- Gebundenes Buch
- Merkliste
- Auf die Merkliste
- Bewerten Bewerten
- Teilen
- Produkt teilen
- Produkterinnerung
- Produkterinnerung
The current volume continues the tradition of the Organic Synthesis series, providing carefully checked and edited experimental procedures that describe important synthetic methods, transformations, reagents, and synthetic building blocks or intermediates with demonstrated utility in organic synthesis. These significant and interesting procedures should prove worthwhile to many synthetic chemists working in increasingly diverse areas. A trusted guide for professionals in organic and medicinal chemistry in academia, government, and industries, including phar-maceuticals, fine chemicals, agrochemicals, and biotech.…mehr
Andere Kunden interessierten sich auch für
- William R. Roush (Hrsg.)Organic Syntheses, Volume 78148,99 €
- Peter J. H. ScottSolid-Phase Organic Syntheses, Volume 2187,99 €
- Tse-Lok HoFiesers' Reagents for Organic Synthesis, Volume 19266,99 €
- Tse-Lok HoFiesers' Reagents for Organic Synthesis, Volume 18270,99 €
- Robert M. CoatesHandbook of Reagents for Organic Synthesis, 4 Volume Set1.177,99 €
- Larry E. Overman (Hrsg.)Organic Reactions, Volume 60259,99 €
- Tse-Lok HoFiesers' Reagents for Organic Synthesis, Volume 21266,99 €
-
-
-
The current volume continues the tradition of the Organic Synthesis series, providing carefully checked and edited experimental procedures that describe important synthetic methods, transformations, reagents, and synthetic building blocks or intermediates with demonstrated utility in organic synthesis. These significant and interesting procedures should prove worthwhile to many synthetic chemists working in increasingly diverse areas. A trusted guide for professionals in organic and medicinal chemistry in academia, government, and industries, including phar-maceuticals, fine chemicals, agrochemicals, and biotech.
Produktdetails
- Produktdetails
- Organic Syntheses .88
- Verlag: Wiley & Sons
- 1. Auflage
- Seitenzahl: 528
- Erscheinungstermin: 13. Dezember 2011
- Englisch
- Abmessung: 229mm x 155mm x 30mm
- Gewicht: 821g
- ISBN-13: 9781118173978
- ISBN-10: 111817397X
- Artikelnr.: 34448319
- Organic Syntheses .88
- Verlag: Wiley & Sons
- 1. Auflage
- Seitenzahl: 528
- Erscheinungstermin: 13. Dezember 2011
- Englisch
- Abmessung: 229mm x 155mm x 30mm
- Gewicht: 821g
- ISBN-13: 9781118173978
- ISBN-10: 111817397X
- Artikelnr.: 34448319
Jonathan A. Ellman is Eugene Higgins Professor of Chemistry at Yale University. He received his B.S. in Chemistry from MIT and his PhD in Organic Chemistry from Harvard University. His research efforts are focused on the development of efficient, systematic chemical tools to establish protein function through the design and synthesis of small molecule libraries targeting protein families, methods for the asymmetric synthesis of amines, and the development of synthetic applications of C-H activation.
Editorial: Organic Syntheses: The "Gold Standard" for Experimental Synthetic Organic Chemistry 1 Rick L. Danheiser ±
Arylation of Esters Catalyzed by the Pd(I) Dimer [P(t
Bu)3Pd(µ
Br)] 4 David S. Huang, Ryan J. DeLuca, and John F. Hartwig The Preparation of Amides by Copper
medicated Oxidative Coupling of Aldehydes and Amine Hydrochloride Salts 14 Maxime Giguère
Bisson, Woo
Jin Yoo, and Chao
Jun Li Synthesis of 2
Aryl Pyridines by Palladium
Catalyzed Direct Arylation of Pyridine N
Oxides 22 Louis
Charles Campeau and Keith Fagnou The Preparation of Indazoles via Metal Free Intramolecular Electrophilic Animation of 2
Aminophenyl Ketoximes 33 Carla M. Councellar, Chad C. Eichman, Brenda C. Wray, Eric R. Welin, and James P. Stambuli The Preparation of (2R,5S)
2
t
Butyl
3,5
Dimethylimidazolidin
4
One 42 Thomas H. Graham, Benjamin D. Horning, and David W. C. MacMillan Synthesis of Et2SB*SbCl5Br and Its Use in Biomimetic Brominative Polyene Cyclizations 54 Scott A. Snyder and Daniel S. Treitler Discussion Addendum for: Asymmetric Synthesis of (M)
2
Hydroxymethyl
1
(2
Hydroxy
3,6
Dimethylphenyl)Naphthalene via a Configurationally Unstable Biaryl Lactone 70 G. Bringmann, T. A. M. Gulder, and T. Gulder Synthesis of Lithium 2
Pyridyltriolborate and Its Cross
Coupling Reaction with Aryl Halides 79 Yasunori Yamamoto, Juugaku Sigai, Miho Takizawa, and Norio Miyaura Synthesis of (+)
B
Allyldiisopinocampheylborane and It Reaction with Aldehydes 87 Huikai Sun and William R. Roush Discussion Addendum for: Palladium
Catalyzed Cross
Coupling of (Z)
1
Heptenyldimethylsilanol with 4
Iodoanisole: (Z)
(1
Heptenyl)
4
Methoxybenzene 102 Scott E. Denmark and Jack Hung
Chang Liu The Preparation of Cyclohept
4
Enones by Rhodium
Catalyzed Intermolecular [5+2] Cycloaddition 109 Paul A. Wender, Adam B. Lesser, and Lauren E. Sirois Organocatalytic Enantioselective Synthesis of Bicyclic ß
Lactones from Aldehyde Acids via Nucleophile
Catalyzed Aldol
Lactonization (NCAL) 121 Henry Nguyen, Seongho Oh, Huda Henry
Riyad, Diana Sepulveda, and Daniel Romo Phosphine
Catalyzed [3 + 2) Annulation: Synthesis of Ethyl 5
(tert
Butyl)
2
Phenyl
1
Tosyl
3
Pyrroline
3
Carboxylate 138 Ian P. Andrews and Ohyun Kwon Preparation of Horner
Wadsworth
Emmons Reagent: Methyl 2
Benzyloxycarbonylamino
2
(Dimethoxy
Phosphinyl)Acetate 152 Hiroki Azuma, Kentaro Okano, Tohru Fukuyama, and Hidetoshi Tokuyama Discussion Addendum for: 5
ENDO
TRIG Cyclization of 1,1
Difluoro
1
Alkenes: Synthesis of 3
Butyl
2
Fluoro
1
Tosylindole (1H
Indole, 3
Butyl
2
Fluoro
1
[(4
Methylphenyl)Sulfonyl
) 162 Junji Ichikawa Preparation of a Thrifluoromethyl Transfer Agent: 1
Trifloromethyl
1,3
Dihydro
3,3
Dimenthyl
1,2
Benziodoxole 168 Patrick Eisenberger, Iris Kieltsch, Raffael Koller, Kyrill Stanek, and Antonio Tongni Synthesis of (S,S)
Diisopropyl Tartrate (E)
Crothylboronate and Its Reaction with Aldehydes: (2R,3R,4R)
1,2
Dideoxy
2
Ethenyl
4,5,
O
(1
Methylethylidene)
Xylitol 181 Huikai Sun and William R. Roush Discussion Addendum for: 4
Methoxy
4'
Nitrophenyl. Recent Advances in the Stille Biaryl Coupling Reaction and Applications in Complex Natural Products Synthesis 197 Robert M. Williams Discussion Addendum for: Palladium
Catalyzed Reaction of 1
Alkenylboronates with Vinylic Halides: (1Z,3E)
1
Phenyl
1,3
Octadiene 202 Norio Miyaura Discussion Addendum for: Palladium (0)
Catalyzed Reaction of 9
Alkyl
9
Borabicyclo[3.3.1]Nonane with 1
Bromo
1
Phenylthioethene: 4
(3
Cyclohexenyl )
2
Phenylthio
1
1
Butene 207 Norio Miyaura Preparation of Isopropyl 2
Diazoacetyl(Phenyl)Carbamate 212 Hubert Muchalski, Amanda B. Doody, Timothy L. Troyer, and Jeffrey N. Johnson Gram Scale Catalytic Asymmetric Aziridination: Preparation of (2R,3R)
Ethyl 1
Benzhydryl
3
(4
Bromopheneyl)Aziridine 2
Carboxylate 224 Aman A. Desai, Roberto Morán
Ramallal, and William D. Wulff Cu
Catalyzed Azide
Alkyne Cycloaddition: Preparation of Tris((1
Benzyl
1H
1,2,3
Triazolyl )Methyl)Amine 238 Jason E. Hein, Larissa B. Krasnova, Masayuki Iwasaki, and Valery V. Fokin Lithiated Primary Alkyl Carbamates for the Homologation of Boronic Esters Matthew P. Webster, Benjamin M. Partridge, and Varinder K. Aggarwal Discussion Addendum for: Palladium
Catalyzed Reduction of Vinyl Trifluoromethanesulfonates to Alkenes: Cholesta
3,5
Diene 260 Sandro Cacchi, Enrico Morera, and Giorgio Ortar Discussion Addendum for: Synthesis of Indoles by Palladium
Catalyzed Reductive N
Heteroannulation of 2
Nitrostyrenes: Methyl Indole
4
Carboxylate 291 Björn C. Söderberg An Economical Synthesis of 4
Trimethysilyl
2
Butyn
1
OL 296 Alexander N. Wein, Rongbiao Tong, and Frank E. McDonald Silver
Catalyzed Rearrangement of Propargylic Sulfinates: Synthesis of Allengic Sulfones 309 Michael Harmata, Zhengxin Cai and Chaofeng Huang (Sa,S)
N
[2'
(Methylphenylsulfonamido)
1
1'
Binaphthyl
2
YL]Pyrrolidine
2
Carboxamide: An Organocatalyst for the Direct Aldol Reaction 317 Santiago F. Viózquez, Gabriela Guillene, Carmen Nájera, Ben Bradshaw, Gorka Etxebarria
Jardi, and Josep Bonjoch Synthesis of (S)
8a
Methyl
3,4,8,8a
Tetrahydro
1,6
(2H,7H)
Naphthalenedione via N
Tosyl
(Sa)
Binam
L
Pholinamide Organocatalysis 330 Ben Bradshaw, Gorka Etxebarria
Jardi, Josep Bonjoch, Santiago F. Viózquez, Gabriela Guillena, and Carmen Nájera Stereoselective Nickel
Catalyzed 1,4
Hydroboration of 1,3
Dienes 342 Robert J. Ely and James P. Morken Tandem Nucleophilic Addition/Fragmentation of Vinylogous Acyl Triflates: 2
Methyl
2
(1
Oxo
5
Heptynyl)
1
3
Dithiane 353 Marilda P. Lisboa, Tunf T. Hoang, and Gregory B. Dudley Synthesis and Diasteroselective Aldol Reactions of a Thiazolidinethione Chiral Auxiliary 364 Michael T. Crimmins, Hamish S. Christie, and Colin O. Hughes Synthesis of 2,3
Disubstituted Indoles via Palladium
Catalyzed Annulation of Internal Alkynes: 3
Methyl
2
(Trimethylsilyl)Indole 377 Yu Chen, Nataliya A. Markina, Tuanli Yao, and Richard C. Larock An Intramolecular Amination of Aryyl Halides with a Combination of Copper (I) and Cesium Acetate: Preparation of 5,6
Dimethoxyindole
1,2
Dicarboxylic Acid 1
Benzyl Ester 2
Methyl Ester 388 Toshiharu Noji, Kentaro Okano, Tohru Fukuyama, and Hidetoshi Tokuyama Ligand
Free Copper(II) Oxide Nanoparticles
Catalyzed Synthesis of Substituted Benzoxazoles 398 Prasenjit Saha, Md Ashif Ali, and Tharmalingam Punniyamurthy (R)
3,3'
Bis(9
Phenanthyryl)
1,1'
Binaphthalene
2,2'
Diyl Hydrogen Phosphate 406 Wenhao Hu, Jing Zhou, Xinfang Xu, Weijun Liu, and Liuzhu Gong Enantioselective Three
Component Reaction for the Preparation of ß
Amino
a
Hydroxy Esters 418 Jing Zhou, Xinfang Xu, and Wenhao Hu Mild Conversion of Tertiary Amides to Aldehydes Using Cp2Zr(H)Cl (Schwartz's Reagent) 427 Matthew W. Leighty, Jared T. Spletstoser, and Gunda I. Georg
Arylation of Esters Catalyzed by the Pd(I) Dimer [P(t
Bu)3Pd(µ
Br)] 4 David S. Huang, Ryan J. DeLuca, and John F. Hartwig The Preparation of Amides by Copper
medicated Oxidative Coupling of Aldehydes and Amine Hydrochloride Salts 14 Maxime Giguère
Bisson, Woo
Jin Yoo, and Chao
Jun Li Synthesis of 2
Aryl Pyridines by Palladium
Catalyzed Direct Arylation of Pyridine N
Oxides 22 Louis
Charles Campeau and Keith Fagnou The Preparation of Indazoles via Metal Free Intramolecular Electrophilic Animation of 2
Aminophenyl Ketoximes 33 Carla M. Councellar, Chad C. Eichman, Brenda C. Wray, Eric R. Welin, and James P. Stambuli The Preparation of (2R,5S)
2
t
Butyl
3,5
Dimethylimidazolidin
4
One 42 Thomas H. Graham, Benjamin D. Horning, and David W. C. MacMillan Synthesis of Et2SB*SbCl5Br and Its Use in Biomimetic Brominative Polyene Cyclizations 54 Scott A. Snyder and Daniel S. Treitler Discussion Addendum for: Asymmetric Synthesis of (M)
2
Hydroxymethyl
1
(2
Hydroxy
3,6
Dimethylphenyl)Naphthalene via a Configurationally Unstable Biaryl Lactone 70 G. Bringmann, T. A. M. Gulder, and T. Gulder Synthesis of Lithium 2
Pyridyltriolborate and Its Cross
Coupling Reaction with Aryl Halides 79 Yasunori Yamamoto, Juugaku Sigai, Miho Takizawa, and Norio Miyaura Synthesis of (+)
B
Allyldiisopinocampheylborane and It Reaction with Aldehydes 87 Huikai Sun and William R. Roush Discussion Addendum for: Palladium
Catalyzed Cross
Coupling of (Z)
1
Heptenyldimethylsilanol with 4
Iodoanisole: (Z)
(1
Heptenyl)
4
Methoxybenzene 102 Scott E. Denmark and Jack Hung
Chang Liu The Preparation of Cyclohept
4
Enones by Rhodium
Catalyzed Intermolecular [5+2] Cycloaddition 109 Paul A. Wender, Adam B. Lesser, and Lauren E. Sirois Organocatalytic Enantioselective Synthesis of Bicyclic ß
Lactones from Aldehyde Acids via Nucleophile
Catalyzed Aldol
Lactonization (NCAL) 121 Henry Nguyen, Seongho Oh, Huda Henry
Riyad, Diana Sepulveda, and Daniel Romo Phosphine
Catalyzed [3 + 2) Annulation: Synthesis of Ethyl 5
(tert
Butyl)
2
Phenyl
1
Tosyl
3
Pyrroline
3
Carboxylate 138 Ian P. Andrews and Ohyun Kwon Preparation of Horner
Wadsworth
Emmons Reagent: Methyl 2
Benzyloxycarbonylamino
2
(Dimethoxy
Phosphinyl)Acetate 152 Hiroki Azuma, Kentaro Okano, Tohru Fukuyama, and Hidetoshi Tokuyama Discussion Addendum for: 5
ENDO
TRIG Cyclization of 1,1
Difluoro
1
Alkenes: Synthesis of 3
Butyl
2
Fluoro
1
Tosylindole (1H
Indole, 3
Butyl
2
Fluoro
1
[(4
Methylphenyl)Sulfonyl
) 162 Junji Ichikawa Preparation of a Thrifluoromethyl Transfer Agent: 1
Trifloromethyl
1,3
Dihydro
3,3
Dimenthyl
1,2
Benziodoxole 168 Patrick Eisenberger, Iris Kieltsch, Raffael Koller, Kyrill Stanek, and Antonio Tongni Synthesis of (S,S)
Diisopropyl Tartrate (E)
Crothylboronate and Its Reaction with Aldehydes: (2R,3R,4R)
1,2
Dideoxy
2
Ethenyl
4,5,
O
(1
Methylethylidene)
Xylitol 181 Huikai Sun and William R. Roush Discussion Addendum for: 4
Methoxy
4'
Nitrophenyl. Recent Advances in the Stille Biaryl Coupling Reaction and Applications in Complex Natural Products Synthesis 197 Robert M. Williams Discussion Addendum for: Palladium
Catalyzed Reaction of 1
Alkenylboronates with Vinylic Halides: (1Z,3E)
1
Phenyl
1,3
Octadiene 202 Norio Miyaura Discussion Addendum for: Palladium (0)
Catalyzed Reaction of 9
Alkyl
9
Borabicyclo[3.3.1]Nonane with 1
Bromo
1
Phenylthioethene: 4
(3
Cyclohexenyl )
2
Phenylthio
1
1
Butene 207 Norio Miyaura Preparation of Isopropyl 2
Diazoacetyl(Phenyl)Carbamate 212 Hubert Muchalski, Amanda B. Doody, Timothy L. Troyer, and Jeffrey N. Johnson Gram Scale Catalytic Asymmetric Aziridination: Preparation of (2R,3R)
Ethyl 1
Benzhydryl
3
(4
Bromopheneyl)Aziridine 2
Carboxylate 224 Aman A. Desai, Roberto Morán
Ramallal, and William D. Wulff Cu
Catalyzed Azide
Alkyne Cycloaddition: Preparation of Tris((1
Benzyl
1H
1,2,3
Triazolyl )Methyl)Amine 238 Jason E. Hein, Larissa B. Krasnova, Masayuki Iwasaki, and Valery V. Fokin Lithiated Primary Alkyl Carbamates for the Homologation of Boronic Esters Matthew P. Webster, Benjamin M. Partridge, and Varinder K. Aggarwal Discussion Addendum for: Palladium
Catalyzed Reduction of Vinyl Trifluoromethanesulfonates to Alkenes: Cholesta
3,5
Diene 260 Sandro Cacchi, Enrico Morera, and Giorgio Ortar Discussion Addendum for: Synthesis of Indoles by Palladium
Catalyzed Reductive N
Heteroannulation of 2
Nitrostyrenes: Methyl Indole
4
Carboxylate 291 Björn C. Söderberg An Economical Synthesis of 4
Trimethysilyl
2
Butyn
1
OL 296 Alexander N. Wein, Rongbiao Tong, and Frank E. McDonald Silver
Catalyzed Rearrangement of Propargylic Sulfinates: Synthesis of Allengic Sulfones 309 Michael Harmata, Zhengxin Cai and Chaofeng Huang (Sa,S)
N
[2'
(Methylphenylsulfonamido)
1
1'
Binaphthyl
2
YL]Pyrrolidine
2
Carboxamide: An Organocatalyst for the Direct Aldol Reaction 317 Santiago F. Viózquez, Gabriela Guillene, Carmen Nájera, Ben Bradshaw, Gorka Etxebarria
Jardi, and Josep Bonjoch Synthesis of (S)
8a
Methyl
3,4,8,8a
Tetrahydro
1,6
(2H,7H)
Naphthalenedione via N
Tosyl
(Sa)
Binam
L
Pholinamide Organocatalysis 330 Ben Bradshaw, Gorka Etxebarria
Jardi, Josep Bonjoch, Santiago F. Viózquez, Gabriela Guillena, and Carmen Nájera Stereoselective Nickel
Catalyzed 1,4
Hydroboration of 1,3
Dienes 342 Robert J. Ely and James P. Morken Tandem Nucleophilic Addition/Fragmentation of Vinylogous Acyl Triflates: 2
Methyl
2
(1
Oxo
5
Heptynyl)
1
3
Dithiane 353 Marilda P. Lisboa, Tunf T. Hoang, and Gregory B. Dudley Synthesis and Diasteroselective Aldol Reactions of a Thiazolidinethione Chiral Auxiliary 364 Michael T. Crimmins, Hamish S. Christie, and Colin O. Hughes Synthesis of 2,3
Disubstituted Indoles via Palladium
Catalyzed Annulation of Internal Alkynes: 3
Methyl
2
(Trimethylsilyl)Indole 377 Yu Chen, Nataliya A. Markina, Tuanli Yao, and Richard C. Larock An Intramolecular Amination of Aryyl Halides with a Combination of Copper (I) and Cesium Acetate: Preparation of 5,6
Dimethoxyindole
1,2
Dicarboxylic Acid 1
Benzyl Ester 2
Methyl Ester 388 Toshiharu Noji, Kentaro Okano, Tohru Fukuyama, and Hidetoshi Tokuyama Ligand
Free Copper(II) Oxide Nanoparticles
Catalyzed Synthesis of Substituted Benzoxazoles 398 Prasenjit Saha, Md Ashif Ali, and Tharmalingam Punniyamurthy (R)
3,3'
Bis(9
Phenanthyryl)
1,1'
Binaphthalene
2,2'
Diyl Hydrogen Phosphate 406 Wenhao Hu, Jing Zhou, Xinfang Xu, Weijun Liu, and Liuzhu Gong Enantioselective Three
Component Reaction for the Preparation of ß
Amino
a
Hydroxy Esters 418 Jing Zhou, Xinfang Xu, and Wenhao Hu Mild Conversion of Tertiary Amides to Aldehydes Using Cp2Zr(H)Cl (Schwartz's Reagent) 427 Matthew W. Leighty, Jared T. Spletstoser, and Gunda I. Georg
Editorial: Organic Syntheses: The "Gold Standard" for Experimental Synthetic Organic Chemistry 1 Rick L. Danheiser ±
Arylation of Esters Catalyzed by the Pd(I) Dimer [P(t
Bu)3Pd(µ
Br)] 4 David S. Huang, Ryan J. DeLuca, and John F. Hartwig The Preparation of Amides by Copper
medicated Oxidative Coupling of Aldehydes and Amine Hydrochloride Salts 14 Maxime Giguère
Bisson, Woo
Jin Yoo, and Chao
Jun Li Synthesis of 2
Aryl Pyridines by Palladium
Catalyzed Direct Arylation of Pyridine N
Oxides 22 Louis
Charles Campeau and Keith Fagnou The Preparation of Indazoles via Metal Free Intramolecular Electrophilic Animation of 2
Aminophenyl Ketoximes 33 Carla M. Councellar, Chad C. Eichman, Brenda C. Wray, Eric R. Welin, and James P. Stambuli The Preparation of (2R,5S)
2
t
Butyl
3,5
Dimethylimidazolidin
4
One 42 Thomas H. Graham, Benjamin D. Horning, and David W. C. MacMillan Synthesis of Et2SB*SbCl5Br and Its Use in Biomimetic Brominative Polyene Cyclizations 54 Scott A. Snyder and Daniel S. Treitler Discussion Addendum for: Asymmetric Synthesis of (M)
2
Hydroxymethyl
1
(2
Hydroxy
3,6
Dimethylphenyl)Naphthalene via a Configurationally Unstable Biaryl Lactone 70 G. Bringmann, T. A. M. Gulder, and T. Gulder Synthesis of Lithium 2
Pyridyltriolborate and Its Cross
Coupling Reaction with Aryl Halides 79 Yasunori Yamamoto, Juugaku Sigai, Miho Takizawa, and Norio Miyaura Synthesis of (+)
B
Allyldiisopinocampheylborane and It Reaction with Aldehydes 87 Huikai Sun and William R. Roush Discussion Addendum for: Palladium
Catalyzed Cross
Coupling of (Z)
1
Heptenyldimethylsilanol with 4
Iodoanisole: (Z)
(1
Heptenyl)
4
Methoxybenzene 102 Scott E. Denmark and Jack Hung
Chang Liu The Preparation of Cyclohept
4
Enones by Rhodium
Catalyzed Intermolecular [5+2] Cycloaddition 109 Paul A. Wender, Adam B. Lesser, and Lauren E. Sirois Organocatalytic Enantioselective Synthesis of Bicyclic ß
Lactones from Aldehyde Acids via Nucleophile
Catalyzed Aldol
Lactonization (NCAL) 121 Henry Nguyen, Seongho Oh, Huda Henry
Riyad, Diana Sepulveda, and Daniel Romo Phosphine
Catalyzed [3 + 2) Annulation: Synthesis of Ethyl 5
(tert
Butyl)
2
Phenyl
1
Tosyl
3
Pyrroline
3
Carboxylate 138 Ian P. Andrews and Ohyun Kwon Preparation of Horner
Wadsworth
Emmons Reagent: Methyl 2
Benzyloxycarbonylamino
2
(Dimethoxy
Phosphinyl)Acetate 152 Hiroki Azuma, Kentaro Okano, Tohru Fukuyama, and Hidetoshi Tokuyama Discussion Addendum for: 5
ENDO
TRIG Cyclization of 1,1
Difluoro
1
Alkenes: Synthesis of 3
Butyl
2
Fluoro
1
Tosylindole (1H
Indole, 3
Butyl
2
Fluoro
1
[(4
Methylphenyl)Sulfonyl
) 162 Junji Ichikawa Preparation of a Thrifluoromethyl Transfer Agent: 1
Trifloromethyl
1,3
Dihydro
3,3
Dimenthyl
1,2
Benziodoxole 168 Patrick Eisenberger, Iris Kieltsch, Raffael Koller, Kyrill Stanek, and Antonio Tongni Synthesis of (S,S)
Diisopropyl Tartrate (E)
Crothylboronate and Its Reaction with Aldehydes: (2R,3R,4R)
1,2
Dideoxy
2
Ethenyl
4,5,
O
(1
Methylethylidene)
Xylitol 181 Huikai Sun and William R. Roush Discussion Addendum for: 4
Methoxy
4'
Nitrophenyl. Recent Advances in the Stille Biaryl Coupling Reaction and Applications in Complex Natural Products Synthesis 197 Robert M. Williams Discussion Addendum for: Palladium
Catalyzed Reaction of 1
Alkenylboronates with Vinylic Halides: (1Z,3E)
1
Phenyl
1,3
Octadiene 202 Norio Miyaura Discussion Addendum for: Palladium (0)
Catalyzed Reaction of 9
Alkyl
9
Borabicyclo[3.3.1]Nonane with 1
Bromo
1
Phenylthioethene: 4
(3
Cyclohexenyl )
2
Phenylthio
1
1
Butene 207 Norio Miyaura Preparation of Isopropyl 2
Diazoacetyl(Phenyl)Carbamate 212 Hubert Muchalski, Amanda B. Doody, Timothy L. Troyer, and Jeffrey N. Johnson Gram Scale Catalytic Asymmetric Aziridination: Preparation of (2R,3R)
Ethyl 1
Benzhydryl
3
(4
Bromopheneyl)Aziridine 2
Carboxylate 224 Aman A. Desai, Roberto Morán
Ramallal, and William D. Wulff Cu
Catalyzed Azide
Alkyne Cycloaddition: Preparation of Tris((1
Benzyl
1H
1,2,3
Triazolyl )Methyl)Amine 238 Jason E. Hein, Larissa B. Krasnova, Masayuki Iwasaki, and Valery V. Fokin Lithiated Primary Alkyl Carbamates for the Homologation of Boronic Esters Matthew P. Webster, Benjamin M. Partridge, and Varinder K. Aggarwal Discussion Addendum for: Palladium
Catalyzed Reduction of Vinyl Trifluoromethanesulfonates to Alkenes: Cholesta
3,5
Diene 260 Sandro Cacchi, Enrico Morera, and Giorgio Ortar Discussion Addendum for: Synthesis of Indoles by Palladium
Catalyzed Reductive N
Heteroannulation of 2
Nitrostyrenes: Methyl Indole
4
Carboxylate 291 Björn C. Söderberg An Economical Synthesis of 4
Trimethysilyl
2
Butyn
1
OL 296 Alexander N. Wein, Rongbiao Tong, and Frank E. McDonald Silver
Catalyzed Rearrangement of Propargylic Sulfinates: Synthesis of Allengic Sulfones 309 Michael Harmata, Zhengxin Cai and Chaofeng Huang (Sa,S)
N
[2'
(Methylphenylsulfonamido)
1
1'
Binaphthyl
2
YL]Pyrrolidine
2
Carboxamide: An Organocatalyst for the Direct Aldol Reaction 317 Santiago F. Viózquez, Gabriela Guillene, Carmen Nájera, Ben Bradshaw, Gorka Etxebarria
Jardi, and Josep Bonjoch Synthesis of (S)
8a
Methyl
3,4,8,8a
Tetrahydro
1,6
(2H,7H)
Naphthalenedione via N
Tosyl
(Sa)
Binam
L
Pholinamide Organocatalysis 330 Ben Bradshaw, Gorka Etxebarria
Jardi, Josep Bonjoch, Santiago F. Viózquez, Gabriela Guillena, and Carmen Nájera Stereoselective Nickel
Catalyzed 1,4
Hydroboration of 1,3
Dienes 342 Robert J. Ely and James P. Morken Tandem Nucleophilic Addition/Fragmentation of Vinylogous Acyl Triflates: 2
Methyl
2
(1
Oxo
5
Heptynyl)
1
3
Dithiane 353 Marilda P. Lisboa, Tunf T. Hoang, and Gregory B. Dudley Synthesis and Diasteroselective Aldol Reactions of a Thiazolidinethione Chiral Auxiliary 364 Michael T. Crimmins, Hamish S. Christie, and Colin O. Hughes Synthesis of 2,3
Disubstituted Indoles via Palladium
Catalyzed Annulation of Internal Alkynes: 3
Methyl
2
(Trimethylsilyl)Indole 377 Yu Chen, Nataliya A. Markina, Tuanli Yao, and Richard C. Larock An Intramolecular Amination of Aryyl Halides with a Combination of Copper (I) and Cesium Acetate: Preparation of 5,6
Dimethoxyindole
1,2
Dicarboxylic Acid 1
Benzyl Ester 2
Methyl Ester 388 Toshiharu Noji, Kentaro Okano, Tohru Fukuyama, and Hidetoshi Tokuyama Ligand
Free Copper(II) Oxide Nanoparticles
Catalyzed Synthesis of Substituted Benzoxazoles 398 Prasenjit Saha, Md Ashif Ali, and Tharmalingam Punniyamurthy (R)
3,3'
Bis(9
Phenanthyryl)
1,1'
Binaphthalene
2,2'
Diyl Hydrogen Phosphate 406 Wenhao Hu, Jing Zhou, Xinfang Xu, Weijun Liu, and Liuzhu Gong Enantioselective Three
Component Reaction for the Preparation of ß
Amino
a
Hydroxy Esters 418 Jing Zhou, Xinfang Xu, and Wenhao Hu Mild Conversion of Tertiary Amides to Aldehydes Using Cp2Zr(H)Cl (Schwartz's Reagent) 427 Matthew W. Leighty, Jared T. Spletstoser, and Gunda I. Georg
Arylation of Esters Catalyzed by the Pd(I) Dimer [P(t
Bu)3Pd(µ
Br)] 4 David S. Huang, Ryan J. DeLuca, and John F. Hartwig The Preparation of Amides by Copper
medicated Oxidative Coupling of Aldehydes and Amine Hydrochloride Salts 14 Maxime Giguère
Bisson, Woo
Jin Yoo, and Chao
Jun Li Synthesis of 2
Aryl Pyridines by Palladium
Catalyzed Direct Arylation of Pyridine N
Oxides 22 Louis
Charles Campeau and Keith Fagnou The Preparation of Indazoles via Metal Free Intramolecular Electrophilic Animation of 2
Aminophenyl Ketoximes 33 Carla M. Councellar, Chad C. Eichman, Brenda C. Wray, Eric R. Welin, and James P. Stambuli The Preparation of (2R,5S)
2
t
Butyl
3,5
Dimethylimidazolidin
4
One 42 Thomas H. Graham, Benjamin D. Horning, and David W. C. MacMillan Synthesis of Et2SB*SbCl5Br and Its Use in Biomimetic Brominative Polyene Cyclizations 54 Scott A. Snyder and Daniel S. Treitler Discussion Addendum for: Asymmetric Synthesis of (M)
2
Hydroxymethyl
1
(2
Hydroxy
3,6
Dimethylphenyl)Naphthalene via a Configurationally Unstable Biaryl Lactone 70 G. Bringmann, T. A. M. Gulder, and T. Gulder Synthesis of Lithium 2
Pyridyltriolborate and Its Cross
Coupling Reaction with Aryl Halides 79 Yasunori Yamamoto, Juugaku Sigai, Miho Takizawa, and Norio Miyaura Synthesis of (+)
B
Allyldiisopinocampheylborane and It Reaction with Aldehydes 87 Huikai Sun and William R. Roush Discussion Addendum for: Palladium
Catalyzed Cross
Coupling of (Z)
1
Heptenyldimethylsilanol with 4
Iodoanisole: (Z)
(1
Heptenyl)
4
Methoxybenzene 102 Scott E. Denmark and Jack Hung
Chang Liu The Preparation of Cyclohept
4
Enones by Rhodium
Catalyzed Intermolecular [5+2] Cycloaddition 109 Paul A. Wender, Adam B. Lesser, and Lauren E. Sirois Organocatalytic Enantioselective Synthesis of Bicyclic ß
Lactones from Aldehyde Acids via Nucleophile
Catalyzed Aldol
Lactonization (NCAL) 121 Henry Nguyen, Seongho Oh, Huda Henry
Riyad, Diana Sepulveda, and Daniel Romo Phosphine
Catalyzed [3 + 2) Annulation: Synthesis of Ethyl 5
(tert
Butyl)
2
Phenyl
1
Tosyl
3
Pyrroline
3
Carboxylate 138 Ian P. Andrews and Ohyun Kwon Preparation of Horner
Wadsworth
Emmons Reagent: Methyl 2
Benzyloxycarbonylamino
2
(Dimethoxy
Phosphinyl)Acetate 152 Hiroki Azuma, Kentaro Okano, Tohru Fukuyama, and Hidetoshi Tokuyama Discussion Addendum for: 5
ENDO
TRIG Cyclization of 1,1
Difluoro
1
Alkenes: Synthesis of 3
Butyl
2
Fluoro
1
Tosylindole (1H
Indole, 3
Butyl
2
Fluoro
1
[(4
Methylphenyl)Sulfonyl
) 162 Junji Ichikawa Preparation of a Thrifluoromethyl Transfer Agent: 1
Trifloromethyl
1,3
Dihydro
3,3
Dimenthyl
1,2
Benziodoxole 168 Patrick Eisenberger, Iris Kieltsch, Raffael Koller, Kyrill Stanek, and Antonio Tongni Synthesis of (S,S)
Diisopropyl Tartrate (E)
Crothylboronate and Its Reaction with Aldehydes: (2R,3R,4R)
1,2
Dideoxy
2
Ethenyl
4,5,
O
(1
Methylethylidene)
Xylitol 181 Huikai Sun and William R. Roush Discussion Addendum for: 4
Methoxy
4'
Nitrophenyl. Recent Advances in the Stille Biaryl Coupling Reaction and Applications in Complex Natural Products Synthesis 197 Robert M. Williams Discussion Addendum for: Palladium
Catalyzed Reaction of 1
Alkenylboronates with Vinylic Halides: (1Z,3E)
1
Phenyl
1,3
Octadiene 202 Norio Miyaura Discussion Addendum for: Palladium (0)
Catalyzed Reaction of 9
Alkyl
9
Borabicyclo[3.3.1]Nonane with 1
Bromo
1
Phenylthioethene: 4
(3
Cyclohexenyl )
2
Phenylthio
1
1
Butene 207 Norio Miyaura Preparation of Isopropyl 2
Diazoacetyl(Phenyl)Carbamate 212 Hubert Muchalski, Amanda B. Doody, Timothy L. Troyer, and Jeffrey N. Johnson Gram Scale Catalytic Asymmetric Aziridination: Preparation of (2R,3R)
Ethyl 1
Benzhydryl
3
(4
Bromopheneyl)Aziridine 2
Carboxylate 224 Aman A. Desai, Roberto Morán
Ramallal, and William D. Wulff Cu
Catalyzed Azide
Alkyne Cycloaddition: Preparation of Tris((1
Benzyl
1H
1,2,3
Triazolyl )Methyl)Amine 238 Jason E. Hein, Larissa B. Krasnova, Masayuki Iwasaki, and Valery V. Fokin Lithiated Primary Alkyl Carbamates for the Homologation of Boronic Esters Matthew P. Webster, Benjamin M. Partridge, and Varinder K. Aggarwal Discussion Addendum for: Palladium
Catalyzed Reduction of Vinyl Trifluoromethanesulfonates to Alkenes: Cholesta
3,5
Diene 260 Sandro Cacchi, Enrico Morera, and Giorgio Ortar Discussion Addendum for: Synthesis of Indoles by Palladium
Catalyzed Reductive N
Heteroannulation of 2
Nitrostyrenes: Methyl Indole
4
Carboxylate 291 Björn C. Söderberg An Economical Synthesis of 4
Trimethysilyl
2
Butyn
1
OL 296 Alexander N. Wein, Rongbiao Tong, and Frank E. McDonald Silver
Catalyzed Rearrangement of Propargylic Sulfinates: Synthesis of Allengic Sulfones 309 Michael Harmata, Zhengxin Cai and Chaofeng Huang (Sa,S)
N
[2'
(Methylphenylsulfonamido)
1
1'
Binaphthyl
2
YL]Pyrrolidine
2
Carboxamide: An Organocatalyst for the Direct Aldol Reaction 317 Santiago F. Viózquez, Gabriela Guillene, Carmen Nájera, Ben Bradshaw, Gorka Etxebarria
Jardi, and Josep Bonjoch Synthesis of (S)
8a
Methyl
3,4,8,8a
Tetrahydro
1,6
(2H,7H)
Naphthalenedione via N
Tosyl
(Sa)
Binam
L
Pholinamide Organocatalysis 330 Ben Bradshaw, Gorka Etxebarria
Jardi, Josep Bonjoch, Santiago F. Viózquez, Gabriela Guillena, and Carmen Nájera Stereoselective Nickel
Catalyzed 1,4
Hydroboration of 1,3
Dienes 342 Robert J. Ely and James P. Morken Tandem Nucleophilic Addition/Fragmentation of Vinylogous Acyl Triflates: 2
Methyl
2
(1
Oxo
5
Heptynyl)
1
3
Dithiane 353 Marilda P. Lisboa, Tunf T. Hoang, and Gregory B. Dudley Synthesis and Diasteroselective Aldol Reactions of a Thiazolidinethione Chiral Auxiliary 364 Michael T. Crimmins, Hamish S. Christie, and Colin O. Hughes Synthesis of 2,3
Disubstituted Indoles via Palladium
Catalyzed Annulation of Internal Alkynes: 3
Methyl
2
(Trimethylsilyl)Indole 377 Yu Chen, Nataliya A. Markina, Tuanli Yao, and Richard C. Larock An Intramolecular Amination of Aryyl Halides with a Combination of Copper (I) and Cesium Acetate: Preparation of 5,6
Dimethoxyindole
1,2
Dicarboxylic Acid 1
Benzyl Ester 2
Methyl Ester 388 Toshiharu Noji, Kentaro Okano, Tohru Fukuyama, and Hidetoshi Tokuyama Ligand
Free Copper(II) Oxide Nanoparticles
Catalyzed Synthesis of Substituted Benzoxazoles 398 Prasenjit Saha, Md Ashif Ali, and Tharmalingam Punniyamurthy (R)
3,3'
Bis(9
Phenanthyryl)
1,1'
Binaphthalene
2,2'
Diyl Hydrogen Phosphate 406 Wenhao Hu, Jing Zhou, Xinfang Xu, Weijun Liu, and Liuzhu Gong Enantioselective Three
Component Reaction for the Preparation of ß
Amino
a
Hydroxy Esters 418 Jing Zhou, Xinfang Xu, and Wenhao Hu Mild Conversion of Tertiary Amides to Aldehydes Using Cp2Zr(H)Cl (Schwartz's Reagent) 427 Matthew W. Leighty, Jared T. Spletstoser, and Gunda I. Georg