The Synthesis Of Metal Complexes With Macrocyclic Glyoxime Ether
Emin Karapinar
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The Synthesis Of Metal Complexes With Macrocyclic Glyoxime Ether

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In this work, by the reaction of four different chloroglyoximes with 4 -Amminobenzo[15-Crown-5] in absolute ethanol, eight of new macrocylic glyoxime ether compounds and their Ni(II), Co(II) and Cu(II) complexes have been synthesized. For this, firstly chlorophenylglyoxime, p-tolylchloroglyoxime, p-chlorophenyl chloroglyoxime and 4 -biphenylchloroglyoxime were synthesized according to previously reported literatures. Then novel glyoxime derivatives with macrocyclic glyoxime ethers by the reactions between these compounds with 4 -amminobenzo[15-crown-5] were obtained. The complexes of these lig...