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Tin chemistry retains a place in contemporary science as an important element owing to its wide range of applications. New and exciting research is being generated on an annual basis from all parts of the world - the study of tin and its compounds attracts considerable interest from a range of perspectives such as organic synthesis, medicine, materials chemistry, catalysis and environment. Tin Chemistry - Fundamentals, Frontiers and Applications collects, in one comprehensive volume, authoritative and concise snapshots of modern tin chemistry in a full range of applications. Over forty of the…mehr
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Tin chemistry retains a place in contemporary science as an important element owing to its wide range of applications. New and exciting research is being generated on an annual basis from all parts of the world - the study of tin and its compounds attracts considerable interest from a range of perspectives such as organic synthesis, medicine, materials chemistry, catalysis and environment. Tin Chemistry - Fundamentals, Frontiers and Applications collects, in one comprehensive volume, authoritative and concise snapshots of modern tin chemistry in a full range of applications. Over forty of the leading tin chemistry experts have contributed reviews in six themes: * fundamentals in tin chemistry * materials chemistry and structural chemistry of tin compounds * medicinal and biocidal applications of tin compounds * tin in the environment * tin in organic synthesis * tin in catalysis Tin Chemistry - Fundamentals, Frontiers and Applications is an essential overview of modern perspectives on this important element for the specialist and non-specialist alike. It will promote cross-disciplinary interactions and at the same time be an essential teaching resource for advanced university classes.
Produktdetails
- Produktdetails
- Verlag: John Wiley & Sons
- Seitenzahl: 752
- Erscheinungstermin: 15. September 2008
- Englisch
- ISBN-13: 9780470758083
- Artikelnr.: 37299274
- Verlag: John Wiley & Sons
- Seitenzahl: 752
- Erscheinungstermin: 15. September 2008
- Englisch
- ISBN-13: 9780470758083
- Artikelnr.: 37299274
Professor Alwyn Davies, FRS, University College London, UK Professor Davies is the author of Organotin Chemistry (Wiley-VCH, 2nd Edition 2004) and editor-in-chief of Journal of Chemical Research and Science Reviews. Professor Marcel Gielen, Vrije Universiteit Brussel, Belgium Professor Gielen is the author of several organometallic books and editor of the journals Main Group Metal Chemistry and Applied Organometallic Chemistry. Professor Keith Pannell, University of Texas at El Paso, USA Professor Pannell has published over 200 articles in the international literature in the general area of main group chemistry. Professor Edward Tiekink, University of Texas at San Antonio, USA Professor Tiekink serves as co/associate editor for Acta Crystallographica E, Applied Organometallic Chemistry, Bioinorganic Chemistry & Applications, and Zeitschrift fur Kristallographie.
1. Introduction and overview (A. G. Davies). 2. Fundamentals in tin
chemistry. 2.1 NMR of tin compounds (Bernd Wrackmeyer). 2.2 Sn(II) clusters
(Tris Chivers and Dana Eisler). 2.3 Monorganotin oxo-clusters (François
Ribot). 2.4 Organotin carboxylate and -sulfonate clusters (Vadapalli Chand
Rasekhar). 2.5 Macrocyclic and supramolecular chemistry of organotin
compounds (Herbert Höpfl). 2.6 Tin Zintl Ions: Synthesis, Structures, and
Reactivity (Slavi Sevov). 2.7 Stable stannyl cations in condensed phase
(Joe Lambert). 2.8 Preparation and coordination chemistry of mono- and
bidentate stannylenes (Alexander V. Zabula and F. Ekkehardt Hahn). 2.9
Stannenes, distannenes and stannynes (Norihiro Tokitoh and Yoshiyuki
Mizuhata). 2.10 Distannoxanes (Klaus Jurkschat). 2.11 Unusual bonds and
coordination geometries (Raymundo Cea-Olivares). 2.12 Tin(II)
heterobimetallic and oligometallic derivatives (Muhammad Mazhar). 2.13
Computational Methods for Organotin Compounds (Sarah Whittleton, Russell J.
Boyd, and T. Bruce Grindley). 3. Materials Chemistry and Structural
Chemistry of tin compounds. 3.1 Tin compounds for CVD (Geraldo Lima). 3.2
Class II Tin-Based Hybrid Materials Prepared From Alkynyltin Precursors
(Thierry Toupance). 3.3 Organotin compounds as PVC stabilizers (Esen
Arkis). 3.4 Organotin compounds as anion-selective carriers in chemical
sensors (Nikos Chaniotakis). 3.5 Tin compounds as flame retardants and
smoke suppressants (Paul Cusack). 3.6 Quadratic nonlinear optical
properties in tin-based compounds (Pascal G. Lacroix). 3.7 Tin-based hybrid
materials (Bernard Jousseaume). 3.8 Organotin polymers and related
materials (Keith Pannell and Sharma). 3.9 Intermolecular tin...À-aryl
interactions: fact or artifact*? A new bonding motif for supramolecular
self-assembly in organotin compounds (Ionel Haiduc, Edward Tiekink and
Julio Zukerman-Schpector). 4. Medicinal/Biocidal Applications of tin
compounds and Environmental Aspects. 4.1 The cardiovascular activity of
organotin compounds (Mala Nath). 4.2 Organotins: Insecticidal and
larvicidal activity (George Eng and Xueqing Song). 4.3 Antifungal activity
of organotin compounds (Heloisa Beraldo and Geraldo M. de Lima). 4.4
Chemical and biotechnological developments in organotin cancer chemotherapy
(Claudio Pettinariÿ and Fabio Marchetti). 4.5 Impact of organotin compounds
on the function of human natural killer cells (Margaret M. Whalen). 4.6
Biological aspects of organotins: perspective in structural and molecular
biology (Norberto Farfán, Hiram Beltran and Rosa Santillan). 5. Tin in
Organic Synthesis. 5.1 Applications of Organotin Derivatives for
Carbohydrate Synthesis (T. Bruce Grindley). 5.2 Reactions of SE?
Substitution for Organostannanes in Organic Synthesis (David R. Williams
and Partha P. Nag). 5.3 Organotin compounds for Carbon-Carbon
Cross-Coupling (Pablo Espinet and Miroslav Genov). 5.4 Cross-Coupling of
Organotin compounds for Carbon-Carbon Bond Formation: Applications in Total
Synthesis (Antonio Echavarren). 5.5 New Trends in the Synthesis of
Solid-Supported Organotin Reagents and Interest of their Use in Organic
Synthesis in a Concept of Green Chemistry (Jean-Mathieu Chrétien, Jeremy D.
Kilburn, Françoise Zammattio, Erwan Le Grognec and Jean-Paul Quintard). 5.6
Palladium Catalysed Cascade Cyclisation-Anion Capture Processes Employing
Pre- and In Situ-Formed Organostannanes (Ronald Grigg and V. Sridharan).
5.7 Carbostannylations of carbon-carbon unsaturated bonds (Eiji Shirakawa).
5.8 Green Organostannane Chemistry: an Oxymoron (David Young)? 6. Tin in
Catalysis. 6.1 Green organotin catalysts (Junzo Otera, Monique Biesemans,
Vanja Pinoie, Kevin Poelmans and Rudolph Willem). 6.2 Organotin catalysts
for isocyanate reactions (Werner J. Blank and Edward T. Hessell). 6.3
Catalysis of reactions of allyltin compounds and organotin phenoxides by
lithium perchlorate (Wojciech J. Kinart and Cezary M. Kinart).
chemistry. 2.1 NMR of tin compounds (Bernd Wrackmeyer). 2.2 Sn(II) clusters
(Tris Chivers and Dana Eisler). 2.3 Monorganotin oxo-clusters (François
Ribot). 2.4 Organotin carboxylate and -sulfonate clusters (Vadapalli Chand
Rasekhar). 2.5 Macrocyclic and supramolecular chemistry of organotin
compounds (Herbert Höpfl). 2.6 Tin Zintl Ions: Synthesis, Structures, and
Reactivity (Slavi Sevov). 2.7 Stable stannyl cations in condensed phase
(Joe Lambert). 2.8 Preparation and coordination chemistry of mono- and
bidentate stannylenes (Alexander V. Zabula and F. Ekkehardt Hahn). 2.9
Stannenes, distannenes and stannynes (Norihiro Tokitoh and Yoshiyuki
Mizuhata). 2.10 Distannoxanes (Klaus Jurkschat). 2.11 Unusual bonds and
coordination geometries (Raymundo Cea-Olivares). 2.12 Tin(II)
heterobimetallic and oligometallic derivatives (Muhammad Mazhar). 2.13
Computational Methods for Organotin Compounds (Sarah Whittleton, Russell J.
Boyd, and T. Bruce Grindley). 3. Materials Chemistry and Structural
Chemistry of tin compounds. 3.1 Tin compounds for CVD (Geraldo Lima). 3.2
Class II Tin-Based Hybrid Materials Prepared From Alkynyltin Precursors
(Thierry Toupance). 3.3 Organotin compounds as PVC stabilizers (Esen
Arkis). 3.4 Organotin compounds as anion-selective carriers in chemical
sensors (Nikos Chaniotakis). 3.5 Tin compounds as flame retardants and
smoke suppressants (Paul Cusack). 3.6 Quadratic nonlinear optical
properties in tin-based compounds (Pascal G. Lacroix). 3.7 Tin-based hybrid
materials (Bernard Jousseaume). 3.8 Organotin polymers and related
materials (Keith Pannell and Sharma). 3.9 Intermolecular tin...À-aryl
interactions: fact or artifact*? A new bonding motif for supramolecular
self-assembly in organotin compounds (Ionel Haiduc, Edward Tiekink and
Julio Zukerman-Schpector). 4. Medicinal/Biocidal Applications of tin
compounds and Environmental Aspects. 4.1 The cardiovascular activity of
organotin compounds (Mala Nath). 4.2 Organotins: Insecticidal and
larvicidal activity (George Eng and Xueqing Song). 4.3 Antifungal activity
of organotin compounds (Heloisa Beraldo and Geraldo M. de Lima). 4.4
Chemical and biotechnological developments in organotin cancer chemotherapy
(Claudio Pettinariÿ and Fabio Marchetti). 4.5 Impact of organotin compounds
on the function of human natural killer cells (Margaret M. Whalen). 4.6
Biological aspects of organotins: perspective in structural and molecular
biology (Norberto Farfán, Hiram Beltran and Rosa Santillan). 5. Tin in
Organic Synthesis. 5.1 Applications of Organotin Derivatives for
Carbohydrate Synthesis (T. Bruce Grindley). 5.2 Reactions of SE?
Substitution for Organostannanes in Organic Synthesis (David R. Williams
and Partha P. Nag). 5.3 Organotin compounds for Carbon-Carbon
Cross-Coupling (Pablo Espinet and Miroslav Genov). 5.4 Cross-Coupling of
Organotin compounds for Carbon-Carbon Bond Formation: Applications in Total
Synthesis (Antonio Echavarren). 5.5 New Trends in the Synthesis of
Solid-Supported Organotin Reagents and Interest of their Use in Organic
Synthesis in a Concept of Green Chemistry (Jean-Mathieu Chrétien, Jeremy D.
Kilburn, Françoise Zammattio, Erwan Le Grognec and Jean-Paul Quintard). 5.6
Palladium Catalysed Cascade Cyclisation-Anion Capture Processes Employing
Pre- and In Situ-Formed Organostannanes (Ronald Grigg and V. Sridharan).
5.7 Carbostannylations of carbon-carbon unsaturated bonds (Eiji Shirakawa).
5.8 Green Organostannane Chemistry: an Oxymoron (David Young)? 6. Tin in
Catalysis. 6.1 Green organotin catalysts (Junzo Otera, Monique Biesemans,
Vanja Pinoie, Kevin Poelmans and Rudolph Willem). 6.2 Organotin catalysts
for isocyanate reactions (Werner J. Blank and Edward T. Hessell). 6.3
Catalysis of reactions of allyltin compounds and organotin phenoxides by
lithium perchlorate (Wojciech J. Kinart and Cezary M. Kinart).
1. Introduction and overview (A. G. Davies). 2. Fundamentals in tin
chemistry. 2.1 NMR of tin compounds (Bernd Wrackmeyer). 2.2 Sn(II) clusters
(Tris Chivers and Dana Eisler). 2.3 Monorganotin oxo-clusters (François
Ribot). 2.4 Organotin carboxylate and -sulfonate clusters (Vadapalli Chand
Rasekhar). 2.5 Macrocyclic and supramolecular chemistry of organotin
compounds (Herbert Höpfl). 2.6 Tin Zintl Ions: Synthesis, Structures, and
Reactivity (Slavi Sevov). 2.7 Stable stannyl cations in condensed phase
(Joe Lambert). 2.8 Preparation and coordination chemistry of mono- and
bidentate stannylenes (Alexander V. Zabula and F. Ekkehardt Hahn). 2.9
Stannenes, distannenes and stannynes (Norihiro Tokitoh and Yoshiyuki
Mizuhata). 2.10 Distannoxanes (Klaus Jurkschat). 2.11 Unusual bonds and
coordination geometries (Raymundo Cea-Olivares). 2.12 Tin(II)
heterobimetallic and oligometallic derivatives (Muhammad Mazhar). 2.13
Computational Methods for Organotin Compounds (Sarah Whittleton, Russell J.
Boyd, and T. Bruce Grindley). 3. Materials Chemistry and Structural
Chemistry of tin compounds. 3.1 Tin compounds for CVD (Geraldo Lima). 3.2
Class II Tin-Based Hybrid Materials Prepared From Alkynyltin Precursors
(Thierry Toupance). 3.3 Organotin compounds as PVC stabilizers (Esen
Arkis). 3.4 Organotin compounds as anion-selective carriers in chemical
sensors (Nikos Chaniotakis). 3.5 Tin compounds as flame retardants and
smoke suppressants (Paul Cusack). 3.6 Quadratic nonlinear optical
properties in tin-based compounds (Pascal G. Lacroix). 3.7 Tin-based hybrid
materials (Bernard Jousseaume). 3.8 Organotin polymers and related
materials (Keith Pannell and Sharma). 3.9 Intermolecular tin...À-aryl
interactions: fact or artifact*? A new bonding motif for supramolecular
self-assembly in organotin compounds (Ionel Haiduc, Edward Tiekink and
Julio Zukerman-Schpector). 4. Medicinal/Biocidal Applications of tin
compounds and Environmental Aspects. 4.1 The cardiovascular activity of
organotin compounds (Mala Nath). 4.2 Organotins: Insecticidal and
larvicidal activity (George Eng and Xueqing Song). 4.3 Antifungal activity
of organotin compounds (Heloisa Beraldo and Geraldo M. de Lima). 4.4
Chemical and biotechnological developments in organotin cancer chemotherapy
(Claudio Pettinariÿ and Fabio Marchetti). 4.5 Impact of organotin compounds
on the function of human natural killer cells (Margaret M. Whalen). 4.6
Biological aspects of organotins: perspective in structural and molecular
biology (Norberto Farfán, Hiram Beltran and Rosa Santillan). 5. Tin in
Organic Synthesis. 5.1 Applications of Organotin Derivatives for
Carbohydrate Synthesis (T. Bruce Grindley). 5.2 Reactions of SE?
Substitution for Organostannanes in Organic Synthesis (David R. Williams
and Partha P. Nag). 5.3 Organotin compounds for Carbon-Carbon
Cross-Coupling (Pablo Espinet and Miroslav Genov). 5.4 Cross-Coupling of
Organotin compounds for Carbon-Carbon Bond Formation: Applications in Total
Synthesis (Antonio Echavarren). 5.5 New Trends in the Synthesis of
Solid-Supported Organotin Reagents and Interest of their Use in Organic
Synthesis in a Concept of Green Chemistry (Jean-Mathieu Chrétien, Jeremy D.
Kilburn, Françoise Zammattio, Erwan Le Grognec and Jean-Paul Quintard). 5.6
Palladium Catalysed Cascade Cyclisation-Anion Capture Processes Employing
Pre- and In Situ-Formed Organostannanes (Ronald Grigg and V. Sridharan).
5.7 Carbostannylations of carbon-carbon unsaturated bonds (Eiji Shirakawa).
5.8 Green Organostannane Chemistry: an Oxymoron (David Young)? 6. Tin in
Catalysis. 6.1 Green organotin catalysts (Junzo Otera, Monique Biesemans,
Vanja Pinoie, Kevin Poelmans and Rudolph Willem). 6.2 Organotin catalysts
for isocyanate reactions (Werner J. Blank and Edward T. Hessell). 6.3
Catalysis of reactions of allyltin compounds and organotin phenoxides by
lithium perchlorate (Wojciech J. Kinart and Cezary M. Kinart).
chemistry. 2.1 NMR of tin compounds (Bernd Wrackmeyer). 2.2 Sn(II) clusters
(Tris Chivers and Dana Eisler). 2.3 Monorganotin oxo-clusters (François
Ribot). 2.4 Organotin carboxylate and -sulfonate clusters (Vadapalli Chand
Rasekhar). 2.5 Macrocyclic and supramolecular chemistry of organotin
compounds (Herbert Höpfl). 2.6 Tin Zintl Ions: Synthesis, Structures, and
Reactivity (Slavi Sevov). 2.7 Stable stannyl cations in condensed phase
(Joe Lambert). 2.8 Preparation and coordination chemistry of mono- and
bidentate stannylenes (Alexander V. Zabula and F. Ekkehardt Hahn). 2.9
Stannenes, distannenes and stannynes (Norihiro Tokitoh and Yoshiyuki
Mizuhata). 2.10 Distannoxanes (Klaus Jurkschat). 2.11 Unusual bonds and
coordination geometries (Raymundo Cea-Olivares). 2.12 Tin(II)
heterobimetallic and oligometallic derivatives (Muhammad Mazhar). 2.13
Computational Methods for Organotin Compounds (Sarah Whittleton, Russell J.
Boyd, and T. Bruce Grindley). 3. Materials Chemistry and Structural
Chemistry of tin compounds. 3.1 Tin compounds for CVD (Geraldo Lima). 3.2
Class II Tin-Based Hybrid Materials Prepared From Alkynyltin Precursors
(Thierry Toupance). 3.3 Organotin compounds as PVC stabilizers (Esen
Arkis). 3.4 Organotin compounds as anion-selective carriers in chemical
sensors (Nikos Chaniotakis). 3.5 Tin compounds as flame retardants and
smoke suppressants (Paul Cusack). 3.6 Quadratic nonlinear optical
properties in tin-based compounds (Pascal G. Lacroix). 3.7 Tin-based hybrid
materials (Bernard Jousseaume). 3.8 Organotin polymers and related
materials (Keith Pannell and Sharma). 3.9 Intermolecular tin...À-aryl
interactions: fact or artifact*? A new bonding motif for supramolecular
self-assembly in organotin compounds (Ionel Haiduc, Edward Tiekink and
Julio Zukerman-Schpector). 4. Medicinal/Biocidal Applications of tin
compounds and Environmental Aspects. 4.1 The cardiovascular activity of
organotin compounds (Mala Nath). 4.2 Organotins: Insecticidal and
larvicidal activity (George Eng and Xueqing Song). 4.3 Antifungal activity
of organotin compounds (Heloisa Beraldo and Geraldo M. de Lima). 4.4
Chemical and biotechnological developments in organotin cancer chemotherapy
(Claudio Pettinariÿ and Fabio Marchetti). 4.5 Impact of organotin compounds
on the function of human natural killer cells (Margaret M. Whalen). 4.6
Biological aspects of organotins: perspective in structural and molecular
biology (Norberto Farfán, Hiram Beltran and Rosa Santillan). 5. Tin in
Organic Synthesis. 5.1 Applications of Organotin Derivatives for
Carbohydrate Synthesis (T. Bruce Grindley). 5.2 Reactions of SE?
Substitution for Organostannanes in Organic Synthesis (David R. Williams
and Partha P. Nag). 5.3 Organotin compounds for Carbon-Carbon
Cross-Coupling (Pablo Espinet and Miroslav Genov). 5.4 Cross-Coupling of
Organotin compounds for Carbon-Carbon Bond Formation: Applications in Total
Synthesis (Antonio Echavarren). 5.5 New Trends in the Synthesis of
Solid-Supported Organotin Reagents and Interest of their Use in Organic
Synthesis in a Concept of Green Chemistry (Jean-Mathieu Chrétien, Jeremy D.
Kilburn, Françoise Zammattio, Erwan Le Grognec and Jean-Paul Quintard). 5.6
Palladium Catalysed Cascade Cyclisation-Anion Capture Processes Employing
Pre- and In Situ-Formed Organostannanes (Ronald Grigg and V. Sridharan).
5.7 Carbostannylations of carbon-carbon unsaturated bonds (Eiji Shirakawa).
5.8 Green Organostannane Chemistry: an Oxymoron (David Young)? 6. Tin in
Catalysis. 6.1 Green organotin catalysts (Junzo Otera, Monique Biesemans,
Vanja Pinoie, Kevin Poelmans and Rudolph Willem). 6.2 Organotin catalysts
for isocyanate reactions (Werner J. Blank and Edward T. Hessell). 6.3
Catalysis of reactions of allyltin compounds and organotin phenoxides by
lithium perchlorate (Wojciech J. Kinart and Cezary M. Kinart).