George Wypych

Handbook of Polymers

• Gebundenes Buch

Produktbeschreibung

This book uses various imaging techniques to provide a comprehensive reference source which will enable engineers to more reliably detect material damage at an early stage, implement correct maintenance and replacement regimes, and avoid the serious consequences of unforeseen material failure.

Produktdetails

• Verlag: Elsevier Science
• Seitenzahl: 696
• Erscheinungstermin: 10. September 2011
• Englisch
• Abmessung: 290mm x 228mm x 47mm
• Gewicht: 1722g
• ISBN-13: 9781895198478
• ISBN-10: 189519847X
• Artikelnr.: 33947918

Autorenporträt

George Wypych has a Ph.D. in chemical engineering. His professional expertise includes both university teaching (full professor) and research and development. He has published 18 books, 47 scientific papers, and he has obtained 16 patents. He specializes in polymer additives, polymer processing and formulation, material durability and the development of sealants and coatings.

Inhaltsangabe

* General (Common name
IUPAC name
ACS name
Acronym
CAS number
EC number
RETECS number
Linear formula) * History (Person to discover
Date
Details) * Synthesis (Monomer(s) structure
Monomer(s) CAS number(s)
Monomer(s) molecular weight(s)
Monomer(s) expected purity(ies)
Monomer ratio
Degree of substitution
Formulation example
Method of synthesis
Temperature of polymerization
Time of polymerization
Pressure of polymerization
Catalyst
Yield
Activation energy of polymerization
Free enthalpy of formation
Heat of polymerization
Initiation rate constant
Propagation rate constant
Termination rate constant
Chain transfer rate constant
Inhibition rate constant
Polymerization rate constant
Method of polymer separation
Typical impurities
Typical concentration of residual monomer
Number average molecular weight
Mn
Mass average molecular weight
Mw
Polydispersity
Mw/Mn
Polymerization degree
Molar volume at 298K
Molar volume at melting point
Van der Waals volume
Radius of gyration
End-to-end distance of unperturbed polymer chain
Degree of branching
Type of branching
Chain-end groups) * Structure (Crystallinity
Crystalline structure
Cell type (lattice)
Cell dimensions
Unit cell angles
Number of chains per unit cell
Crystallite size
Spacing between crystallites
Polymorphs
Tacticity
Cis content
Chain conformation
Entanglement molecular weight
Lamellae thickness
Heat of crystallization
Rapid crystallization temperature
Avrami constants
k/n) * Commercial polymers (Some manufacturers
Trade names
Composition information) * Physical properties (Density
Bulk density
Color
Refractive index
Birefringence
Molar polarizability
Transmittance
Haze
Gloss
Odor
Melting temperature
Softening point
Decomposition temperature
Fusion temperature
Thermal expansion coefficient
Thermal conductivity
Glass transition temperature
Specific heat capacity
Heat of fusion
Calorific value
Maximum service temperature
Long term service temperature
Temperature index (50% tensile strength loss after 20
000 h/5000 h)
Heat deflection temperature at 0.45 MPa
Heat deflection temperature at 1.8 MPa
Vicat temperature VST/A/50
Vicat temperature VST/B/50
Start of thermal degradation
Enthalpy
Acceptor number
Donor number
Hansen solubility parameters
dD
dP
dH
Molar volume
Hildebrand solubility parameter
Surface tension
Dielectric constant at 100 Hz/1 MHz
Dielectric loss factor at 1 kHz
Relative permittivity at 100 Hz
Relative permittivity at 1 MHz
Dissipation factor at 100 Hz
Dissipation factor at 1 MHz
Volume resistivity
Surface resistivity
Electric strength K20/P50
d=0.60.8 mm
Comparative tracking index
CTI
test liquid A
Comparative tracking index
CTIM
test liquid B
Arc resistance
Power factor
Coefficient of friction
Permeability to nitrogen
Permeability to oxygen
Permeability to water vapor
Diffusion coefficient of nitrogen
Diffusion coefficient of oxygen
Diffusion coefficient of water vapor
Contact angle of water
Surface free energy
Speed of sound
Acoustic impedance
Attenuation) * Mechanical properties (Tensile strength
Tensile modulus
Tensile stress at yield
Tensile creep modulus
1000 h
elongation 0.5 max
Elongation
Tensile yield strain
Flexural strength
Flexural modulus
Elastic modulus
Compressive strength
Young's modulus
Tear strength
Charpy impact strength
Charpy impact strength
notched
Izod impact strength
Izod impact strength
notched
Shear strength
Tenacity
Abrasion resistance
Adhesive bond strength
Poisson's ratio
Compression set
Shore A hardness
Shore D hardness
Rockwell hardness
Ball indention hardness at 358 N/30 S
Shrinkage
Brittleness temperature
Viscosity number
Intrinsic viscosity
Mooney viscosity
Melt viscosity
shear rate=1000 s-1
Melt volume flow rate
Melt index
Water absorption
Moisture absorption) * Chemical resistance (Acid dilute/concentrated
Alcohols
Alkalis
Aliphatic hydrocarbons
Aromatic hydrocarbons
Esters
Greases & oils
Halogenated hydrocarbons
Ketones
Theta solvent
Good solvent
Non-solvent) * Flammability (Flammability according to UL-standard; thickness 1.6/0.8 mm
Ignition temperature
Autoignition temperature
Limiting oxygen index
Heat release
NBS smoke chamber
Burning rate (Flame spread rate)
Char
Heat of combustion
Volatile products of combustion) * Weather stability (Spectral sensitivity
Activation wavelengths
Excitation wavelengths
Emission wavelengths
Activation energy of photoxidation
Depth of UV penetration
Important initiators and accelerators
Products of degradation
Stabilizers) * Biodegradation (Typical biodegradants
Stabilizers) * Toxicity (NFPA: Health
Flammability
Reactivity rating
Carcinogenic effect
Mutagenic effect
Teratogenic effect
Reproductive toxicity
TLV
ACGIH
NIOSH
MAK/TRK
OSHA
Acceptable daily intake
Oral rat
LD50
Skin rabbit
LD50) * Environmental impact (Aquatic toxicity
Daphnia magna
LC50
48 h
Aquatic toxicity
Bluegill sunfish
LC50
48 h
Aquatic toxicity
Fathead minnow
LC50
48 h
Aquatic toxicity
Rainbow trout
LC50
48 h
Mean degradation half-life
Toxic products of degradation
Biological oxygen demand
BOD5
Chemical oxygen demand
Theoretical oxygen demand
Cradle to grave non-renewable energy use) * Processing (Typical processing methods
Preprocess drying: temperature/time/residual moisture
Processing temperature
Processing pressure
Process time
Additives used in final products
Applications
Outstanding properties) * Blends (Suitable polymers
Compatibilizers) * Analysis (FTIR (wavenumber-assignment)
Raman (wavenumber-assignment)
NMR (chemical shifts)
x-ray diffraction peaks)