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Presenting the wide range of synthetic possibilities opened by sol-gel processes in the field of organic-inorganic materials, Molecular Chemistry of Sol-Gel Derived Nanomaterials discusses the state of the art in the synthesis of the various nanomaterials. The text includes examples of applications, including photoluminescent nanocomposites, grafted nanomaterials for selective separations of ions or isotopes, for cascade syntheses, chelation of transition metals and lanthanides by lamellar structured nanomaterials, and immobilized enzymes on mesoporous nanomaterials. This indispensable text…mehr
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- Produktdetails
- Verlag: John Wiley & Sons
- Seitenzahl: 200
- Erscheinungstermin: 18. Februar 2009
- Englisch
- ISBN-13: 9780470742808
- Artikelnr.: 37299043
- Verlag: John Wiley & Sons
- Seitenzahl: 200
- Erscheinungstermin: 18. Februar 2009
- Englisch
- ISBN-13: 9780470742808
- Artikelnr.: 37299043
Introduction. 1.2 Scope and Origin of Nanosciences: The 'Top-Down' and
'Bottom-Up' Approaches. 1.3 Chemical Mutation: From an Exploratory to a
Creative Science. 1.4 Carbon and Ceramic Fibers: The Nanomaterial
'Ancestors'. 1.5 Conclusions. References. 2 Nano-Objects. 2.1 Introduction.
2.2 Presentation of Nano-Objects. 2.3 Synthesis of Nano-Objects. 2.4 The
Nano-Object: Entry into Nanosciences. References. 3 Introduction to
Material Chemistry. 3.1 General Remarks. 3.2 Inorganic Materials: Crystals
and Glasses. 3.3 Thermodynamically Controlled Organic-Inorganic Hybrid
Materials. 3.4 Ceramic Materials Obtained from Organometallic Polymers:
Ceramics with Interpenetrating Networks. 3.5 Inorganic Polymer Materials
(Sol-Gel Process). 3.6 Inorganic Polymerization and Molecular Chemistry.
3.7 Silica and Molecular Chemistry: A Dream Team. 4 From Nano-Object to
Nanomaterial. 4.1 The Different Types of Nanomaterials. 4.2 Inorganic
Polymerization: A Major Route to Nanomaterials. 4.3 Nanocomposite
Materials. 4.4 Grafted Materials. 4.5 Selective Separation. 4.6 Materials
Obtained by Polycondensation of Monosubstituted Trialkoxysilanes. 4.7
Multistage Syntheses - Cascade Reactions. References. 5 Nanostructured
Materials. 5.1 General Remarks. 5.2 Synthesis of Hybrid Nanomaterials. 5.3
Nanostructured Hybrid Materials. 5.4 Kinetic Control of the Texture of
Nanostructured Hybrid Materials. 5.5 Supramolecular Self-Organization
Induced by Hydrogen Bonds. 5.6 Supramolecular Self-Organization Induced by
Weak van der Waals Type Bonds. 5.7 Lamellar Materials. 5.8 Prospects. 5.9
Some Possible Developments. References. 6 Chemistry Leading to Interactive
Nanomaterials. 6.1 Introduction. 6.2 Smart Materials. 6.3 The Route to
Interactive Materials - Definitions. 6.4 Mesoporous Materials. 6.5
Functionalization of the Pores. 6.6 Functionalization of the Framework. 6.7
Importance of Functionalization and of Weight Analyses. 6.8 On the Way to
Interactive Nanomaterials. 6.9 Preparation of New Matrices. 6.10 On the Way
to Biological Applications. 6.11 Conclusions. References. 7 Prospects and
Stakes. 7.1 General Remarks. 7.2 Predictable Developments. References.
Index.
Introduction. 1.2 Scope and Origin of Nanosciences: The 'Top-Down' and
'Bottom-Up' Approaches. 1.3 Chemical Mutation: From an Exploratory to a
Creative Science. 1.4 Carbon and Ceramic Fibers: The Nanomaterial
'Ancestors'. 1.5 Conclusions. References. 2 Nano-Objects. 2.1 Introduction.
2.2 Presentation of Nano-Objects. 2.3 Synthesis of Nano-Objects. 2.4 The
Nano-Object: Entry into Nanosciences. References. 3 Introduction to
Material Chemistry. 3.1 General Remarks. 3.2 Inorganic Materials: Crystals
and Glasses. 3.3 Thermodynamically Controlled Organic-Inorganic Hybrid
Materials. 3.4 Ceramic Materials Obtained from Organometallic Polymers:
Ceramics with Interpenetrating Networks. 3.5 Inorganic Polymer Materials
(Sol-Gel Process). 3.6 Inorganic Polymerization and Molecular Chemistry.
3.7 Silica and Molecular Chemistry: A Dream Team. 4 From Nano-Object to
Nanomaterial. 4.1 The Different Types of Nanomaterials. 4.2 Inorganic
Polymerization: A Major Route to Nanomaterials. 4.3 Nanocomposite
Materials. 4.4 Grafted Materials. 4.5 Selective Separation. 4.6 Materials
Obtained by Polycondensation of Monosubstituted Trialkoxysilanes. 4.7
Multistage Syntheses - Cascade Reactions. References. 5 Nanostructured
Materials. 5.1 General Remarks. 5.2 Synthesis of Hybrid Nanomaterials. 5.3
Nanostructured Hybrid Materials. 5.4 Kinetic Control of the Texture of
Nanostructured Hybrid Materials. 5.5 Supramolecular Self-Organization
Induced by Hydrogen Bonds. 5.6 Supramolecular Self-Organization Induced by
Weak van der Waals Type Bonds. 5.7 Lamellar Materials. 5.8 Prospects. 5.9
Some Possible Developments. References. 6 Chemistry Leading to Interactive
Nanomaterials. 6.1 Introduction. 6.2 Smart Materials. 6.3 The Route to
Interactive Materials - Definitions. 6.4 Mesoporous Materials. 6.5
Functionalization of the Pores. 6.6 Functionalization of the Framework. 6.7
Importance of Functionalization and of Weight Analyses. 6.8 On the Way to
Interactive Nanomaterials. 6.9 Preparation of New Matrices. 6.10 On the Way
to Biological Applications. 6.11 Conclusions. References. 7 Prospects and
Stakes. 7.1 General Remarks. 7.2 Predictable Developments. References.
Index.