Limin Wu, Jamil Baghdachi

Functional Polymer Coatings (eBook, PDF)

Principles, Methods, and Applications

• Format: PDF

Produktbeschreibung

Focusing on a variety of coatings, this book provides detailed discussion on preparation, novel techniques, recent developments, and design theories to present the advantages of each function and provide the tools for better product performance and properties. * Presents advantages and benefits of properties and applications of the novel coating types * Includes chapters on specific and novel coatings, like nanocomposite, surface wettability tunable, stimuli-responsive, anti-fouling, antibacterial, self-healing, and structural coloring * Provides detailed discussion on recent developments in the field as well as current and future perspectives * Acts as a guide for polymer and materials researchers in optimizing polymer coating properties and increasing product performance

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Produktdetails

• Verlag: John Wiley & Sons
• Seitenzahl: 368
• Erscheinungstermin: 18. Mai 2015
• Englisch
• ISBN-13: 9781118883037
• Artikelnr.: 42923316

Autorenporträt

Limin Wu is the director of the Advanced Coatings Research Center of the Ministry of Education of China and a Professor of the Department of Materials Science at Fudan University in Shanghai. He has over 20 years of experience in the areas of nano/micro hybrid colloidal spheres and functional polymer coatings. Jamil Baghdachi is the Interim Director of the Coatings Research Institute and a Professor in the Polymers and Coatings department at Eastern Michigan University. He has over 25 years of experience in polymers, coatings, adhesives, paints, and composites and has acted as a consultant for national and international firms.

Inhaltsangabe

Contributors xi Preface xiii 1 Transparent Organic-Inorganic Nanocomposite
Coatings 1 Shuxue Zhou and Limin Wu 1.1 Introduction 1 1.2 Fabrication
Strategies 2 1.2.1 Blending Method 2 1.2.2 Sol-Gel Process 10 1.2.3
Intercalation Method 11 1.3 Mechanically Enhanced Nanocomposite Clearcoats
13 1.3.1 Solventborne Polyurethane Nanocomposite Coatings 15 1.3.2
Waterborne Nanocomposite Clearcoats 17 1.3.3 UV?]Curable Nanocomposite
Coatings 19 1.3.4 Other Mechanically Strong Nanocomposite Coatings 26 1.4
Optical Nanocomposite Coatings 28 1.4.1 Transparent UV?]Shielding
Nanocomposite Coatings 28 1.4.2 High Refractive Index Nanocomposite
Coatings 34 1.4.3 Transparent NIR?]Shielding Nanocomposite Coatings 41 1.5
Transparent Barrier Nanocomposite Coatings 45 1.6 Transparent Conducting
Nanocomposite Coatings 49 1.7 Other Functional Nanocomposite Coatings 54
1.8 Conclusions and Outlook 57 References 58 2 Superhydrophobic and
Superoleophobic Polymeric Surfaces 71 Jie Zhao and W. (Marshall) Ming 2.1
Introduction 71 2.2 Surface Wettability 72 2.3 Various Approaches to Obtain
Super?]Repellent Surfaces 74 2.3.1 Template?]Replicating Methods 74 2.3.2
Hierarchically Structured Particles 75 2.3.3 LbL Deposition 78 2.3.4 Plasma
Treatment 79 2.3.5 Chemical Vapor Deposition 81 2.3.6 Electrospinning 83
2.3.7 Electrochemical Polymerization 85 2.3.8 Other Methods 86 2.4
Applications of Super?]Repellent Polymeric Surfaces 86 2.4.1 Self?]Cleaning
86 2.4.2 Anti?]bioadhesion 87 2.4.3 Anti?]Icing 89 2.4.4 Oil-Water
Separation 89 2.5 Summary and Outlook 90 Acknowledgments 90 References 90 3
Superhydrophilic and Superamphiphilic Coatings 96 Sandro Olveira, Ana
Stojanovic, and Stefan Seeger 3.1 Introduction 96 3.2 Basic Concepts of
Superhydrophilicity 97 3.3 Naturally Occurring Superhydrophilic and
Superamphiphilic Surfaces 100 3.4 Artificial Superhydrophilic Coatings 101
3.4.1 TiO2 Coatings 101 3.4.2 SiO2 Coatings 103 3.5 Methods for Fabricating
Superhydrophilic and Superamphiphilic Surfaces 104 3.5.1 Sol-Gel Method 104
3.5.2 Layer?]By?]Layer Assembly 105 3.5.3 Electrochemical Methods 106 3.5.4
Electrospinning 106 3.5.5 Etching 107 3.5.6 Plasma Treatment 107 3.5.7
Hydrothermal Method 108 3.5.8 Dip Coating 109 3.5.9 Phase Separation 109
3.5.10 Templating Method 109 3.6 Applications 110 3.6.1 Self?]Cleaning 110
3.6.2 Antifogging and Antireflective Coatings 111 3.6.3 Antifouling
Properties 114 3.6.4 Enhanced Boiling Heat Transfer 115 3.6.5 Efficient
Water Evaporation 118 3.6.6 Switchable and Patterned Wettability Coatings
118 3.6.7 Other Applications 119 3.7 Commercial Coatings 120 3.8
Conclusions and Outlook 122 References 123 4 Self?]Healing Polymeric
Coatings 133 A.C.C. Esteves and S.J. García 4.1 Introduction 133 4.1.1
Self?]Healing Materials 134 4.1.2 Self?]Healing Polymeric Coatings 137 4.2
Self?]Healing Approaches for Functional Polymeric Coatings 138 4.2.1
Intrinsic Healing 138 4.2.2 Extrinsic Healing 147 4.3 Functionalities
Recovery and Possible Applications 149 4.3.1 Surface Properties:
Wettability and Anti?](bio)adhesion 149 4.3.2 Barrier and Corrosion
Protection 151 4.3.3 Interfacial Bonding between Dissimilar Materials 153
4.4 Concluding Remarks and Challenges 154 Acknowledgments 155 References
155 5 Stimuli-Responsive Polymers as Active Layers for Sensors 163 Sergio
Granados?]Focil 5.1 Introduction 163 5.2 Stimuli?]Responsive Soft Materials
164 5.2.1 Thermally Responsive Polymers 165 5.2.2 Field?]Responsive
Polymers 166 5.2.3 Biologically Responsive Polymer Systems 168 5.2.4
Multistimuli?]Responsive Materials 172 5.2.5 Stimuli?]Responsive Hydrogels
175 5.3 Sensors from Stimuli?]Responsive Hydrogel Layers 176 5.3.1 pH
Sensors 178 5.3.2 Metal Ion Sensors 179 5.3.3 Humidity Sensors 180 5.3.4
DNA Sensors 181 5.3.5 Glucose Sensors 181 5.4 Ionophore?]Based Sensors 182
5.4.1 Ion?]Selective Electrodes 182 5.4.2 Chromoionophores 184 5.4.3
Optodes 185 5.4.4 Dynamic Optodes 185 5.5 Challenges and Opportunities 186
References 187 6 Self?]Stratifying Polymers and Coatings 197 Jamil
Baghdachi, H. Perez, and Punthip Talapatcharoenkit 6.1 Introduction 197 6.2
Basic Concepts of Self?]Stratification 200 6.2.1 Evaporation Effect 200
6.2.2 The Surface Tension Gradient 201 6.2.3 The Substrate?]Wetting Force
203 6.2.4 Kinetically Controlled Reactions 205 6.3 Conclusions 214
References 215 7 Surface?]Grafted Polymer Coatings: Preparation,
Characterization, and Antifouling Behavior 218 Marc A. Rufin and Melissa A.
Grunlan 7.1 Introduction 218 7.2 Surface?]Grafting Methods 219 7.2.1
"Grafting?]From" Method 219 7.2.2 "Grafting?]To" Method 220 7.3 Behavior of
Surface?]Grafted Polymers 222 7.3.1 Conformation of Grafted Chains 222
7.3.2 Chain Migration 223 7.4 Characterization Techniques 224 7.4.1
Ellipsometry 224 7.4.2 Contact Angle 224 7.4.3 X?]ray Photoelectron
Spectroscopy 225 7.4.4 Scanning Probe Microscopies 226 7.5 Antifouling
Coatings 227 7.5.1 Surface?]Grafted PEG 228 7.5.2 Surface?]Grafted
Zwitterionic Polymers 229 7.6 Summary 230 References 230 8 Partially
Fluorinated Coatings by Surface?]Initiated Ring?]Opening Metathesis
Polymerization 239 G. Kane Jennings and Carlos A. Escobar 8.1 Basic
Concepts 239 8.2 Surface Chemistry 241 8.3 Kinetics of Film Growth 242 8.4
Surface Energy of pnbfn Films 243 8.5 Micromolding Sip 245 8.6 Conclusions
and Outlook 247 Acknowledgments 248 References 248 9 Fabrication and
Application of Structural Color Coatings 250 Zhehong Shen, Hao Chen, and
Limin Wu 9.1 Introduction 250 9.2 General Methods of Colloidal Assembly 252
9.2.1 Flow?]Induced Deposition 252 9.2.2 Field?]Induced Deposition 257 9.3
Colloidal Assembly of Soft Polymer Spheres 260 9.4 Uses of Structural
Colors 265 9.4.1 Photonic Paper 265 9.4.2 Coloring and Protection of
Substrates 267 9.4.3 Color Responses 268 9.4.4 Structural Color Coatings
with Lotus Effects and Superhydrophilicity 272 9.4.5 Structural Color as
Effect Pigments 273 9.5 Conclusions and Outlook 274 References 274 10
Antibacterial Polymers and Coatings 280 Jamil Baghdachi and Qinhua Xu 10.1
Introduction 280 10.2 Basic Concepts 281 10.2.1 Coatings that Resist
Adhesion 282 10.2.2 Coatings that Release Toxins 282 10.3 Polymers and
Antimicrobial Coating Binders 283 10.3.1 Polymeric Coatings with QA Groups
283 10.3.2 Polymers with Quaternary Phosphonium Groups 284 10.3.3
Norfloxacin?]Containing Polymers 286 10.3.4 Polymeric N?]Halamines 288 10.4
Addition of Inorganic Particles 289 10.4.1 Titanium Dioxide 289 10.4.2 Zinc
Oxide 290 10.4.3 Silver Compounds 290 10.5 Conclusions and Outlook 292
References 292 11 Novel Marine Antifouling Coatings: Antifouling Principles
and Fabrication Methods 296 Yunjiao Gu and Shuxue Zhou 11.1 Introduction
296 11.2 Marine Biofouling 297 11.3 Enzyme?]Based Coatings 300 11.4 Fouling
Release Coatings 302 11.4.1 Principles of FR Coatings 302 11.4.2 Hybrid
Silicone?]Based FR Coatings 304 11.4.3 Fluoropolymer?]Based FR Coatings 305
11.5 Nonfouling Coatings 305 11.5.1 Principles of NF Coatings 306 11.5.2
PEG?]Based NF Coatings 307 11.5.3 Poly(Zwitterionic) NF Coatings 311 11.5.4
Other Hydrophilic NF Materials 313 11.6 Bioinspired Micro?]Topographical
Surfaces 316 11.6.1 AF Principles of Bioinspired Microtopographical
Surfaces 316 11.6.2 Approaches to the Production of AF Coatings with
Surface Topographies 320 11.7 Amphiphilic Nanostructured Coatings 322
11.7.1 Principles of Amphiphilic Nanostructured Coatings 323 11.7.2
PEG?]Fluoropolymers Amphiphilic Coatings 325 11.7.3 Other Amphiphilic AF
Polymers 329 11.7.4 Characterization Techniques 329 11.8 Summary 331
References 333 Index 338