Fiona M Gray

Solid Polymer Electrolytes

Fundamentals and Technological Applications

• Gebundenes Buch

Produktbeschreibung

Das Buch gibt eine umfassende Übersicht über den gegenwärtigen Stand des Gebietes Polymerelektrolyten. Theoretische Modelle und experimentelle Techniken, mit der diese Stoffklasse analysiert werden kann, werden beschrieben. Das Buch behandelt viele Aspekte des Themas: Batterien und andere Möglichkeiten zur Energiespeicherung sowie Methoden des Ladungstransports. Die Auswertung und Interpretation experimentell gewonnener Daten werden erläutert. Es dient sowohl als Einführung als auch als kritische Übersicht. Gerade im Hinblick auf zukünftige Energiegewinnung und -technik ist dieses Buch wichtig.

Produktdetails

• Verlag: John Wiley & Sons / Wiley
• Seitenzahl: 256
• Erscheinungstermin: 17. Dezember 1996
• Englisch
• Abmessung: 240mm x 161mm x 18mm
• Gewicht: 554g
• ISBN-13: 9780471187370
• ISBN-10: 0471187372
• Artikelnr.: 21373091

Autorenporträt

Fiona M. Gray is the author of Solid Polymer Electrolytes: Fundamentals and Technological Applications, published by Wiley.

Inhaltsangabe

2.2 Poly(ethylene imine). 2.3 Thia-alkanes. References. Chapter 3. The
Interaction Between Polymer and Salt. 3.1 Ion Solvation by the Polymer.
3.2. Hard-Soft Acid-Base Principle. 3.3. Artions. 3.4. Complex Formation.
References. Chapter 4. Structure and Morphology. 4.1 Crystalline Phases in
Polymers. 4.2 Preparation of Polymer Electrolyte Films. 4.3 Solvent
Deposited and Melt Recrystallized Films. 4.4 Solvent Effects on Morphology.
4.5 Trace Impurities. 4.6 Intercrystalline Amorphous Phases. 4.7 Polymer
Electrolyte Structural Determination by EXAFS. 4.8 Phase Diagrams. 4.8.1
Thiocyanates of Monovalent Cations. 4.8.2 Halide Systems. 4.8.3 Tetraphenyl
Borate Systems. 4.8.4 Halogen-Containing Complex Anionic Systems. 4.8.5
Perchlorate Systems. 4.8.6 Trifluoromethanesulfonate Systems. 4.9 Mesogenic
PEO-Salt Systems. References. Chapter 5. Aspects of Conductivity in Polymer
Electrolytes. 5.1 Total Direct-Current Conductivity. 5.1.1 Crystallinity in
Polymer Electrolytes. 5.1.2 Salt Concentration. 5.2 Pressure Dependence of
the Conductivity. 5.3 Mixed Salt Systems. 5.4 Mixed Conductors. References.
Chapter 6. Polymer Electrolyte Architecture. 6.1 Non-Ether-Based Polymer
Electrolytes. 6.2 Amorphous Polyether-Based Polymer Architecture. 6.3
Enhanced Chain Flexibility. 6.4 Mechanical Stability. 6.4.1 Networks. 6.4.2
Comb-Branched Copolymers. 6.4.3 Block Copolymers. 6.4.4 Random Polyethers.
6.5 Blends. 6.6 Single-Ion Conductors. 6.7 Salts. References. Chapter 7.
Further Developments in Polymer Electrolyte Materials. 7.1 Proton
Conductors. 7.1.1 Polyethers. 7.1.2 Polyamides. 7.1.3 Poly(acrylic acid).
7.1.4 Polyamines. 7.1.5 Poly(vinyl alcohol). 7.2 Ormocers. 7.2.1 The
Sol-Gel Process. 7.2.2 Ormolytes. 7.3 Multivalent Cation-Based Polymer
Electrolytes. 7.3.1 Preparation of Materials. 7.3.2 Physical Properties.
7.3.2.1 Alkaline Earth Metal Cations. 7.3.2.2 Zinc(II). 7.3.2.3
Cadmium(II). 7.3.2.4 Lead(II). 7.3.2.5 Cobalt(II), Nickel(II), and
Manganese(II). 7.3.2.6 Mercury(II). 7.3.2.7 Copper(II). 7.3.2.8 Trivalent
Cation-Containing Electrolytes. References. Chapter 8. Transport
Properties: Effects of Dynamic Disorder. 8.1 Macroscopic Models. 8.2
Microscopic Approach. 8.3 Experimental Techniques Relating to Microscopic
Dynamic Properties. 8.3.1 Brillouin Scattering. 8.3.2 Dielectric
Relaxation. 8.3.3 Nuclear Magnetic Resonance Spectroscopy. 8.3.4
Quasi-elastic Neutron Scattering. References. Chapter 9. Transport
Properties: Ionic Species and Mobility. 9.1 Ion-Ion Interactions. 9.2
Spectroscopic Studies. 9.2.1 General Interpretation of Spectral Data. 9.3
Transference Numbers. 9.3.1 Transport Numbers from Diffusion Coefficient
Determinations. 9.3.1.1 Radiotracer Studies. 9.3.1.2 Pulsed Field Gradient
NMR. 9.3.1.3 Electrochemical Determination of Diffusion Coefficients. 9.3.2
Measurement of the Transport of Charged Species Only. 9.3.2.1
Hittorf/Tubandt Method. 9.3.2.2 Concentration Cell Techniques. 9.3.2.3
Cells in Force Fields. 9.3.3 Transport under a Chemical Potential and
Electrical Gradient. 9.3.3.1 Alternating-Current Impedance. 9.3.3.2
Direct-Current Polarization Methods. Fully Dissociated Electrolytes.
Systems Containing Mobile Ion Pairs. Systems Containing Triple Ions.
References. Chapter 10. The Electrode-Electrolyte Interface. 10.1 The
Lithium-Polymer Electrolyte Interface. 10.2 Electrochemical Stability. 10.3
Intercalation. 10.4 Electrochromism of Intercalation Compounds. References.
Index.