Claude H. Yoder

Ionic Compounds (eBook, PDF)

Applications of Chemistry to Mineralogy

• Format: PDF

Produktbeschreibung

A practical introduction to ionic compounds for both mineralogists and chemists, this book bridges the two disciplines. It explains the fundamental principles of the structure and bonding in minerals, and emphasizes the relationship of structure at the atomic level to the symmetry and properties of crystals. This is a great reference for those interested in the chemical and crystallographic properties of minerals.

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Produktdetails

• Verlag: John Wiley & Sons
• Seitenzahl: 208
• Erscheinungstermin: 10. Oktober 2006
• Englisch
• ISBN-13: 9780470075098
• Artikelnr.: 37290088

Autorenporträt

CLAUDE H. YODER is a chemistry professor at Franklin & Marshall College. He is the recipient of numerous national awards and research grants and is the author of over 100 publications.

Inhaltsangabe

Chapter 1. Bonding and Composition. Types of Bonding. Ionic Compounds.
Types of Ions. Names of Ions. Percent Composition and Empirical Formula.
The Mole. Molar Mass (Formula Weight). Calculation of Empirical Formula
from Percent Composition. Use of Oxide Data. Formulas for Solid Solutions.
Covalent Character in Ionic Compounds. Interactions Between Ions. Some Laws
of Electrostatics. Potential Energy of Charged Particles. Lattice Energy
and Its Effect on Properties. Chapter 2. Structure of Ionic Compounds:
Close-packing. Closest Packing of Ions. The Holes Between the Layers.
Stacking Sequences. Closest Packing for Ionic Compounds. Relationship of
Formula to Occupation of Voids. Chapter 3. The Symmetry of Crystals.
Symmetry Elements. Hermann-Mauguin Notation (Point Groups). Crystal
Systems. Chapter 4. Structure of Some Simple Closest-packed Compounds.
Symmetry of the AB and ABC Closest-Packed Arrangements. The Unit Cell. The
NaCl Structure. The Sphalerite Structure. Axial Relationships. Wurtzite, a
Polymorph of Sphalerite. The Fluorite Structure. The Rutile Structure,
Polyhedral Coordination Models. Chapter 5. Factors that Affect the Symmetry
of the Unit Cell. Effect of Cation. The Chalcopyrite Structure and Solid
Solution. Effect of the Anion. Some Oxy Anions. The Pyrite Structure. The
Calcite Structure. Aragonite, A Polymorph of Calcite. Several Sulfates,
Anhydrite and Barite. Several Silicates, Zircon and Beryl. Effect of
Temperature and Pressure. Chapter 6. Physical Properties: Morphology.
Morphology. Miller indices. Forms. Habit. Deviations in Crystal Growths.
Parallel Growth. Twinning. Epitaxis and Pseudomorphism. Chapter 7. Physical
Properties: Color. Light and the Electromagnetic Spectrum. The Nature of
Electrons. Electron Configurations. The Crystal Field Model. Colored
Cations. Ion Impurities. Crystal Defects. Chapter 8. Chemical Properties.
Solubility. Energetics of Dissolution. Solubility Rules. Double Salts.
Reaction with Acids. Types of Chemical Reactions. Water as Both Acid and
Base. Strong and Weak Acids. Conjugate Bases. Use of Chemical Reactions for
Identification. Appendices. 1. The periodic chart. 2. The elements:
Symbols, melting points, boiling points, densities, and electronegativities
. 3. Metallic, covalent, and ionic radii. 4. Quartz. 5. Crystal system
identification practice. 6. Crystal classes and point groups. 7. Additional
reading and resources.

Rezensionen

"...a useful reference for both introductory mineralogy and chemistry students...its greatest application might be for serious mineral collectors." ( CHOICE , April 2007)