Donald W. Rogers

Concise Physical Chemistry (eBook, ePUB)

• Format: ePub

Produktbeschreibung

This book is a physical chemistry textbook that presents the essentials of physical chemistry as a logical sequence from its most modest beginning to contemporary research topics. Many books currently on the market focus on the problem sets with a cursory treatment of the conceptual background and theoretical material, whereas this book is concerned only with the conceptual development of the subject. Comprised of 19 chapters, the book will address ideal gas laws, real gases, the thermodynamics of simple systems, thermochemistry, entropy and the second law, the Gibbs free energy, equilibrium, statistical approaches to thermodynamics, the phase rule, chemical kinetics, liquids and solids, solution chemistry, conductivity, electrochemical cells, atomic theory, wave mechanics of simple systems, molecular orbital theory, experimental determination of molecular structure, and photochemistry and the theory of chemical kinetics.

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Produktdetails

• Verlag: John Wiley & Sons
• Seitenzahl: 404
• Erscheinungstermin: 31. März 2011
• Englisch
• ISBN-13: 9781118102237
• Artikelnr.: 37351984

Autorenporträt

Donald W. Rogers is Professor Emeritus in the Department of Chemistry and Biochemistry at Long Island University. He is the author of six books and received his PhD from the University of North Carolina.

Inhaltsangabe

Chapter 1 Ideal Gas Laws. 1.1 Empirical Gas Laws. 1.2 The Mole. 1.3
Equations of State. 1.4 Dalton's Law. 1.5 The Mole Fraction. 1.6 Extensive
and Intensive Variables. 1.7 Graham's Law of Effusion. 1.8 The
Maxwell-Boltzmann Distribution. 1.9 A Digression on "Space". 1.10 The
Sum-Over-States or Partition Function. Chapter 2 Real Gases: Empirical
Equations. 2.1 The van der Waals Equation. 2.2 The Virial Equation: A
Parametric Curve Fit. 2.3 The Compressibility Factor. 2.4 The Critical
Temperature. 2.5 Reduced Variables. 2.6 The Law of Corresponding States,
Another View. 2.7 Compressibility Factors Calculated From the van der Waals
Constants. 2.8 Boyle's Law Plot for an Ideal Gas (lower curve) and for
Nitrogen (upper curve). 2.9 Determining the Molecular Weight of a Nonideal
Gas. Chapter 3 The Thermodynamics of Simple Systems. 3.1 Conservation Laws
and Exact Differentials. 3.2 Thermodynamic Cycles. 3.3 Line Integrals in
General. 3.3 Pythagorean Approximation to the Short Arc of a Curve. 3.4
Thermodynamic States and Systems. 3.5 State Functions. 3.6 Reversible
Processes and Path Independence. 3.7 Heat Capacity. 3.8 Energy and
Enthalpy. 3.9 The Joule and Joule-Thomson Experiments. 3.10 The Heat
Capacity of an Ideal Gas. 3.11 Adiabatic Work. Chapter 4 Thermochemistry.
4.1 Calorimetry. 4.2 Energies and Enthalpies of Formation. 4.3 Standard
States. 4.4 Molecular Enthalpies of Formation. 4.5 Enthalpies of Reaction.
4.6 Group Additivity. 4.7 from Classical Mechanics. 4.8 The Schroedinger
Equation. 4.9 Variation of with T. 4.10 Differential Scanning Calorimetry.
Chapter 5 Entropy and the Second Law. 5.1 Entropy. 5.2 Entropy Changes. 5.3
Spontaneous Processes. 5.4 The Third Law. Chapter 6 The Gibbs Free Energy.
6.1 Combining Enthalpy and Entropy. 6.2 Free Energies of Formation. 6.3
Some Fundamental Thermodynamic Identities. 6.4 The Free Energy of Reaction.
6.5 Pressure Dependence of the Chemical Potential. 6.6 The Temperature
dependence of the Free Energy. Chapter 7 Equilibrium. 7.1 The Equilibrium
Constant. 7.2 General Formulation. 7.3 The Extent of Reaction. 7.4 Fugacity
and Activity. 7.5 Variation of the Equilibrium Constant with Temperature.
7.6 Computational Thermochemistry. 7.7 Chemical Potential: Nonideal Systems
. 7.8 Free Energy and Equilibria in Biochemical Systems. Chapter 8 A
Statistical Approach to Thermodynamics. 8.1 Equilibrium. 8.2 Degeneracy and
Equilibrium. 8.3 Gibbs Free Energy and the Partition Function. 8.4 Entropy
and Probability. 8.5 The Thermodynamic Functions . 8.6 The Partition
Function of a Simple System. 8.7 The Partition Function for Different modes
of Motion. 8.8 The Equilibrium Constant: A Statistical Approach. 8.9
Computational Statistical Thermodynamics. Chapter 9 The Phase Rule. 9.1
Components, Phases, and Degrees of Freedom. 9.2 Coexistance Curves. 9.3 The
Clausius-Clapeyron Equation. 9.4 Partial Molar Volume. 9.5 The Gibbs Phase
Rule. 9.6 Two Component Phase Diagrams. 9.7 Compound Phase Diagrams. 9.8
Ternary Phase Diagrams. Chapter 10 Chemical Kinetics. 10.1 First Order
Kinetic Rate Laws. 10.2 Second Order Reactions. 10.3 Other Reaction Orders.
10.4 Experimental Determination of the Rate Equation. 10.5 Reaction
Mechanisms. 10.6 The Influence of Temperature on Rate. 10.7 Collision
Theory. 10.8 Computational Kinetics. Chapter 11 Liquids and Solids. 11.1
Surface Tension. 11.2 Heat Capacity of Liquids and Solids. 11.3 Viscosity
of Liquids. 11.4 Crystals. 11.5 Bravais Lattices. 11.6 Computational
Geometries. 11.7 Lattice Energies (Enthalpies). Chapter 12 Solution
Chemistry. 12.1 The Ideal Solution. 12.2 Raoult's Law. 12.3 A Digression on
Concentration Units Real Solutions.. 12.4 Real Solutions. 12.5 Henry's Law.
12.6 Vapor Pressure. 12.7 Boiling Point Elevation. 12.8 Osmotic Presure.
12.9 Colligative Properties. Chapter 13 Conductivity. 13.1 Electrical
Potential. 13.2 Resistivity, Conductivity and Conductance. 13.3 Molar
Conductivity. 13.4 Partial Ionization: Weak Electrolytes. 13.5 Ion
Mobilities. 13.6 Faraday's Laws. 13.7 Mobility and Conductance. 13.8 The
Hittorf Cell. 13.9 Ion Activities. Chapter 14 Electrochemical Cells. 14.1
The Daniell Cell. 14.2 Half Cells. 14.3 Half Cell Potentials. 14.4 Cell
Diagrams. 14.5 Electrical Work. 14.6 The Nernst Equation. 14.7
Concentration Cells. 14.8 Finding . 14.9 Solubility and Stability Products.
14.10 Mean Ionic Activity Coefficients. 14.11 The Calomel Electrode. 14.12
The Glass electrode. Chapter 15 Early Atomic Theory: A Summary. 15.1 The
Hydrogen Spectrum. 15.2 Early Quantum Theory. 15.3 Molecular Quantum
Chemistry. 15.4 The Hartree Independent Electron Method. Chapter 16 Wave
Mechanics of Simple Systems. 16.1 Wave Motion. 16.2 Wave Equations. 16.3
The Schroedinger Equation. 16.4 Quantum Mechanical Systems. 16.5 The
Particle in a One Dimensional Box. 16.6 The Particle in a Cubic Box. 16.7
The Hydrogen Atom. 16.8 Breaking Degeneracy. 16.9 Orthogonality and
Overlap. 16.10 Many Electron Atomic Systems. Chapter 17 The Variational
Method: Atoms. 17.1 More on The Variational Method. 17.2 The Secular
Determinant. 17.3 A Variational Treatment for the Hydrogen Atom: The Energy
Spectrum . 17.4 Helium. 17.5 Spin. 17.6 Bosons and Fermions. 17.7 Slater
Determinants. 17.8 The Aufbau Principle. 17.9 The SCF Energies of First Row
Atoms and Ions. 17.10 Slater-Type Orbitals STO. 17.11 Spin-Orbit Coupling.
Chapter 18 Experimental Determination of Molecular Structure. 18.1 The
Harmonic Oscillator. 18.2 The Hooke's Law Potential Well. 18.3 Diatomic
Molecules. 18.4 The Quantum Rigid Rotor. 18.5 Microwave Spectroscopy: Bond
strength and Bond Length. 18.6 Electronic Spectra. 18.7 Dipole Moments.
18.8 Nuclear Magnetic Resonance (NMR). 18.9 Electron Spin Resonance.
Chapter 19 Part A Classical Molecular Modeling. 19.1 Enthalpy: Additive
Methods. 19.2 Bond Enthalpies. 19.3 Structure. 19.4 Geometry and Enthalpy:
Molecular Mechanics . 19.5 Molecular Modeling. 19.6 The gui. 19.7 Finding
Thermodynamic Properties. 19.8 The Outside World. 19.9 Transition States.
Chapter 20. Quantum Molecular Modeling. 20.1 The Molecular Variational
Method. 20.2 The Hydrogen Molecule Ion. 20.3 Higher Molecular Orbital
Calculations . 20.4 Semiempirical Methods. 20.5 Ab Initio Methods. 20.6 The
Gaussian Basis Set. 20.7 Stored Parameters. 20.8 Molecular Orbitals. 20.9
Methane. 20.10 Split Valence Basis Sets. 20.11 Polarized Basis Functions.
20.12 Heteroatoms: Oxygen. 20.13 Finding of Methanol. 20.14 Further Basis
Set Improvements. 20.15 Post Hartree-Fock Calculations. 20.16 Perturbation.
20.17 Combined or Scripted Methods. 20.18 Density Functional Theory (DFT).
Chapter 21 Photochemistry and the Theory of Chemical Kinetics. 21.1
Einstein's Law. 21.2 Quantum Yields. 21.3 Bond Dissociation Energies (BDE).
21.4 Isodesmic Reactions. 21.5 The Eyring Theory of Reaction Rates. 21.6
The Potential Energy Surface. 21.7 Steady State Pseudo Equilibrium. 21.8
Entropies of Activation. 21.9 The Structure of the Activated Complex.