Functionalized Inorganic Fluorides (eBook, PDF)
Synthesis, Characterization and Properties of Nanostructured Solids
Redaktion: Tressaud, Alain
Functionalized Inorganic Fluorides (eBook, PDF)
Synthesis, Characterization and Properties of Nanostructured Solids
Redaktion: Tressaud, Alain
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Functionalized Inorganic Fluorides: Synthesis, Characterization & Properties of Nanostructured Solids covers several classes of nanostructured and functionalized inorganic fluorides, oxide-fluorides, and fluorinated oxides such as silica and alumina. Ranging from powders or glass-ceramics to thin layers and coatings, they have applications as more efficient and less aggressive catalysts, UV absorbers, planar optical waveguides, integrated lasers and optical amplifiers, luminescent materials, anti-reflective coatings and high Tc superconductors. With a focus on new types of solids, such as…mehr
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- Produktdetails
- Verlag: John Wiley & Sons
- Seitenzahl: 614
- Erscheinungstermin: 5. April 2010
- Englisch
- ISBN-13: 9780470660751
- Artikelnr.: 37298368
- Verlag: John Wiley & Sons
- Seitenzahl: 614
- Erscheinungstermin: 5. April 2010
- Englisch
- ISBN-13: 9780470660751
- Artikelnr.: 37298368
Fluorides - Mechanism and Properties Erhard Kemnitz, Gudrun Scholz, Stephan
Rüdiger 1.1 Introduction 1.2 Fluorolytic sol-gel synthesis References 2
Microwave-Assisted Route Towards Fluorinated Nanomaterials Damien
Dambournet, Alain Demourgues and Alain Tressaud 2.1 Introduction 2.2
Introduction to Microwave Synthesis 2.3 Preparation of Nanosized Metal
Fluorides 2.4 Concluding remarks Acknowledgements References 3 High Surface
Area Metal Fluorides as Catalysts Erhard Kemnitz, Stephan Rüdiger 3.1
Introduction 3.2 High Surface Area Aluminium Fluoride as Catalyst 3.3
Host-Guest Metal Fluoride Systems 3.4 Hydroxy(oxo)fluorides as bi-acidic
catalysts 3.5 Oxidation Catalysis 3.6 Metal Fluoride Supported Noble Metal
Catalysts References 4 Investigation of surface acidity using a range of
probe molecules Alexandre Vimont, Marco Daturi and John M. Winfield 4.1
Introduction 4.2 Characterisation of Acidity on a Surface: Contrasts with
Molecular Fluorides 4.3 Experimental Methodology 4.4 Experimental Studies
of Surface Acidity 4.5 Conclusions References 5 Probing short and medium
range order in Al-based fluorides using high resolution solid state nuclear
magnetic resonance and parameter modelling Christophe Legein, Monique Body,
Jean-Yves Buzaré, Charlotte Martineau and Gilles Silly 5.1 Introduction 5.2
High Resolution NMR Techniques 5.3 Application to Functionalized Al-Based
Fluorides with catalytic properties 5.4 Alkali and Alkaline-earth
Fluoroaluminates: Model Compounds for modelling of NMR Parameters 5.5
Conclusion References 6 Predictive Modelling of Aluminium Fluoride Surfaces
Christine. L. Bailey, Sanghamutra Mukhopadhyay, Adrian Wander, Barry G.
Searle and Nicholas M. Harrison 6.1 Introduction 6.2 Methodology 6.3
Geometric Structure of ± and ²-AIF3 6.4 Characterisation of AlF3 Surfaces
6.5 Surface Composition under Reaction Conditions 6.6 Characterisation of
Hydroxylated Surfaces 6.7 Surface Catalysis 6.8 Conclusions
Acknowledgements References 7 Inorganic Fluoride materials from
Solvay-Fluor and their industrial applications Placido Garcia Juan,
Hans-Walter Swidersky, Thomas Schwarze and Johannes Eicher 7.1 Introduction
7.2 Hydrogen Fluoride 7.3 Elemental fluorine, F2 7.4 Iodine pentafluoride,
IF5 7.5 Sulfur hexafluoride, SF6 7.6 Ammonium bifluoride, NH4HF2 7.7
Potassium fluorometalates, KZnF3 and K2SiF6 7.8 Cryolite and related
Hexafluoroaluminates, Na3AlF6, Li3AlF6, K3AlF6 7.9 Potassium fluoroborate,
KBF4 7.10 Fluoboric acid, HBF4 7.11 Barium fluoride, BaF2 7.12 Synthetic
Calcium fluoride, CaF2 7.13 Sodium fluoride, NaF 7.14 Sodium bifluoride,
NaHF2 7.15 Potassium bifluoride, KHF2 7.16 Potassium fluoroaluminate, KAlF4
7.17 Fluoroaluminate fluxes in Aluminum brazing 7.18 Summary References 8
New nanostructured fluorocompounds as UV absorbers Alain Demourgues,
Laetitia Sronek and Nicolas Penin 8.1 Introduction 8.2 Synthesis of
tetravalent Ce and Ti-based oxyfluorides 8.3 Chemical compositions and
structural features of Ce and Ti-based oxyfluorides: 8.4 UV shielding
properties of divided oxyfluorides 8.5 Conclusion Acknowledgements
References 9 Oxyfluoride transparent glass-ceramics Michel Mortier and
Géraldine Dantelle 9.1 Introduction 9.2 Synthesis 9.3 Different systems 9.4
Thermal characterisation 9.5 Morphology of the separated phases 9.6 Optical
properties of glass-ceramics 9.7 Conclusion References 10 Sol-Gel Route to
Inorganic Fluoride Nanomaterials with Optical Properties Shinobu Fujihara
10.1 Introduction 10.2 Principle of a Sol-Gel Method 10.3 Fluorinating
Reagents and Method of Fluorination 10.4 Control of Shapes and
Microstructures 10.5 Optical Properties 10.6 Concluding Remarks References
11 Fluoride glasses and planar optical waveguides Brigitte Boulard 11.1
Introduction 11.2 Rare earth in fluoride glasses 11.3 Fabrication of
waveguides: a review 11.4 Performances of active waveguides 11.5 Fluoride
transparent glass-ceramics: an emerging material 11.6 Conclusion References
12 Polyanion condensation in inorganic and hybrid fluoroaluminates Karim
Adil, Amandine Cadiau, Annie Hemon-Ribaud, Marc Leblanc and Vincent
Maisonneuve 12.1 Introduction 12.2 Synthesis 12.3 Extended finite
polyanions (0D) 12.4 1D networks 12.5 2D networks 12.6 3D networks 12.7
Evolution of the condensation of inorganic polyanions Acknowledgements
Supplementary materials References 13 Synthesis, structure and
superconducting/magnetic properties of Cu- and Mn- based oxyfluorides
Evgeny V. Antipov and Artem M. Abakumov 13.1 Introduction 13.2 Chemical
aspects of fluorination of complex oxides 13.3 Structural aspects of
fluorination of complex cuprates and superconducting properties 13.4
Fluorination of manganites 13.5 Conclusions References 14 Doping Influence
on the Defect Structure and Ionic Conductivity of Fluorine- Containing
Phases Elena I. Ardashnikova, V. A. Prituzhalovand I. B. Kutsenok 14.1
Introduction 14.2 Influence of Oxygen Ions on Fluoride Properties 14.3
Cation Doping of Fluorides 14.4 Active Lone Electron Pair of Cations and
Ionic Conductivity 14.5 Peculiarities of the Defect Structure of
Nonstoichiometric Fluorite-like Phases 14.6 Ionic Transfer in Fluorite-like
Phases 14.7 Peculiarities of the Defect Structure of Nonstoichiometric
Tysonite-like Phases 14.8 Ionic Transfer in Tysonite-like Phases 14.9
Conclusions References 15 Hybrid intercalation compounds containing
perfluoroalkyl groups Yoshiaki Matsuo 15.1 Introduction 15.2 Preparation
and properties of intercalation compounds containing perfluoroalkyl groups
15.3 Photophysical and photochemical properties of dyes in intercalation
compounds containing perfluoroalkyl groups 15.4 Conclusion and future
perspectives References 16 The fluoride route: a good opportunity for the
preparation of 2D and 3D inorganic microporous frameworks Jean-Louis
Paillaud, Philippe Caullet, Jocelyne Brendlé, Angélique Simon- Masseron and
Joël Patarin 16.1 Introduction 16.2 Silica-based microporous materials 16.3
Germanium-based microporous materials 16.4 Phosphate-based microporous
materials 16.5 Synthetic clays 16.6 Conclusion References 17 Access to
Highly Fluorinated Silica by Direct F2 Fluorination Alain Demourgues,
Emilie Lataste, Etienne Durand and Alain Tressaud 17.1 Introduction 17.2
Mesoporous silica and fluorination procedure 17.3 About the chemical
composition and morphology of highly fluorinated silica 17.4 FTIR analysis
17.5 Thermal stability and water affinity of highly fluorinated silica 17.6
NMR investigations 17.7 Conclusions on the F2-gas fluorination mechanism of
mesoporous silica Acknowledgements References 18 Preparation and properties
of rare-earth containing oxide fluoride glasses Susumu Yonezawa, Jae-ho Kim
and Masayuki Takashima 18.1 Introduction 18.2 Preparation and basic
characteristics of oxide fluoride glasses containing LnF3 18.3 Optical and
magnetic properties of LnF3-BaF2-AlF3-GeO2 (SiO2) glasses 18.4 Conclusions
References 19 Switchable hydrophobic-hydrophilic fluorinated layer for
offset processing Alain Tressaud, Christine Labrugère and Etienne Durand
19.1 Introduction 19.2 The principles of lithographic printing process 19.3
Experimental part 19.4 Various types of surface modifications using
fluorinated rf plasmas 19.5 Comparison of surface modifications of porous
alumina using various fluorinated media: CF4, C3F8 and c-C4F8 19.6
Conclusions Acknowledgements References
Fluorides - Mechanism and Properties Erhard Kemnitz, Gudrun Scholz, Stephan
Rüdiger 1.1 Introduction 1.2 Fluorolytic sol-gel synthesis References 2
Microwave-Assisted Route Towards Fluorinated Nanomaterials Damien
Dambournet, Alain Demourgues and Alain Tressaud 2.1 Introduction 2.2
Introduction to Microwave Synthesis 2.3 Preparation of Nanosized Metal
Fluorides 2.4 Concluding remarks Acknowledgements References 3 High Surface
Area Metal Fluorides as Catalysts Erhard Kemnitz, Stephan Rüdiger 3.1
Introduction 3.2 High Surface Area Aluminium Fluoride as Catalyst 3.3
Host-Guest Metal Fluoride Systems 3.4 Hydroxy(oxo)fluorides as bi-acidic
catalysts 3.5 Oxidation Catalysis 3.6 Metal Fluoride Supported Noble Metal
Catalysts References 4 Investigation of surface acidity using a range of
probe molecules Alexandre Vimont, Marco Daturi and John M. Winfield 4.1
Introduction 4.2 Characterisation of Acidity on a Surface: Contrasts with
Molecular Fluorides 4.3 Experimental Methodology 4.4 Experimental Studies
of Surface Acidity 4.5 Conclusions References 5 Probing short and medium
range order in Al-based fluorides using high resolution solid state nuclear
magnetic resonance and parameter modelling Christophe Legein, Monique Body,
Jean-Yves Buzaré, Charlotte Martineau and Gilles Silly 5.1 Introduction 5.2
High Resolution NMR Techniques 5.3 Application to Functionalized Al-Based
Fluorides with catalytic properties 5.4 Alkali and Alkaline-earth
Fluoroaluminates: Model Compounds for modelling of NMR Parameters 5.5
Conclusion References 6 Predictive Modelling of Aluminium Fluoride Surfaces
Christine. L. Bailey, Sanghamutra Mukhopadhyay, Adrian Wander, Barry G.
Searle and Nicholas M. Harrison 6.1 Introduction 6.2 Methodology 6.3
Geometric Structure of ± and ²-AIF3 6.4 Characterisation of AlF3 Surfaces
6.5 Surface Composition under Reaction Conditions 6.6 Characterisation of
Hydroxylated Surfaces 6.7 Surface Catalysis 6.8 Conclusions
Acknowledgements References 7 Inorganic Fluoride materials from
Solvay-Fluor and their industrial applications Placido Garcia Juan,
Hans-Walter Swidersky, Thomas Schwarze and Johannes Eicher 7.1 Introduction
7.2 Hydrogen Fluoride 7.3 Elemental fluorine, F2 7.4 Iodine pentafluoride,
IF5 7.5 Sulfur hexafluoride, SF6 7.6 Ammonium bifluoride, NH4HF2 7.7
Potassium fluorometalates, KZnF3 and K2SiF6 7.8 Cryolite and related
Hexafluoroaluminates, Na3AlF6, Li3AlF6, K3AlF6 7.9 Potassium fluoroborate,
KBF4 7.10 Fluoboric acid, HBF4 7.11 Barium fluoride, BaF2 7.12 Synthetic
Calcium fluoride, CaF2 7.13 Sodium fluoride, NaF 7.14 Sodium bifluoride,
NaHF2 7.15 Potassium bifluoride, KHF2 7.16 Potassium fluoroaluminate, KAlF4
7.17 Fluoroaluminate fluxes in Aluminum brazing 7.18 Summary References 8
New nanostructured fluorocompounds as UV absorbers Alain Demourgues,
Laetitia Sronek and Nicolas Penin 8.1 Introduction 8.2 Synthesis of
tetravalent Ce and Ti-based oxyfluorides 8.3 Chemical compositions and
structural features of Ce and Ti-based oxyfluorides: 8.4 UV shielding
properties of divided oxyfluorides 8.5 Conclusion Acknowledgements
References 9 Oxyfluoride transparent glass-ceramics Michel Mortier and
Géraldine Dantelle 9.1 Introduction 9.2 Synthesis 9.3 Different systems 9.4
Thermal characterisation 9.5 Morphology of the separated phases 9.6 Optical
properties of glass-ceramics 9.7 Conclusion References 10 Sol-Gel Route to
Inorganic Fluoride Nanomaterials with Optical Properties Shinobu Fujihara
10.1 Introduction 10.2 Principle of a Sol-Gel Method 10.3 Fluorinating
Reagents and Method of Fluorination 10.4 Control of Shapes and
Microstructures 10.5 Optical Properties 10.6 Concluding Remarks References
11 Fluoride glasses and planar optical waveguides Brigitte Boulard 11.1
Introduction 11.2 Rare earth in fluoride glasses 11.3 Fabrication of
waveguides: a review 11.4 Performances of active waveguides 11.5 Fluoride
transparent glass-ceramics: an emerging material 11.6 Conclusion References
12 Polyanion condensation in inorganic and hybrid fluoroaluminates Karim
Adil, Amandine Cadiau, Annie Hemon-Ribaud, Marc Leblanc and Vincent
Maisonneuve 12.1 Introduction 12.2 Synthesis 12.3 Extended finite
polyanions (0D) 12.4 1D networks 12.5 2D networks 12.6 3D networks 12.7
Evolution of the condensation of inorganic polyanions Acknowledgements
Supplementary materials References 13 Synthesis, structure and
superconducting/magnetic properties of Cu- and Mn- based oxyfluorides
Evgeny V. Antipov and Artem M. Abakumov 13.1 Introduction 13.2 Chemical
aspects of fluorination of complex oxides 13.3 Structural aspects of
fluorination of complex cuprates and superconducting properties 13.4
Fluorination of manganites 13.5 Conclusions References 14 Doping Influence
on the Defect Structure and Ionic Conductivity of Fluorine- Containing
Phases Elena I. Ardashnikova, V. A. Prituzhalovand I. B. Kutsenok 14.1
Introduction 14.2 Influence of Oxygen Ions on Fluoride Properties 14.3
Cation Doping of Fluorides 14.4 Active Lone Electron Pair of Cations and
Ionic Conductivity 14.5 Peculiarities of the Defect Structure of
Nonstoichiometric Fluorite-like Phases 14.6 Ionic Transfer in Fluorite-like
Phases 14.7 Peculiarities of the Defect Structure of Nonstoichiometric
Tysonite-like Phases 14.8 Ionic Transfer in Tysonite-like Phases 14.9
Conclusions References 15 Hybrid intercalation compounds containing
perfluoroalkyl groups Yoshiaki Matsuo 15.1 Introduction 15.2 Preparation
and properties of intercalation compounds containing perfluoroalkyl groups
15.3 Photophysical and photochemical properties of dyes in intercalation
compounds containing perfluoroalkyl groups 15.4 Conclusion and future
perspectives References 16 The fluoride route: a good opportunity for the
preparation of 2D and 3D inorganic microporous frameworks Jean-Louis
Paillaud, Philippe Caullet, Jocelyne Brendlé, Angélique Simon- Masseron and
Joël Patarin 16.1 Introduction 16.2 Silica-based microporous materials 16.3
Germanium-based microporous materials 16.4 Phosphate-based microporous
materials 16.5 Synthetic clays 16.6 Conclusion References 17 Access to
Highly Fluorinated Silica by Direct F2 Fluorination Alain Demourgues,
Emilie Lataste, Etienne Durand and Alain Tressaud 17.1 Introduction 17.2
Mesoporous silica and fluorination procedure 17.3 About the chemical
composition and morphology of highly fluorinated silica 17.4 FTIR analysis
17.5 Thermal stability and water affinity of highly fluorinated silica 17.6
NMR investigations 17.7 Conclusions on the F2-gas fluorination mechanism of
mesoporous silica Acknowledgements References 18 Preparation and properties
of rare-earth containing oxide fluoride glasses Susumu Yonezawa, Jae-ho Kim
and Masayuki Takashima 18.1 Introduction 18.2 Preparation and basic
characteristics of oxide fluoride glasses containing LnF3 18.3 Optical and
magnetic properties of LnF3-BaF2-AlF3-GeO2 (SiO2) glasses 18.4 Conclusions
References 19 Switchable hydrophobic-hydrophilic fluorinated layer for
offset processing Alain Tressaud, Christine Labrugère and Etienne Durand
19.1 Introduction 19.2 The principles of lithographic printing process 19.3
Experimental part 19.4 Various types of surface modifications using
fluorinated rf plasmas 19.5 Comparison of surface modifications of porous
alumina using various fluorinated media: CF4, C3F8 and c-C4F8 19.6
Conclusions Acknowledgements References