Dave J. Adams, Paul J. Dyson, Stewart J. Tavener

Chemistry in Alternative Reaction Media

• Broschiertes Buch

Produktbeschreibung

At a time when environmental concerns are increasing, it's important that chemical processes are as environmentally friendly as possible. This book outlines various methods for producing inorganic and organic solvents without the use of traditional solvents that can have detrimental effects on the environment.
_ This is the first book to give extensive and exclusive coverage to the topic
_ Includes important environmental issues

This book will appeal to anyone with an interest in organic synthesis; reaction chemistry; catalysis; and process development, and to undergraduate and graduate students of organic chemistry; catalysis; green chemistry; clean technology and environmental chemistry courses.

Produktdetails

• Verlag: Wiley & Sons
• 1. Auflage
• Seitenzahl: 272
• Erscheinungstermin: 21. November 2003
• Englisch
• Abmessung: 229mm x 152mm x 16mm
• Gewicht: 420g
• ISBN-13: 9780471498490
• ISBN-10: 0471498491
• Artikelnr.: 11442742

Autorenporträt

Dave J. Adams is the author of Chemistry In Alternative Reaction Media, published by Wiley. Paul J. Dyson is the author of Chemistry In Alternative Reaction Media, published by Wiley. Stewart J. Tavener is the author of Chemistry In Alternative Reaction Media , published by Wiley.

Inhaltsangabe

Preface. Abbreviations and Acronyms. 1 Chemistry in Alternative Reaction
Media. 1.1 Economic and Political Considerations. 1.2 Why Do Things
Dissolve? 1.3 Solvent Properties and Solvent Classification. 1.4 Solvent
Polarity. 1.5 The Effect of Solvent Polarity on Chemical Systems. 1.6 W hat
is Required from Alternative Solvent Strategies? References. 2 Multiphasic
Solvent Systems. 2.1 An Introduction to Multiphasic Chemistry. 2.2 Solvent
Combinations. 2.3 Benefits and Problems Associated with Multiphasic
Systems. 2.4 Kinetics of Homogeneous Reactions. 2.5 Kinetics of Biphasic
Reactions. 2.6 Conclusions. References. 3 Reactions in Fluorous Media. 3.1
Introduction. 3.2 Properties of Perfluorinated Solvents. 3.3 Designing
Molecules for Fluorous Compatibility. 3.4 Probing the Effect of
Perfluoroalkylation on Ligand Properties. 3.5 Partition Coefficients. 3.6
Liquid-Liquid Extractions. 3.7 Solid Separations. 3.8 Conclusions.
References. 4 Ionic Liquids. 4.1 Introduction. 4.2 Physical Properties of
Ionic Liquids. 4.3 Benefits and Problems Associated with Using Ionic
Liquids in Synthesis. 4.4 Catalyst Design. 4.5 Conclusions. References. 5
Reactions in Water. 5.1 The Structure and Properties of Water. 5.2 The
Benefits and Problems Associated with Using Water in Chemical Synthesis.
5.3 Organometallic Reactions in Water. 5.4 Aqueous Biphasic Catalysis. 5.5
Phase Transfer Catalysis. 5.6 Organometallic Catalysis under Phase Transfer
Conditions. 5.7 Triphase Catalysis. 5.8 Conclusions. References. 6
Supercritical Fluids. 6.1 Introduction. 6.2 Physical Properties. 6.3 Local
Density Augmentation. 6.4 Supercritical Fluids as Replacement Solvents. 6.5
Reactor Design. 6.6 Spectroscopic Analysis of Supercritical Media. 6.7
Reactions in Supercritical Media. 6.8 Conclusions. References. 7
Diels-Alder Reactions in Alternative Media. 7.1 Diels-Alder Reactions in
Water. 7.2 Diels-Alder Reactions in Perfluorinated Solvents. 7.3
Diels-Alder Reactions in Ionic Liquids. 7.4 Diels-Alder Reactions in
Supercritical Carbon Dioxide. 7.5 Conclusions. References. 8 Hydrogenation
and Hydroformylation Reactions in Alternative Solvents. 8.1 Introduction.
8.2 Hydrogenation of Simple Alkenes and Arenes. 8.3 Hydroformylation
Reactions in Alternative Media. 8.4 Conclusions. References. 9
FromAlkanestoCO2: Oxidation in Alternative Reaction Media. 9.1 Oxidation of
Alkanes. 9.2 Oxidation of Alkenes. 9.3 Oxidation of Alcohols. 9.4 Oxidation
of Aldehydes and Ketones. 9.5 Destructive Oxidation. 9.6 Conclusions.
References. 10 Carbon-Carbon Bond Formation, Metathesis and Polymerization.
10.1 Carbon-Carbon Coupling Reactions. 10.2 Metathesis Reactions. 10.3
Polymerization Reactions in Alternative Reaction Media. 10.4 Conclusions.
References. 11 Alternative Reaction Media in Industrial Processes. 11.1
Obstacles and Opportunities for Alternative Media. 11.2 Reactor
Considerations for Alternative Media. 11.3 Industrial Applications of
Alternative Solvent Systems. 11.4 Outlook for Fluorous Solvents and Ionic
Liquids. 11.5 Conclusions. References. Index.

Rezensionen

"...a convenient and effective book giving a good introduction to the possibilities and problems of new reaction media..." (Angewandte Chemie International Edition, 2004/43)

"...a well-written and timely piece of work for any scientists and engineers who work with solvents...and will be a valuable addition to their bookshelves." (Energy Sources, Vol. 26, 2004)

"...well written and easy to read, very useful for a student audience...will introduce the subject to a wider audience..." (Organic Process Research & Development, Dec 2003)