This timely overview of silicon electrochemistry and surface modification covers current approaches for the production of photovoltaic-grade silicon materials, including innovative molten-salt methods.
This timely overview of silicon electrochemistry and surface modification covers current approaches for the production of photovoltaic-grade silicon materials, including innovative molten-salt methods.
Professor Eimutis Juzeliunas is the principal research associate and head of the Department of Electrochemical Materials Science at the Centre for Physical Sciences and Technology in Vilnius, Lithuania. Prior to these positions, he was the rector of Klaipeda University (2014-2018) and the director of the Institute of Chemistry (2001-2009) in Lithuania. From 2009 to 2014, he was a Marie Curie Intra-European and International fellow at the University of Cambridge, UK. His main research topics include: electrochemical materials science, silicon electrochemistry for energy applications, corrosion of metals, surface technologies. He published 116 papers in peer-reviewedjournals, holds two patents and reported orally in 40 international conferences. He received research fellowships from the Alexander von Humboldt Foundation (DECHEMA, Germany 1995-1997), the American Chemical Society (Pennsylvania StateUniversity, USA 2001-2002), the Fulbright Programme (Vanderbilt University, USA 2009-2010) and the Commission of the European Communities, Marie Curie actions (the University of Cambridge, UK 2009-2010; 2013-2014).
Inhaltsangabe
1. Introduction 2. Silicon Electrochemistry: Towards a Low-Carbon Economy 3. Historcal Overview of Silicon Production 4. Physical and Chemical Properties of Silicon 5. Refining of Silicon: From Metallurgical-Grade to Electronic-Grade 6. Silicon Electrowinning and Electrodeposition of Thin Layers 7.Photoelectrochemistry and Nanogravimetry of Si and Si-oxide Electrodes 8. Electro-deoxidation of Solid Compounds in Molten Salts 9. Voltammetry and Basic Reactions of Silicon Electrode in Molten CaCl2 10. Si-SiO2 Electrode in Molten CaCl2 11. Formation of Silicon Oxide Layer 12. In situ Studies of SiO2 to Si Conversion 13. Molten Oxide Electrochemistry at Ultra-High Temperatures 14. Silicon Surface Structuring 15. Electrochemical Si Surface Structuring and Formation of Black Si in High Temperature Molten Salts 16. Silicon Compositions: Perspectives for Semiconductor Production 17. Silicon Photo-Electrodes for Water Splitting and Their Protection 18. Conclusion, Outlook, Challenges
1. Introduction 2. Silicon Electrochemistry: Towards a Low-Carbon Economy 3. Historcal Overview of Silicon Production 4. Physical and Chemical Properties of Silicon 5. Refining of Silicon: From Metallurgical-Grade to Electronic-Grade 6. Silicon Electrowinning and Electrodeposition of Thin Layers 7.Photoelectrochemistry and Nanogravimetry of Si and Si-oxide Electrodes 8. Electro-deoxidation of Solid Compounds in Molten Salts 9. Voltammetry and Basic Reactions of Silicon Electrode in Molten CaCl2 10. Si-SiO2 Electrode in Molten CaCl2 11. Formation of Silicon Oxide Layer 12. In situ Studies of SiO2 to Si Conversion 13. Molten Oxide Electrochemistry at Ultra-High Temperatures 14. Silicon Surface Structuring 15. Electrochemical Si Surface Structuring and Formation of Black Si in High Temperature Molten Salts 16. Silicon Compositions: Perspectives for Semiconductor Production 17. Silicon Photo-Electrodes for Water Splitting and Their Protection 18. Conclusion, Outlook, Challenges
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