Jiro Tsuji

Palladium Reagents and Catalysts

Innovations in Organic Synthesis

• Broschiertes Buch

Produktbeschreibung

Palladium ist das Übergangsmetall, dessen Anwendungsmöglichkeiten in der organischen Synthese am breitesten gefächert sind. Dieser Band gibt einen vollständigen Überblick über die Erkenntnisse der Palladiumchemie der letzten 35 Jahre und behandelt viele innovative Synthesemethoden. Die Reaktionen sind übersichtlich nach ihrem Mechanismus klassifiziert; ergänzt wird das Werk durch umfangreiche Literaturangaben.

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Palladium Reagents and Catalysts Innovations in Organic Synthesis Jiro Tsuji Okayama University of Science, Okayama, Japan Palladium Reagents and Catalysts brings to synthetic organic chemists the many applications of organopalladium chemistry, highlighting the most recent discoveries in this rapidly expanding field. This volume provides a comprehensive overview of the development of many innovative synthetic methods, using palladium reagents either as catalysts or stoichiometric reagents. Palladium is the most versatile of the transition metals used in organic synthesis and knowledge of this rapidly expanding and challenging area is essential for all synthetic organic chemists. Palladium Reagents and Catalysts fulfils, systematically and efficiently, the urgent need for understanding the essence of organopalladium chemistry.

Produktdetails

• Verlag: Wiley & Sons
• Revised edition
• Seitenzahl: 574
• Erscheinungstermin: 4. März 1997
• Englisch
• Abmessung: 229mm x 152mm x 31mm
• Gewicht: 798g
• ISBN-13: 9780471972020
• ISBN-10: 0471972029
• Artikelnr.: 09455627

Autorenporträt

Jiro Tsuji, Okayama University of Science, Okayama, Japan, is the author of Palladium Reagents and Catalysts: Innovations in Organic Synthesis, published by Wiley.

Inhaltsangabe

From the contents: The Basic Chemistry of Organopalladium Compounds. Classification of the Reactions Involving Pd(II) Compounds and Pd(0) Complexes in This Book. Oxidative Reactions with Pd(II) Compounds. Catalytic Reactions with Pd(0) and Pd(II). Various Reactions Catalyzed by Pd(II) and Pd(0). Index.Aus dem Inhalt: The Basic Chemistry of Organopalladium Compounds;. Classification of the reactions; Oxidation Reactions; Catalytic Reactions; Various reactions catalysed by Pd (II) and Pd(0).

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Preface. Abbreviations. 1 The Basic Chemistry of Organopalladium Compounds.
1.1 Characteristic Features of Pd-Promoted or -Catalyzed Reactions. 1.2
Palladium Compounds, Complexes, and Ligands Widely Used in Organic
Synthesis. 1.3 Fundamental Reactions of Pd Compounds. References. 2
Oxidative Reactions with Pd(II) Compounds. 2.1 Introduction. 2.2 Reactions
of Alkenes. 2.3 Stoichiometric Reactions of Pi-Allyl Complexes. 2.4
Reactions of Conjugated Dienes. 2.5 Reactions of Allenes. 2.6 Reaction of
Alkynes. 2.7 Homocoupling and Oxidative Substitution Reactions of Aromatic
Compounds. 2.8 Regioselective Reactions Based on Chelation and
Participation of Heteroatoms. 2.9 Oxidative Carbonylation of Alcohols and
Amines. 2.10 Oxidation of Alcohols. 2.11 Enone Formation from Ketones and
Cycloalkenylation. References. 3 Pd(0)-Catalyzed Reactions of sp2Organic
Halides and Pseudohalides. 3.1 Introduction. 3.2 Reactions with Alkenes
(Mizoroki-Heck Reaction). References. 3.3 Reactions of Aromatics and
Heteroaromatics. References. 3.4 Reactions with Alkynes. References.
References. 3.5 Carbonylation and Reactions of Acyl Chlorides. References.
3.6 Cross-Coupling Reactions with Organometallic Compounds of the Main
Group Metals via Transmetallation. References. References. 3.7 Arylation
and Alkenylation of C, N, O, S, and P Nucleophiles. References. References.
References. References. 3.8 Miscellaneous Reactions of Aryl Halides.
References. References. References. 4 Pd(0)-Catalyzed Reactions of Allylic
Compounds via Pi-Allylpalladium Complexes. 4.1 Introduction and Range of
Leaving Groups. 4.2 Allylation. 4.3 Reactions with Main Group
Organometallic Compounds via Transmetallation. 4.4 Carbonylation Reactions.
4.5 Intramolecular Reactions with Alkenes and Alkynes. 4.6 Hydrogenolysis
of Allylic Compounds. 4.7 Allyl Group as a Protecting Group. 4.8
1,4-Elimination. 4.9 Reactions via Pi-Allylpalladium Enolates. 4.10 Pd(0)
and Pd(II)-Catalyzed Allylic Rearrangement. 4.11 Reactions of
2,3-Alkadienyl Derivatives via Methylene-Pi-allylpalladiums. References. 5
Pd(0)-Catalyzed Reactions of 1,3-Dienes, 1,2-Dienes (Allenes), and
Methylenecyclopropanes. 5.1 Reactions of Conjugated Dienes. 5.2 Reactions
of Allenes. 5.3 Reactions of Methylenecyclopropanes. References. 6
Pd(0)-Catalyzed Reactions of Propargyl Compounds. 6.1 Introduction and
Classification of Reactions. 6.2 Reactions via Insertion of Alkenes and
Alkynes. 6.3 Carbonylations. 6.4 Reactions of Main Group Metal Compounds.
6.5 Reactions of Terminal Alkynes; Formation of 1,2-Alkadien-4-ynes. 6.6
Reactions of Nucleophiles on Central sp Carbon of Allenylpalladium
Intermediates. 6.7 Hydrogenolysis and Elimination of Propargyl Compounds.
References. 7 Pd(0)- and Pd(II)-Catalyzed Reactions of Alkynes and
Benzynes. 7.1 Reactions of Alkynes. 7.2 Reactions of Benzynes. 8
Pd(0)-Catalyzed Reactions of Alkenes. 8.1 Carbonylation. 8.2
Hydroamination. 8.3 Hydrometallation. 8.4 Miscellaneous Reactions.
References. 9 Pd(0)-Catalyzed Miscellaneous Reactions of Carbon Monoxide.
References. 10 Miscellaneous Reactions Catalyzed by Chiral and Achiral
Pd(II) Complexes. References. Tables 1.1 to 1.18. Index.

Rezensionen

"...amazing that a single book of such scope could actually be written...achieved just the right balance..." (www.organische-chemie.ch, 08 June 2004) "...For the modest price, this book should find its way onto the shelves of all good chemistry libraries..." (Chemistry & Industry, No.22 15 th November, 2004) "This book is beautifully illustrated, very well referenced and covers a wide range of exciting synthetic methods.....". (Applied Organometallic Chemistry, March 2005)