Geoffrey Alan Lawrance

Introduction to Coordination Chemistry (eBook, PDF)

• Format: PDF

Produktbeschreibung

At the heart of coordination chemistry lies the coordinate bond, in its simplest sense arising from donation of a pair of electrons from a donor atom to an empty orbital on a central metalloid or metal. Metals overwhelmingly exist as their cations, but these are rarely met 'naked' - they are clothed in an array of other atoms, molecules or ions that involve coordinate covalent bonds (hence the name coordination compounds). These metal ion complexes are ubiquitous in nature, and are central to an array of natural and synthetic reactions. Written in a highly readable, descriptive and accessible style Introduction to Coordination Chemistry describes properties of coordination compounds such as colour, magnetism and reactivity as well as the logic in their assembly and nomenclature. It is illustrated with many examples of the importance of coordination chemistry in real life, and includes extensive references and a bibliography. Introduction to Coordination Chemistry is a comprehensive and insightful discussion of one of the primary fields of study in Inorganic Chemistry for both undergraduate and non-specialist readers.

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Produktdetails

• Verlag: John Wiley & Sons
• Seitenzahl: 304
• Erscheinungstermin: 5. November 2009
• Englisch
• ISBN-13: 9780470687130
• Artikelnr.: 38190144

Autorenporträt

Professor Geoffrey Lawrance; Professor of Chemistry and Assistant Dean Research (Science & IT), The University of Newcastle, Australia Professor Lawrance is the author or co-author of over 290 journal articles, review articles and book chapters in a career spanning three decades. He has contributed chapters to Encyclopaedia of Inorganic Chemistry II (Wiley, 2005), and Comprehensive Coordination Chemistry II (Elsevier, 2004).

Inhaltsangabe

Preface. Preamble. 1 The Central Atom. 1.1 Key Concepts in Coordination Chemistry. 1.2 A Who's Who of Metal Ions. 1.3 Metals in Molecules. 1.4 The Road Ahead. Concept Keys. Further Reading. 2 Ligands. 2.1 Membership: Being A Ligand. 2.2 Monodentate Ligands
The Simple Type. 2.3 Greed is Good
Polydentate Ligands. 2.4 Polynucleating Species
Molecular Bigamists. 2.5 A Separate Race
Organometallic Species. Concept Keys. Further Reading. 3 Complexes. 3.1 The Central Metal Ion. 3.2 Metal
Ligand Marriage. 3.3 Holding On
The Nature of Bonding in Metal Complexes. 3.4 Coupling
Polymetallic Complexes. 3.5 Making Choices. 3.6 Complexation Consequences. Concept Keys. Further Reading. 4 Shape. 4.1 Getting in Shape. 4.2 Forms of Complex Life. 4.3 Influencing Shape. 4.4 Isomerism
Real 3D Effects. 4.5 Sophisticated Shapes. 4.6 Defining Shape. Concept Keys. Further Reading. 5 Stability. 5.1 The Makings of a Stable Relationship. 5.2 Complexation
Will it Last? 5.3 Reactions. Concept Keys. Further Reading. 6 Synthesis. 6.1 Molecular Creation
Ways to Make Complexes. 6.2 Core Metal Chemistry
Periodic Table Influences. 6.3 Reactions Involving the Coordination Shell. 6.4 Reactions Involving the Metal Oxidation State. 6.5 Reactions Involving Coordinated. 6.6 Organometallic Synthesis. Concept Keys. Further Reading. 7 Properties. 7.1 Finding Ways to Make Complexes Talk
Investigative Methods. 7.2 Getting Physical
Methods and Outcomes. 7.3 Probing the Life of Complexes
Using Physical Methods. Concept Keys. Further Reading. 8 A Complex Life. 8.1 Life's a Metal Ion. 8.2 Metalloproteins and Metalloenzymes. 8.3 Doing What Comes Unnaturally
Synthetic Biomolecules. 8.4 A Laboratory
free Approach
In Silico Prediction. Concept Keys. Further Reading. 9 Complexes and Commerce. 9.1 Kill or Cure?
Complexes as Drugs. 9.2 How Much?
Analysing with Complexes. 9.3 Profiting from Complexation. 9.4 Being Green. 9.5 Complex Futures. Concept Keys. Further Reading. Appendix A Nomenclature. Appendix B Molecular Symmetry: The Point Group. Index.