The field of unimolecular reaction has witnessed impressive advances in both experimental and theoretical techniques during the past 20 years. These developments have resulted in experimental measurements that finally permit critical test of the major assumptions made more than 60 years ago when Rice and Ramsperger and Kassel first proposed their statistical RRK theory of unimolecular decay.
The field of unimolecular reaction has witnessed impressive advances in both experimental and theoretical techniques during the past 20 years. These developments have resulted in experimental measurements that finally permit critical test of the major assumptions made more than 60 years ago when Rice and Ramsperger and Kassel first proposed their statistical RRK theory of unimolecular decay.
* 1.: Introduction * 2.: Vibrational/Rotational Energy Levels * 3.: Potential Energy Surfaces * 4.: State Preparation and Intramolecular Vibrational Energy Redistribution * 5.: Experimental Methods in Unimolecular Dissociation Studies * 6.7.: Theory of Unimolecular Decomposition - The Statistical ApproachApplications and Extensions of Statistical Theories * 8.: Dynamical Approaches * 9.: Product Energy Distributions * 10.: The Dissociation fo Small and Large Clusters * Appendix
* 1.: Introduction * 2.: Vibrational/Rotational Energy Levels * 3.: Potential Energy Surfaces * 4.: State Preparation and Intramolecular Vibrational Energy Redistribution * 5.: Experimental Methods in Unimolecular Dissociation Studies * 6.7.: Theory of Unimolecular Decomposition - The Statistical ApproachApplications and Extensions of Statistical Theories * 8.: Dynamical Approaches * 9.: Product Energy Distributions * 10.: The Dissociation fo Small and Large Clusters * Appendix
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