Marc Monthioux

Carbon Meta-Nanotubes (eBook, ePUB)

Synthesis, Properties and Applications

• Format: ePub

Produktbeschreibung

Meta-Nanotubes are a new generation of carbon nanotubes (CNTs) which result from the chemical transformation of regular CNTs and their subsequent combination with foreign materials (atoms, molecules, chemical groups, nanocrystals) by various ways such as functionalisation, doping, filling, and substitution. These new nanomaterials exhibit enhanced or new properties, such as reactivity, solubility, and magnetism, which pristine CNTs do not possess. Their many applications include electronic and optoelectronic devices, chemical and biosensors, solar cells, drug delivery, and reinforced glasses and ceramics. Carbon Meta-Nanotubes: Synthesis, Properties and Applications discusses these third generation carbon nanotubes and the unique characteristics they possess. Beginning with a general overview of the subject, this book covers the five main categories of meta-nanotubes, namely: * Doped Carbon Nanotubes * Functionalised Carbon Nanotubes * Decorated or Coated Carbon Nanotubes * Filled Carbon Nanotubes * Heterogeneous Nanotubes Providing unparalleled coverage of these third generation or meta-nanotubes, and possibilities for future development, this book is essential for anyone working on carbon nanotubes.

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Produktdetails

• Verlag: John Wiley & Sons
• Seitenzahl: 432
• Erscheinungstermin: 27. Oktober 2011
• Englisch
• ISBN-13: 9781119960942
• Artikelnr.: 37338921

Autorenporträt

Dr. Marc Monthioux is Research Director at the French National Research Institute (CNRS), and is currently working at CEMES (Centre d'Elaboration des Matériaux et d'Etudes Structurales, Toulouse, France). He has been conducting research on carbon-related materials since 1979, including coals, cokes, carbon fibers, composites and even oils and derivatives, from the point of view of structure, texture, nanotexture, and behavior (thermal, mechanical, chemical). He has focused his work on carbon nanotubes and related materials since 1998, when he co-discovered "nanopeapods". He has authored more than 130 articles and chapters in refereed journals and conference proceedings, including contributions to ten books, and is co-inventor of two patents. He is currently one of the Editors of Carbon journal and consultant for companies involved in the carbon business.

Inhaltsangabe

List of Contributors xiii Foreword xv List of Abbreviations xvii
Acknowledgements xxi Introduction to the Meta-Nanotube Book 1 Marc
Monthioux 1 Time for a Third-Generation of Carbon Nanotubes 1 2 Introducing
Meta-Nanotubes 2 2.1 Doped Nanotubes (X:CNTs) 3 2.2 Functionalized
Nanotubes (X-CNTs) 3 2.3 Decorated (Coated) Nanotubes (X /CNTs) 3 2.4
Filled Nanotubes (X@CNTs) 3 2.5 Heterogeneous Nanotubes (X*CNTs) 4 3
Introducing the Meta-Nanotube Book 4 References 5 1 Introduction to Carbon
Nanotubes 7 Marc Monthioux 1.1 Introduction 7 1.2 One Word about
Synthesizing Carbon Nanotubes 7 1.3 SWCNTs: The Perfect Structure 11 1.4
MWCNTs: The Amazing (Nano)Textural Variety 18 1.5 Electronic Structure 29
1.6 Some Properties of Carbon Nanotubes 31 1.7 Conclusion 36 References 36
2 Doped Carbon Nanotubes: (X:CNTs) 41 Alain Pénicaud, Pierre Petit and John
E. Fischer 2.1 Introduction 41 2.1.1 Scope of this Chapter 41 2.1.2 A Few
Definitions 42 2.1.3 Doped/Intercalated Carbon Allotropes - a Brief History
43 2.1.4 What Happens upon Doping SWCNTs? 48 2.2 n-Doping of Nanotubes 52
2.2.1 Synthetic Routes for Preparing Doped SWCNTs 52 2.2.2 Crystalline
Structure and Chemical Composition of n-Doped Nanotubes 54 2.2.3
Modification of the Electronic Structure of SWCNTs upon Doping 59 2.2.4
Electrical Transport in Doped SWCNTs 61 2.2.5 Spectroscopic Evidence for
n-Doping 65 2.2.6 Solutions of Reduced Nanotubes 72 2.3 p-Doping of Carbon
Nanotubes 73 2.3.1 p-Doping of SWCNTs with Halogens 74 2.3.2 p-Doping with
Acceptor Molecules 80 2.3.3 p-Doping of SWCNTs with FeCl3 84 2.3.4 p-Doping
of SWCNTs with SOCl2 87 2.3.5 p-Doping of SWCNTs with Acids 87 2.3.6
p-Doping of SWCNTs with Superacids 91 2.3.7 p-Doping with other Oxidizing
Agents 95 2.3.8 Diameter Selective Doping 96 2.4 Practical Applications of
Doped Nanotubes 99 2.5 Conclusions, Perspectives 100 References 101 3
Functionalized Carbon Nanotubes (X-CNTs) 113 Stéphane Campidelli,
Stanislaus S. Wong and Maurizio Prato 3.1 Introduction 113 3.2
Functionalization Routes 113 3.2.1 Noncovalent Sidewall Functionalization
of SWCNTs 114 3.2.2 Covalent Functionalization of SWCNTs 114 3.3 Properties
and Applications 125 3.3.1 Electron Transfer Properties and Photovoltaic
Applications 125 3.3.2 Chemical Sensors (FET-Based) 137 3.3.3
Opto-Electronic Devices (FET-Based) 139 3.3.4 Biosensors 145 3.4 Conclusion
149 References 150 4 Decorated (Coated) Carbon Nanotubes (X/CNTs) 163
Revathi R. Bacsa and Philippe Serp 4.1 Introduction 163 4.2 Metal-Nanotube
Interactions - Theoretical Aspects 166 4.2.1 Curvature-Induced Effects 168
4.2.2 Effect of Defects and Vacancies on the Metal-Graphite Interactions
169 4.3 Carbon Nanotube Surface Activation 170 4.4 Methods for Carbon
Nanotube Coating 171 4.4.1 Deposition from Solution 171 4.4.2 Self-Assembly
Methods 178 4.4.3 Electro- and Electrophoretic Deposition 183 4.4.4
Deposition from Gas Phase 187 4.4.5 Nanoparticles Decorating Inner Surfaces
of Carbon Nanotubes 190 4.5 Characterization of Decorated Nanotubes 191
4.5.1 Electron Microscopy and X-ray Diffraction 191 4.5.2 Spectroscopic
Methods 192 4.5.3 Porosity and Surface Area 196 4.6 Applications of
Decorated Nanotubes 196 4.6.1 Sensors 196 4.6.2 Catalysis 198 4.6.3 Fuel
Cells 202 4.6.4 Hydrogen Storage 204 4.7 Decorated Nanotubes in Biology and
Medicine 205 4.8 Conclusions and Perspectives 207 References 208 5 Filled
Carbon Nanotubes 223 5.1 Presentation of Chapter 5 223 5a Filled Carbon
Nanotubes: (X@CNTs) 225 Jeremy Sloan and Marc Monthioux 5a.1 Introduction
225 5a.2 Synthesis of X@CNTs 227 5a.2.1 A Glimpse at the Past 227 5a.2.2
The Expectations with Filling CNTs 228 5a.2.3 Filling Parameters, Routes
and Mechanisms 229 5a.2.4 Materials for Filling 240 5a.2.5 Filling
Mechanisms 245 5a.3 Behaviours and Properties 247 5a.3.1 Peculiar in-Tube
Behaviour (Diffusion, Coalescence, Crystallization) 247 5a.3.2 Electronic
Properties (Transport, Magnetism and Others) 252 5a.4 Applications
(Demonstrated or Expected) 256 5a.4.1 Applications that Make Use of Mass
Transport Properties 256 5a.4.2 Applications Arising as a Result of Filling
258 Acknowledgements 261 References 261 5b Fullerenes inside Carbon
Nanotubes: The Peapods 273 F. Simon and Marc Monthioux 5b.1 Introduction
273 5b.2 The Discovery of Fullerene Peapods 274 5b.3 Classification of
Peapods 277 5b.4 Synthesis and Behavior of Fullerene Peapods 279 5b.4.1
Synthesis of Peapods 279 5b.4.2 Behavior of Peapods under Various
Treatments 289 5b.5 Properties of Peapods 295 5b.5.1 Structural Properties
295 5b.5.2 Peapod Band Structure from Theory and Experiment 298 5b.5.3
Transport Properties 301 5b.5.4 Optical Properties 302 5b.5.5 Vibrational
Properties 303 5b.5.6 Magnetic Properties 305 5b.6 Applications of Peapods
308 5b.6.1 Demonstrated Applications 308 5b.6.2 Expected Applications 310
Acknowledgements 314 References 314 6 Heterogeneous Nanotubes (X*CNTs,
X*BNNTs) 323 Dmitri Golberg, Mauricio Terrones 6.1 Overall Introduction 323
6.2 Pure BN Nanotubes 324 6.2.1 Introduction 324 6.2.2 Synthesis of BN
Nanotubes 325 6.2.3 Morphology and Structure of BN Nanotubes 331 6.2.4
Properties of BN Nanotubes 337 6.2.5 Stability of BN Nanotubes to
High-Energy Irradiation 346 6.2.6 Boron Nitride Meta-Nanotubes 346 6.2.7
Other BN Nanomaterials 353 6.2.8 Challenging Applications 355 6.3 BxCyNz
Nanotubes and Nanofibers 359 6.3.1 Tuning the Electronic Structure with
C-Substituted BN Nanotubes 359 6.3.2 Production and Characterization of
BxCyNz Nanotubes and Nanofibers 362 6.4 B-Substituted or N-Substituted
Carbon Nanotubes 368 6.4.1 Substituting Carbon Nanotubes with B or N 368
6.4.2 Synthesis Strategies for Producing Bor N-Substituted CNTs 370 6.4.3
Morphology and Structure of Substituted CNTs 374 6.4.4 Properties of
Substituted CNTs 379 6.4.5 Applications of Substituted CNTs 385 6.5
Perspectives and Future Outlook 392 Acknowledgements 394 References 395
Index

Rezensionen

"The variations are exhaustively described and well-supported with clear illustrations. The book should be considered an essential reference for professionals working in fields related to carbon nanotubes." (Book News, 1 April 2012)