. 8.4 Studies on Cellulosic/Latex Nanocomposites. 8.5
Conclusions. References. 9 Nanofillers In Rubber-Rubber Blends (Rosamma
Alex). 9.1 Introduction. 9.2 Types of Nanofillers. 9.3 Role of Nanofillers
in Reinforcement. 9.4 Methods to Enhance Polymer-Filler Interaction and
Reinforcement. 9.5 Role of Nanofiller as Compatibilizer. 9.6 Structure
Compatibility Concept of NR-Based Latex Blends. 9.7 Solubility Parameter
and Mixing of Latices. 9.8 Preparation of Nanocomposites. 9.9 Rubber Blend
Nanocomposites Based on Skim NR Latex and Fresh NR Latex: Preparation,
Characterization and Mechanical Properties. 9.10 Advantages of
Nanocomposites and Application of Rubber Nanocomposites. References. 10
Thermoplastic Polyurethane Nanocomposites (S.K. Smart, G.A. Edwards and
D.J. Martin). 10.1 Introduction. 10.2 Market. 10.3 TPU Chemistry,
Morphology and Properties. 10.4 TPU Nanocomposites. 10.5 Layered
Silicate/TPU Nanocomposites. 10.6 Carbon Nanotube/TPU Nanocomposites. 10.7
Future Perspectives. References. 11 Microscope Evaluation of the Morphology
of Rubber Nanocomposites (Hiroaki Miyagawa). 11.1 Introduction. 11.2
Optical Microscopy. 11.3 Scanning Electron Microscopy. 11.4 Transmission
Electron Microscopy. 11.5 Scanning Probe Microscopy. 11.6 Summary.
References. 12 Mechanical Properties of Rubber Nanocomposites: How, Why . .
. and Then? (L. Chazeau, C. Gauthier and J.M. Chenal). 12.1 Introduction.
12.2 Typical Mechanical Behavior of Rubber Nanocomposites. 12.3 How to
Explain Reinforcement in Rubber Nanocomposite? 12.4 Modeling Attempts. 12.5
General Conclusions. References. 13 Nonlinear Viscoelastic Behavior of
Rubbery Bionanocomposites (Alireza S. Sarvestani and Esmaiel Jabbari). 13.1
Introduction. 13.2 Rubbery Bionanocomposites. 13.3 Nonlinear
Viscoelasticity of Hydrogel Nanocomposites. 13.4 Conclusions.
Acknowledgments. References. 14 Rheological Behavior of Rubber
Nanocomposites (Philippe Cassagnau and Claire Barres). 14.1 Introduction.
14.2 Linear Viscoelasticity. 14.3 Payne Effect. 14.4 Flow Properties of
Rubber Nanocomposites. 14.5 Conclusions. References. 15 Electron Spin
Resonance in Studying Nanocomposite Rubber Materials (S. Valic). 15.1 An
Approach to the Study of Polymer Systems. 15.2 ESR - Spin Probe Study of
Nanocomposite Rubber Materials. 15.3 Summary. References. 16 Studies on
Solid-State NMR and Surface Energetics of Silicas for Improving
Filler-Elastomer Interactions in Nanocomposites (Soo-Jin Park and Byung-Joo
Kim). 16.1 Introduction. 16.2 Surface Modification of Silicas. 16.3
Solid-State NMR Analyses of Silicas. 16.4 Surface Energetics of Silicas.
16.5 Other Surface Analyses of Modified Silicas. 16.6 Mechanical
Interfacial Properties of the Compounds. 16.7 Conclusions. References. 17
Wide-Angle X-ray Diffraction and Small-Angle X-ray Scattering Studies of
Rubber Nanocomposites (Valerio Causin). 17.1 Introduction. 17.2 WAXD: An
Overview. 17.3 SAXS: An Overview. 17.4 Lamellar Fillers. 17.5 Nonlamellar
Fillers. 17.6 Characterization of the Matrix in Polymer-Based
Nanocomposites. References. 18 Barrier Properties of Rubber Nanocomposites
(Changwoon Nah and M. Abdul Kader). 18.1 Introduction. 18.2 Theoretical
Consideration. 18.3 Experimental Studies. 18.4 Applications. 18.5
Conclusions. Acknowledgments. References. 19 Rubber/Graphite Nanocomposites
(Guohua Chen and Weifeng Zhao). 19.1 Introduction and Background. 19.2
Graphite and its Nanostructure. 19.3 Rubber/Graphite Nanocomposites. 19.4
Future Outlook. Acknowledgments. References. 20 Aging and Degradation
Behavior of Rubber Nanocomposites (Suneel Kumar Srivastava and Himadri
Acharya). 20.1 Introduction. 20.2 Types of Fillers Used in Rubber
Nanocomposites. 20.3 Aging of Rubber Nanocomposites. 20.4 Degradation of
Rubber Nanocomposites. 20.5 Summary. References. 21 Positron Annihilation
Lifetime Spectroscopy (PALS) and Nanoindentation (NI) (Dariusz M. Bielinski
and Ludomir Slusarski). 21.1 Introduction. 21.2 Positron Annihilation
Lifetime Spectroscopy. 21.3 Nanoindentation 621 22 Thermoelasticity and
Stress Relaxation Behavior of Synthetic Rubber/ Organoclay Nanocomposites
(K.M. Sukhyy, E.G. Privalko, V.P. Privalko and M.V. Burmistr). 22.1
Introduction. 22.2 Experimental. 22.3 Polychloroprene/Organoclay
Nanocomposites. 22.4 Styrene-co-Butadiene Rubber/Organoclay Nanocomposites.
23 Theoretical Modeling and Simulation of Rubber Nanocomposites (Jan Kalfus
and Josef Jancar). 23.1 Introduction. 23.2 Brief Theory of Conformation
Statistics and Chain Dynamics. 23.3 Basic Aspects of Rubber Elasticity.
23.4 Mechanisms of Nanocomposite Reinforcement. 23.5 Chains at
Rubber-Filler Interfaces. 23.6 Structural Peculiarities of Rubbery
Nanocomposites. 23.7 Concluding Remarks. Acknowledgments. References. 24
Application of Rubber Nanocomposites (Miroslawa El Fray and Lloyd A.
Goettler). 24.1 Introduction. 24.2 Rubber Nanocomposites in Tire
Engineering Applications. 24.3 Rubber Nanocomposite Membranes. 24.4
Applications of Rubber Nanocomposites in Sporting Goods. 24.5 Advanced
Nanocomposites for Airspace Applications. 24.6 Nanorubbers in Medicine and
Healthcare. 24.7 Conclusions. References. Index.