This book provides a comprehensive, up-to-date introduction to phase equilibria in ceramic systems. It logically proceeds from one- and two-component systems through increasingly complex systems, enabling students to utilize the phase rule in real application.
This book provides a comprehensive, up-to-date introduction to phase equilibria in ceramic systems. It logically proceeds from one- and two-component systems through increasingly complex systems, enabling students to utilize the phase rule in real application.
PREFACE 1. INTRODUCTION AND DEFINITIONS I. Historical II. Literature Sources III. Statement of the Phase Rule and Definitions Problems References Reading List on Phase Equilibria 2. THE ONE COMPONENT SYSTEM I. Thermodynamic Basis of the Phase Diagram II. Application of the Phase Rule to the System H2 0 at Ordinary Temperature and Pressure III. Le Chatelier's Principle and the Clausius Clapeyron Equation IV. Metastability and Non Equilibrium V. The Bridgman Ice Diagram and the Importance of Pressure; Polymorphism of Solids; Phase Diagram Property Diagram VI. Examples of Real Systems VII. Summary Problems References 3. THE TWO COMPONENT SYSTEM I. Introduction II. The Binary Eutectic System III. Intermediate Compounds IV. Isothermal Analysis; Isothermal Evaporation V. Metastable Relationships in Simple Binary Systems VI. Complete or Continuous Solid Solution VII. Partial Solid Solution VIII. Phase Transitions in the End Members or Intermediate Solid Solutions; Combinations of Continuous and Partial Solid Solution; Exsolution IX. Complex Solid Solution Diagrams X. Liquid Immiscibility XI. Real Oxide Systems XII. Fluoride Model Systems Problems References 4. EXPERIMENTAL METHODS OF CONSTRUCTING PHASE DIAGRAMS I. Introduction II. Major Factors in Experimental Methods III. Glass Forming Systems vs. Non Glass Forming Systems IV. Special Techniques V. Discussion and Evaluation of Experimental Pro cedures on Real Systems VI. Thermodynamics and Computer Calculation Appendix A Appendix B References on High Pressure Methods and Materials Suggested Class Disscussions Which Can Enlarge the Understanding of Experimental Techniques References 5. TERNARY SYSTEMS W ITHOUT SOLID SOLUTION I. Introduction II. Isoplethal Analysis; The Equilibrium Crystallization Path in a Simple Eutectic Type System; Use of the Lever Rule III. Hie Influence of Binary Compounds on the Ternary System; Joins and Alkemades Lines; Composition or Compatibility Triangles; Crystallization Paths IV. The Influence of Ternary Compounds on the Ternary System; Crystallization Paths V. Polymorphism or Phase Transformations in Ternary Systems Without Solid Solution VI. Review and Summary of Factois Which Must Be Considered During Isoplethal Analyses VII. Liquid Immiscibility VIII. Isothermal Sections in Aqueous Systems; Isothermal Evaporation IX. Isothermal Sections in Ternary Oxide Systems X. Vertical Sections in Ternary Oxide Systems XI. Complex Ternary Systems XII. Real Ternary Systems Problems 6. NON EQUILIBRIUM IN CERAMIC SYSTEMS I. General II. One Component Systems III. Two Component Systems IV. Three Component Systems Problems References 7. SOLID SOLUTION IN TERNARY SYSTEMS I. Introduction II. The Complete Solid Solution System; The Equilibrium Ciystallization Path III. Complete Solid Solution in One Binary System Combined With Two Simple Eutectic Systems; Isothermal Planes; Three Phase Boundary Lines; Quantitative Analysis of Crystallization Path (Isoplethal Analysis); Three Phase Triangles IV. Ternary Solid Solutions Crystallizing From Ternary Liquids; One Complete Solid Solution System, Two Partial Solid Solution Systems; Crystallization Path; Isothermal and Vertical Sections V. Solid Solution Systems With Three Phase Equilibria VI. Solid Solution Systems With Four Phase Equilibria VII. Additional Basic Solid Solution Systems VIII. Real Systems with Intermediate Compounds and Solid Solutions Problems References 8. QUATERNARY AND MULTICOMPONENT SYSTEMS I. Introduction; Quaternary Systems Without Solid Solution II. Crystallization Path in a Simple Quaternary Eutectic Type System; Isoplethal Analysis III. Method of Representing Relationships Between Quaternary Invariant Points IV. Solid Models of Real Quaternary Systems V. Solid Solution in Quaternary Systems VI. Multicomponent Systems References INDEX.
PREFACE 1. INTRODUCTION AND DEFINITIONS I. Historical II. Literature Sources III. Statement of the Phase Rule and Definitions Problems References Reading List on Phase Equilibria 2. THE ONE COMPONENT SYSTEM I. Thermodynamic Basis of the Phase Diagram II. Application of the Phase Rule to the System H2 0 at Ordinary Temperature and Pressure III. Le Chatelier's Principle and the Clausius Clapeyron Equation IV. Metastability and Non Equilibrium V. The Bridgman Ice Diagram and the Importance of Pressure; Polymorphism of Solids; Phase Diagram Property Diagram VI. Examples of Real Systems VII. Summary Problems References 3. THE TWO COMPONENT SYSTEM I. Introduction II. The Binary Eutectic System III. Intermediate Compounds IV. Isothermal Analysis; Isothermal Evaporation V. Metastable Relationships in Simple Binary Systems VI. Complete or Continuous Solid Solution VII. Partial Solid Solution VIII. Phase Transitions in the End Members or Intermediate Solid Solutions; Combinations of Continuous and Partial Solid Solution; Exsolution IX. Complex Solid Solution Diagrams X. Liquid Immiscibility XI. Real Oxide Systems XII. Fluoride Model Systems Problems References 4. EXPERIMENTAL METHODS OF CONSTRUCTING PHASE DIAGRAMS I. Introduction II. Major Factors in Experimental Methods III. Glass Forming Systems vs. Non Glass Forming Systems IV. Special Techniques V. Discussion and Evaluation of Experimental Pro cedures on Real Systems VI. Thermodynamics and Computer Calculation Appendix A Appendix B References on High Pressure Methods and Materials Suggested Class Disscussions Which Can Enlarge the Understanding of Experimental Techniques References 5. TERNARY SYSTEMS W ITHOUT SOLID SOLUTION I. Introduction II. Isoplethal Analysis; The Equilibrium Crystallization Path in a Simple Eutectic Type System; Use of the Lever Rule III. Hie Influence of Binary Compounds on the Ternary System; Joins and Alkemades Lines; Composition or Compatibility Triangles; Crystallization Paths IV. The Influence of Ternary Compounds on the Ternary System; Crystallization Paths V. Polymorphism or Phase Transformations in Ternary Systems Without Solid Solution VI. Review and Summary of Factois Which Must Be Considered During Isoplethal Analyses VII. Liquid Immiscibility VIII. Isothermal Sections in Aqueous Systems; Isothermal Evaporation IX. Isothermal Sections in Ternary Oxide Systems X. Vertical Sections in Ternary Oxide Systems XI. Complex Ternary Systems XII. Real Ternary Systems Problems 6. NON EQUILIBRIUM IN CERAMIC SYSTEMS I. General II. One Component Systems III. Two Component Systems IV. Three Component Systems Problems References 7. SOLID SOLUTION IN TERNARY SYSTEMS I. Introduction II. The Complete Solid Solution System; The Equilibrium Ciystallization Path III. Complete Solid Solution in One Binary System Combined With Two Simple Eutectic Systems; Isothermal Planes; Three Phase Boundary Lines; Quantitative Analysis of Crystallization Path (Isoplethal Analysis); Three Phase Triangles IV. Ternary Solid Solutions Crystallizing From Ternary Liquids; One Complete Solid Solution System, Two Partial Solid Solution Systems; Crystallization Path; Isothermal and Vertical Sections V. Solid Solution Systems With Three Phase Equilibria VI. Solid Solution Systems With Four Phase Equilibria VII. Additional Basic Solid Solution Systems VIII. Real Systems with Intermediate Compounds and Solid Solutions Problems References 8. QUATERNARY AND MULTICOMPONENT SYSTEMS I. Introduction; Quaternary Systems Without Solid Solution II. Crystallization Path in a Simple Quaternary Eutectic Type System; Isoplethal Analysis III. Method of Representing Relationships Between Quaternary Invariant Points IV. Solid Models of Real Quaternary Systems V. Solid Solution in Quaternary Systems VI. Multicomponent Systems References INDEX.
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