Produktbild: Smith, M: March's Advanced Organic Chemistry

Smith, M: March's Advanced Organic Chemistry

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Beschreibung

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

13.04.2020

Verlag

John Wiley & Sons Inc

Seitenzahl

2144

Maße (L/B/H)

25,6/18,4/8,5 cm

Gewicht

3478 g

Auflage

8. Auflage

Sprache

Englisch

ISBN

978-1-119-37180-9

Beschreibung

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

13.04.2020

Verlag

John Wiley & Sons Inc

Seitenzahl

2144

Maße (L/B/H)

25,6/18,4/8,5 cm

Gewicht

3478 g

Auflage

8. Auflage

Sprache

Englisch

ISBN

978-1-119-37180-9

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Wiley & Sons
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  • Produktbild: Smith, M: March's Advanced Organic Chemistry
  • New Reaction Sections Correlation: 7th Edition --> 8th Edition xv
     
    Preface xxi
     
    Common Abbreviations xxv
     
    Biographical Statement xxxi
     
    New Features of the 8th Edition xxxiii
     
    Part I Introduction 1
     
    1. Localized Chemical Bonding 3
     
    1.A. Covalent Bonding 3
     
    1.B. Multiple Valence 7
     
    1.C. Hybridization 7
     
    1.D. Multiple Bonds 9
     
    1.E. Photoelectron Spectroscopy 12
     
    1.F. Electronic Structures of Molecules 15
     
    1.G. Electronegativity 17
     
    1.H. Dipole Moment 19
     
    1.I. Inductive and Field Effects 20
     
    1.J. Bond Distances 23
     
    1.K. Bond Angles 27
     
    1.L. Bond Energies 29
     
    2. Delocalized Chemical Bonding 33
     
    2.A. Molecular Orbitals 34
     
    2.B. Bond Energies and Distances in Compounds Containing Delocalized Bonds 37
     
    2.C. Molecules that have Delocalized Bonds 39
     
    2.D. Cross Conjugation 44
     
    2.E. The Rules of Resonance 46
     
    2.F. The Resonance Effect 48
     
    2.G. Steric Inhibition of Resonance and the Influences of Strain 48
     
    2.H. ppi-dpi Bonding: Ylids 52
     
    2.I. Aromaticity 54
     
    2.I.i. Six-Membered Rings 58
     
    2.I.ii. Five-, Seven-, and Eight-Membered Rings 62
     
    2.I.iii. Other Systems Containing Aromatic Sextets 67
     
    2.J. Alternant and Nonalternant Hydrocarbons 68
     
    2.K. Aromatic Systems with Electron Numbers Other Than Six 70
     
    2.K.i. Systems of Two Electrons 72
     
    2.K.ii. Systems of Four Electrons: Antiaromaticity 73
     
    2.K.iii. Systems of Eight Electrons 76
     
    2.K.iv. Systems of Ten Electrons 77
     
    2.K.v. Systems of More than Ten Electrons: 4n + 2 Electrons 80
     
    2.K.vi. Systems of More Than Ten Electrons: 4n Electrons 85
     
    2.L. Other Aromatic Compounds 89
     
    2.M. Hyperconjugation 92
     
    2.N. Tautomerism 96
     
    2.N.i. Keto-Enol Tautomerism 97
     
    2.N.ii. Other Proton-Shift Tautomerism 100
     
    3. Bonding Weaker Than Covalent 105
     
    3.A. Hydrogen Bonding 105
     
    3.B. pi-pi Interactions 113
     
    3.C. Addition Compounds 114
     
    3.C.i. Electron Donor-Acceptor (EDA) Complexes 114
     
    3.C.ii. Crown Ether Complexes and Cryptates 117
     
    3.C.iii. Inclusion Compounds 122
     
    3.C.iv. Cyclodextrins 125
     
    3.D. Catenanes and Rotaxanes 127
     
    3.E. Cucurbit[n]Uril-Based Gyroscane 131
     
    4. Stereochemistry and Conformation 133
     
    4.A. Optical Activity and Chirality 133
     
    4.B. Dependence of Rotation on Conditions of Measurement 135
     
    4.C. What Kinds of Molecules Display Optical Activity? 136
     
    4.D. The Fischer Projection 147
     
    4.E. Absolute Configuration 148
     
    4.E.i. The Cahn-Ingold-Prelog System 150
     
    4.E.ii. Methods of Determining Configuration 152
     
    4.F. The Cause of Optical Activity 156
     
    4.G. Molecules with More Than One Stereogenic Center 157
     
    4.H. Asymmetric Synthesis 161
     
    4.I. Methods of Resolution 166
     
    4.J. Optical Purity 173
     
    4.K. Cis-Trans Isomerism 175
     
    4.K.i. Cis-Trans Isomerism Resulting from Double Bonds 175
     
    4.K.ii. Cis-Trans Isomerism of Monocyclic Compounds 179
     
    4.K.iii. Cis-Trans Isomerism of Fused and Bridged Ring Systems 180
     
    4.L. Out-In Isomerism 181
     
    4.M. Enantiotopic and Diastereotopic Atoms, Groups, and Faces 183
     
    4.N. Stereospecific and Stereoselective Syntheses 186
     
    4.O. Conformational Analysis 187
     
    4.O.i. Conformation in Open-Chain Systems 188
     
    4.O.ii. Conformation in Six-Membered Rings 194
     
    4