Ian W. Hamley

Block Copolymers in Solution (eBook, PDF)

Fundamentals and Applications

• Format: PDF

Produktbeschreibung

This unique text discusses the solution self-assembly of block copolymers and covers all aspects from basic physical chemistry to applications in soft nanotechnology. Recent advances have enabled the preparation of new materials with novel self-assembling structures, functionality and responsiveness and there have also been concomitant advances in theory and modelling. The present text covers the principles of self-assembly in both dilute and concentrated solution, for example micellization and mesophase formation, etc., in chapters 2 and 3 respectively. Chapter 4 covers polyelectrolyte block copolymers - these materials are attracting significant attention from researchers and a solid basis for understanding their physical chemistry is emerging, and this is discussed. The next chapter discusses adsorption of block copolymers from solution at liquid and solid interfaces. The concluding chapter presents a discussion of selected applications, focussing on several important new concepts. The book is aimed at researchers in polymer science as well as industrial scientists involved in the polymer and coatings industries. It will also be of interest to scientists working in soft matter self-assembly and self-organizing polymers.

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Produktdetails

• Verlag: John Wiley & Sons
• Seitenzahl: 300
• Erscheinungstermin: 13. Dezember 2005
• Englisch
• ISBN-13: 9780470016978
• Artikelnr.: 37289645

Autorenporträt

Ian W. Hamley is the author of Block Copolymers in Solution: Fundamentals and Applications, published by Wiley.

Inhaltsangabe

Preface Acknowledgements. Abbreviations. 1. Introduction. References. 2.
Neutral Block Copolymers in Dilute Solution. 2.1 Introduction. 2.2
Techniques for Studying Micellization. 2.3 Micellization in PEO-based Block
Copolymers. 2.4 Micellization in Styrenic Block Copolymers. 2.5
Determination of cmc. 2.6 Thermodynamics of Micellization. 2.7
Micellization and Micelle Dimensions: Theory and Simulation. 2.8 Micelle
Dimensions: Comparison Between Experiment and Theory. 2.9 Interaction
between Micelles. 2.10 Dynamics of Micellization. 2.11 Dynamic Modes. 2.12
Specific Types of Micelles. 2.13 Micellization in Mixed solvents. 2.14
Mixed micelles. 2.15 Block Copolymer/Surfactant complexes. 2.16 Complex
Morphologies. 2.17 Vesicles. 2.18 Crystallization in Micelles. References.
3. Concentrated Solutions. 3.1 Understanding Phase Diagrams. 3.2 Phase
Behaviour of PEO-containing Block Copolymers. 3.3 Gelation. 3.4
Order-Disorder Phase Transition. 3.5 Order-order Phase Transitions. 3.6
Domain Spacing Scaling, and Solvent Distribution profiles. 3.7 Semidilute
Block Copolymer Solution Theory. 3.8 Theoretical understanding of Phase
Diagrams. 3.9 Flow Alignment. 3.10 Dynamics. References. 4. Polyelectrolyte
Block Copolymers. 4.1 Micellization. 4.2 Chain Conformation. 4.3 Theory.
4.4 Polyion Complexes. 4.5 Copolymer-surfactant complexes. 4.6 Complexation
with other Molecules. 4.7 Gelation. 4.8 Hierarchical Order in Peptide Block
Copolyelectrolyte Solutions. References. 5. Adsorption. 5.1 Introduction.
5.2 Adsorption at the Air-Water Interface. 5.3 Adsorption on Solid
Substrates. 5.4 Surface Forces Experiments. 5.5 Modelling Adsorption.
References. 6. Applications 6.1 Surfactancy/Detergency. 6.2 Solubilisation,
Emusification and Stabilization. 6.3 Drug Delivery. 6.4 Biodegradable Block
Copolymer Micelles. 6.5 Thermoresponsive Micellar Systems. 6.6
Metal-Containing Copolymer Micelles and Nanoreactors. 6.7 Vesicles. 6.8
Separation Media. 6.9 Templating. 6.10 Membranes. 6.11 Other Applications.
References. Index.

Rezensionen

" this book nicely summarizes the field, touching on all the important subjects vital to scientists and engineering working with these materials." ( Journal of the American Chemical Society , February 1, 2006)