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High Quality Content by WIKIPEDIA articles! In chemistry, a molecular orbital (or MO ) is a mathematical function that describes the wave-like behavior of an electron in a molecule. This function can be used to calculate chemical and physical properties such as the probability of finding an electron in any specific region. The use of the term "orbital" was first used in English by Robert S. Mulliken in 1925 as the English translation of Schrödinger's use of the German word, 'Eigenfunktion'. It has since been equated with the "region" generated with the function. Molecular orbitals are usually constructed by combining atomic orbitals or hybrid orbitals from each atom of the molecule, or other molecular orbitals from groups of atoms. They can be quantitatively calculated using the Hartree-Fock or Self-Consistent Field method.