Robert A. Stockland

Practical Functional Group Synthesis, Enhanced E-Book (eBook, ePUB)

• Format: ePub

Produktbeschreibung

A practical handbook for chemists performing bond forming reactions, this book features useful information on the synthesis of common functional groups in organic chemistry. * Details modern functional group synthesis through carbon-heteroelement (N, O, P, S, B, halogen) bond forming reactions with a focus on operational simplicity and sustainability. * Summarizes key and recent developments - which are otherwise scattered across journal literature - into a single source * Contains over 100 detailed preparations of common functional groups * Included 25 troubleshooting guides with suggestions and potential solutions to common problems. * Complements the text in enhanced ebook editions with tutorial videos where the author provides an introduction to microwave assisted chemistry

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Produktdetails

• Verlag: John Wiley & Sons
• Seitenzahl: 704
• Erscheinungstermin: 16. März 2016
• Englisch
• ISBN-13: 9781119015826
• Artikelnr.: 59225783

Autorenporträt

Robert A. Stockland, Jr., PhD, is a Professor of Chemistry at Bucknell University where he teaches organic and inorganic chemistry. His research interests are focused on the development of new synthetic methodology leading to the preparation of new compounds and challenging linkages. In addition to reporting the synthesis of over 200 new compounds, Dr. Stockland has authored a book chapter on sustainable organic reactions and co-edited a symposium book on NMR spectroscopy.

Inhaltsangabe

Preface ix Acknowledgments xi 1 Introduction to Practical Functional Group
Synthesis 1 1.1 General Approaches for Designing Syntheses 1 1.2 New
Versions of "Classic" Organic Reactions 6 1.3 Solvent Selection and
Solvent-Free Reactions 7 1.4 Operational Simplicity 11 1.5 Metal-Catalyzed
Transformations 12 1.6 Organocatalysis 16 1.7 Microwave- and
Ultrasound-Assisted Chemistry 17 1.8 Sustainability 25 1.9 Asymmetric
Synthesis 32 References 33 2 Preparation of Alcohols, Ethers, and Related
Compounds 37 2.1 Preparation of Alcohols, Ethers, and Related Compounds
through the Formation of Oxygen-Carbon(sp3) Bonds 37 2.2 Preparation of
Phenols, Aryl Ethers, and Related Compounds through the Formation of
Oxygen-Carbon(sp2) Bonds 57 2.3 Preparation of Vinyl Ethers and Related
Compounds through the Formation of Oxygen-Carbon(sp2) Bonds 84 2.4
Preparation of Alkynyl Ethers and Related Compounds through the Formation
of Oxygen-Carbon(sp) Bonds 114 References 117 3 Synthesis of Amines,
Amides, and Related Compounds 123 Alkylamines 123 3.1 Synthesis of
Alkylamines and Related Compounds through Nitrogen-Carbon(sp3) Bond-Forming
Reactions 123 3.2 Synthesis of Arylamines and Related Compounds through
Nitrogen-Carbon(sp2) Bond-Forming Reactions 150 3.3 Synthesis of
Vinylamines and Related Compounds through Nitrogen-Carbon(sp2) Bond-Forming
Reactions 191 3.4 Synthesis of Ynamides and Related Compounds through
Nitrogen-Carbon(sp) Bond-Forming Reactions 207 References 213 4 Synthesis
of Organophosphines, Phosphonates, and Related Compounds 219 4.1
Introduction to the Synthesis of Organophosphorus Compounds Generated
through the Formation of Phosphorus-Carbon Bonds 219 4.2 Synthesis of
Alkylphosphines and Related Compounds through the Formation of
Phosphorus-Carbon(sp3) Bonds 220 4.3 Synthesis of Arylphosphines and
Related Compounds through the Formation of Phosphorus-Carbon(sp2) Bonds 338
4.4 Synthesis of Vinylphosphines and Related Compounds through the
Formation of Phosphorus-Carbon(sp2) Bonds 398 4.5 Synthesis of
Alkynylphosphines and Related Compounds through the Formation of
Phosphorus-Carbon(sp) Bonds 441 References 454 5 Synthesis of Thioethers,
Sulfones, and Related Compounds 471 5.1 Synthesis of Thioethers and Related
Compounds through the Formation of Sulfur-Carbon(sp3) Bonds 471 5.2
Synthesis of Aryl Thioethers and Related Compounds through the Formation of
Sulfur-Carbon(sp2) Bonds 481 5.3 Synthesis of Vinyl Thioethers and Related
Compounds through the Formation of Sulfur-Carbon(sp2) Bonds 498 5.4
Synthesis of Thioethers and Related Compounds through the Formation of
Sulfur-Carbon(sp) Bonds 506 References 510 6 Synthesis of Organoboronic
Acids, Organoboronates, and Related Compounds 515 6.1 Synthesis of
Alkylboronates and Related Compounds through the Formation of
Boron-Carbon(sp3) Bonds 515 6.2 Synthesis of Arylboronates and Related
Compounds through the Formation of Boron-Carbon(sp2) Bonds 526 6.3
Synthesis of Vinylboronates and Related Compounds through the Formation of
Boron-Carbon(sp2) Bonds 538 6.4 Synthesis of Alkynylboronates and Related
Compounds through the Formation of Boron-Carbon(sp) Bonds 549 References
552 7 Synthesis of Organohalides 557 7.1 Synthesis of Alkyl Halides through
the Formation of Halogen-Carbon(sp3) Bonds 557 7.2 Synthesis of Aryl
Halides through the Formation of Halogen-Carbon(sp2) Bonds 590 7.3
Synthesis of Vinyl Halides through the Formation of Halogen-Carbon(sp2)
Bonds 628 7.4 Synthesis of Alkynyl Halides through the Formation of
Halogen-Carbon(sp) Bonds 655 References 670 Index 679