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An expert overview of current research, applications, and economic and environmental advantages The study and development of new homogeneous catalysts based on first-row metals (Mn, Fe, Co, Ni, and Cu) has grown significantly due to the economic and environmental advantages that non-noble metals present. Base metals offer reduced cost, greater supply, and lower toxicity levels than noble metals-enabling greater opportunity for scientific investigation and increased development of practical applications. Non-Noble Metal Catalysis provides an authoritative survey of the field, from fundamental…mehr
An expert overview of current research, applications, and economic and environmental advantages The study and development of new homogeneous catalysts based on first-row metals (Mn, Fe, Co, Ni, and Cu) has grown significantly due to the economic and environmental advantages that non-noble metals present. Base metals offer reduced cost, greater supply, and lower toxicity levels than noble metals-enabling greater opportunity for scientific investigation and increased development of practical applications. Non-Noble Metal Catalysis provides an authoritative survey of the field, from fundamental concepts and computational methods to industrial applications and reaction classes. Recognized experts in organometallic chemistry and homogeneous catalysis, the authors present a comprehensive overview of the conceptual and practical aspects of non-noble metal catalysts. Examination of topics including non-innocent ligands, proton-coupled electron transfer, and multi-nuclear complexes provide essential background information, while areas such as kinetic lability and lifetimes of intermediates reflect current research and shifting trends in the field. This timely book demonstrates the efficacy of base metal catalysts in the pharmaceutical, fine-chemical, and agrochemical industries, addressing both environmental and economic concerns. Providing essential conceptual and practical exploration, this valuable resource: -Illustrates how unravelling new reactivity patterns can lead to new catalysts and new applications -Highlights the multiple advantages of using non-noble metals in homogenous catalysis -Demonstrates how the availability of non-noble metal catalysis reduces costs and leads to immense savings for the chemical industry -Reveals how non-noble metal catalysis are more sustainable than noble metals such as palladium or platinum Non-Noble Metal Catalysis: Molecular Approaches and Reactions is an indispensable source of up-to-date information for catalytic chemists, organic chemists, industrial chemists, organometallic chemists, and those seeking to broaden their knowledge of catalytic chemistry.
Bert Klein Gebbink, PhD, is full professor at Utrecht University, The Netherlands. His current research interests include homogeneous catalysis, organometallic chemistry, and bioinorganic chemistry, with a specific focus on iron-based catalysis, the immobilization of homogeneous catalysts and the catalytic conversion of biomass into chemical building blocks. Marc-Etienne Moret, MSc, is assistant professor at Utrecht University, The Netherlands. His research interests lie in the organometallic chemistry of base metals with the aim of using these cheap, nontoxic metals to promote (in)organic transformations of environmental / industrial significance.
Inhaltsangabe
Preface APPLICATION OF STIMULI-RESPONSIVE AND "NON-INNOCENT" LIGANDS IN BASE METAL CATALYSIS Introduction Stimuli-Responsive Ligands Redox-Active Ligands as Electron Reservoirs Cooperative Ligands Substrate Radicals in Catalysis Summary and Conclusions COMPUTATIONAL INSIGHTS INTO CHEMICAL REACTIVITY AND ROAD TO CATALYST DESIGN: THE PARADIGM OF CO2 HYDROGENATION Introduction Reaction Energetics and Governing Factor Newly Designed Catalysts and Their Reactivity Correlation Between Hydricity and Reactivity Concluding Remarks CATALYSIS WITH MULTINUCLEAR COMPLEXES Introduction Stoichiometric Reaction Pathways Application in Catalysis Polynuclear Complexes Outlook COPPER-CATALYZED HYDROGENATIONS AND AEROBIC N-N BOND FORMATIONS: ACADEMIC DEVELOPMENTS AND INDUSTRIAL RELEVANCE Introduction Cu-Promoted N-N Bond Formation Cu-Catalyzed Homogeneous Hydrogenation Conclusions C=C HYDROGENATIONS WITH IRON GROUP METAL CATALYSTS Introduction Iron Cobalt Nickel Conclusion BASE METAL-CATALYZED ADDITION REACTIONS ACROSS C-C MULTIPLE BONDS Introduction Catalytic Addition to Alkenes Initiated Through Radical Mechanism Other Catalytic Additions to Unsaturated Bonds Proceeding Through Initial R· (R¿H) Attack Catalytic Addition to Alkenes Initiated Through Polar Mechanisms Hydrosilylation Reactions Conclusion IRON-CATALYZED CYCLOPROPANATION OF ALKENES BY CARBENE TRANSFER REACTIONS Introduction Achiral Iron Porphyrin Catalysts Iron Phthalocyanines and Corroles Iron Catalystswith N or N,OLigands The [Cp(CO)2FeII(THF)]BF4 Catalyst Conclusions NOVEL SUBSTRATES AND NUCLEOPHILES IN ASYMMETRIC COPPER-CATALYZED CONJUGATE ADDITION REACTIONS Introduction Catalytic Asymmetric Conjugate Additions to Alpha-Substituted Alpha,Beta-Unsaturated Carbonyl Compounds Catalytic Asymmetric Conjugate Additions to Alkenyl-Heteroarenes Conclusion ASYMMETRIC REDUCTION OF POLAR DOUBLE BONDS Introduction Manganese Iron Cobalt Nickel Copper Conclusion IRON-, COBALT-, AND MANGANESE-CATALYZED HYDROSILYLATION OF CARBONYL COMPOUNDS AND CARBON DIOXIDE Introduction Hydrosilylation of Aldehydes and Ketones Reduction of Imines and Reductive Amination of Carbonyl Compounds Reduction of Carboxylic Acid Derivatives Hydroelementation of Carbon Dioxide Conclusion REACTIVE INTERMEDIATES AND MECHANISM IN IRON-CATALYZED CROSS-COUPLING Introduction Cross-Coupling Catalyzed by Simple Iron Salts TMEDA in Iron-Catalyzed Cross-Coupling NHCs in Iron-Catalyzed Cross-Coupling Phosphines in Iron-Catalyzed Cross-Coupling Future Outlook RECENT ADVANCES IN COBALT-CATALYZED CROSS-COUPLING REACTIONS Introduction Cobalt-Catalyzed C-C Coupling Through a C-H Activation Approach Cobalt-Catalyzed C-C Couplings Using a Preactivated Substrate Approach (Aryl Halides and Pseudohalides) Cobalt-Catalyzed C-X Couplings Using C-H Activation Approaches Cobalt-Catalyzed C-X Couplings Using a Preactivated Substrate Approach (Aryl Halides and Pseudohalides) Miscellaneous Conclusions and Future Prospects TRIFLUOROMETHYLATION AND RELATED REACTIONS Trifluoromethylation Reactions Trifluoromethylthiolation Reactions Perfluoroalkylation Reactions Conclusion CATALYTIC OXYGENATION OF C=C AND C-H BONDS Introduction Oxygenation of C=C Bonds Oxygenation of C-H Bonds Conclusions and Outlook ORGANOMETALLIC CHELATION-ASSISTED C-H FUNCTIONALIZATION Introduction C-C Bond Formation via C-H Activation C-Heteroatom Formation via C-H Activation Conclusions CATALYTIC WATER OXIDATION: WATER OXIDATION TO O2 MEDIATED BY 3D TRANSITION METAL COMPLEXES Water Oxidation - From Insights into Fundamental Chemical Concepts to Future Solar Fuels ModelWell-DefinedWater Oxidation Catalysts Conclusion and Outlook BASE-METAL-CATALYZED HYDROGEN GENERATION FROM CARBON- AND BORON NITROGEN-BASED SUBSTRATES Introduction Hydrogen Generation from Formic Acid Hydrogen Generation from Alcohols Hydrogen Storage in Liquid Organic Hydrogen Carriers Dehydrogenation of Ammonia Borane and Amine Boranes Conclusion MOLECULAR CATALYSTS FOR PROTON REDUCTION BASED
Preface APPLICATION OF STIMULI-RESPONSIVE AND "NON-INNOCENT" LIGANDS IN BASE METAL CATALYSIS Introduction Stimuli-Responsive Ligands Redox-Active Ligands as Electron Reservoirs Cooperative Ligands Substrate Radicals in Catalysis Summary and Conclusions COMPUTATIONAL INSIGHTS INTO CHEMICAL REACTIVITY AND ROAD TO CATALYST DESIGN: THE PARADIGM OF CO2 HYDROGENATION Introduction Reaction Energetics and Governing Factor Newly Designed Catalysts and Their Reactivity Correlation Between Hydricity and Reactivity Concluding Remarks CATALYSIS WITH MULTINUCLEAR COMPLEXES Introduction Stoichiometric Reaction Pathways Application in Catalysis Polynuclear Complexes Outlook COPPER-CATALYZED HYDROGENATIONS AND AEROBIC N-N BOND FORMATIONS: ACADEMIC DEVELOPMENTS AND INDUSTRIAL RELEVANCE Introduction Cu-Promoted N-N Bond Formation Cu-Catalyzed Homogeneous Hydrogenation Conclusions C=C HYDROGENATIONS WITH IRON GROUP METAL CATALYSTS Introduction Iron Cobalt Nickel Conclusion BASE METAL-CATALYZED ADDITION REACTIONS ACROSS C-C MULTIPLE BONDS Introduction Catalytic Addition to Alkenes Initiated Through Radical Mechanism Other Catalytic Additions to Unsaturated Bonds Proceeding Through Initial R· (R¿H) Attack Catalytic Addition to Alkenes Initiated Through Polar Mechanisms Hydrosilylation Reactions Conclusion IRON-CATALYZED CYCLOPROPANATION OF ALKENES BY CARBENE TRANSFER REACTIONS Introduction Achiral Iron Porphyrin Catalysts Iron Phthalocyanines and Corroles Iron Catalystswith N or N,OLigands The [Cp(CO)2FeII(THF)]BF4 Catalyst Conclusions NOVEL SUBSTRATES AND NUCLEOPHILES IN ASYMMETRIC COPPER-CATALYZED CONJUGATE ADDITION REACTIONS Introduction Catalytic Asymmetric Conjugate Additions to Alpha-Substituted Alpha,Beta-Unsaturated Carbonyl Compounds Catalytic Asymmetric Conjugate Additions to Alkenyl-Heteroarenes Conclusion ASYMMETRIC REDUCTION OF POLAR DOUBLE BONDS Introduction Manganese Iron Cobalt Nickel Copper Conclusion IRON-, COBALT-, AND MANGANESE-CATALYZED HYDROSILYLATION OF CARBONYL COMPOUNDS AND CARBON DIOXIDE Introduction Hydrosilylation of Aldehydes and Ketones Reduction of Imines and Reductive Amination of Carbonyl Compounds Reduction of Carboxylic Acid Derivatives Hydroelementation of Carbon Dioxide Conclusion REACTIVE INTERMEDIATES AND MECHANISM IN IRON-CATALYZED CROSS-COUPLING Introduction Cross-Coupling Catalyzed by Simple Iron Salts TMEDA in Iron-Catalyzed Cross-Coupling NHCs in Iron-Catalyzed Cross-Coupling Phosphines in Iron-Catalyzed Cross-Coupling Future Outlook RECENT ADVANCES IN COBALT-CATALYZED CROSS-COUPLING REACTIONS Introduction Cobalt-Catalyzed C-C Coupling Through a C-H Activation Approach Cobalt-Catalyzed C-C Couplings Using a Preactivated Substrate Approach (Aryl Halides and Pseudohalides) Cobalt-Catalyzed C-X Couplings Using C-H Activation Approaches Cobalt-Catalyzed C-X Couplings Using a Preactivated Substrate Approach (Aryl Halides and Pseudohalides) Miscellaneous Conclusions and Future Prospects TRIFLUOROMETHYLATION AND RELATED REACTIONS Trifluoromethylation Reactions Trifluoromethylthiolation Reactions Perfluoroalkylation Reactions Conclusion CATALYTIC OXYGENATION OF C=C AND C-H BONDS Introduction Oxygenation of C=C Bonds Oxygenation of C-H Bonds Conclusions and Outlook ORGANOMETALLIC CHELATION-ASSISTED C-H FUNCTIONALIZATION Introduction C-C Bond Formation via C-H Activation C-Heteroatom Formation via C-H Activation Conclusions CATALYTIC WATER OXIDATION: WATER OXIDATION TO O2 MEDIATED BY 3D TRANSITION METAL COMPLEXES Water Oxidation - From Insights into Fundamental Chemical Concepts to Future Solar Fuels ModelWell-DefinedWater Oxidation Catalysts Conclusion and Outlook BASE-METAL-CATALYZED HYDROGEN GENERATION FROM CARBON- AND BORON NITROGEN-BASED SUBSTRATES Introduction Hydrogen Generation from Formic Acid Hydrogen Generation from Alcohols Hydrogen Storage in Liquid Organic Hydrogen Carriers Dehydrogenation of Ammonia Borane and Amine Boranes Conclusion MOLECULAR CATALYSTS FOR PROTON REDUCTION BASED
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