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Produktbild: Membrane Materials for Gas and Separation

Membrane Materials for Gas and Separation Synthesis and Application Fo Silicon-Containing Polymers

231,99 €

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Beschreibung

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

27.03.2017

Herausgeber

Yuri Yampolskii + weitere

Verlag

John Wiley & Sons

Seitenzahl

448

Maße (L/B/H)

24,6/17,3/2,5 cm

Gewicht

839 g

Auflage

1. Auflage

Sprache

Englisch

ISBN

978-1-119-11271-6

Beschreibung

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

27.03.2017

Herausgeber

Verlag

John Wiley & Sons

Seitenzahl

448

Maße (L/B/H)

24,6/17,3/2,5 cm

Gewicht

839 g

Auflage

1. Auflage

Sprache

Englisch

ISBN

978-1-119-11271-6

Herstelleradresse

Libri GmbH
Europaallee 1
36244 Bad Hersfeld
DE

Email: gpsr@libri.de

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  • Produktbild: Membrane Materials for Gas and Separation
  • Contributors xi
     
    Preface xv
     
    1 Permeability of Polymers 1
    Yuri Yampolskii
     
    1.1 Introduction 1
     
    1.2 Detailed mechanism of sorption and transport 3
     
    1.2.1 Transition-state model 3
     
    1.2.2 Free volume model 4
     
    1.2.3 Sorption isotherms 5
     
    1.3 Concentration dependence of permeability and diffusion coefficients 6
     
    1.4 Effects of properties of gases and polymers on permeation parameters 10
     
    Acknowledgement 13
     
    References 13
     
    2 Organosiloxanes (Silicones), Polyorganosiloxane Block Copolymers: Synthesis, Properties, and Gas Permeation Membranes Based on Them 17
    Igor Raygorodsky, Victor Kopylov, and Alexander Kovyazin
     
    2.1 Introduction 17
     
    2.2 Synthesis and transformations of organosiloxanes 17
     
    2.2.1 Polyorganosiloxanes with aminoalkyl groups at silicon 19
     
    2.2.2 Organosilicon alcohols and phenols 21
     
    2.3 Synthesis of polyorganosiloxane block copolymers 23
     
    2.3.1 Polyester(ether)-polyorganosiloxane block copolymers 24
     
    2.3.2 Synthesis of polyurethane-, polyurea-, polyamide-, polyimide- organosiloxane POBCs 25
     
    2.4 Properties of polyorganosiloxane block copolymers 29
     
    2.4.1 Phase state of polyblock organosiloxane copolymers 29
     
    2.5 Morphology of POBCs and its effects on their diffusion properties 30
     
    2.5.1 Types of heterogeneous structure 30
     
    2.6 Some representatives of POBC as membrane materials and their properties 32
     
    2.6.1 Polycarbonate-polysiloxanes 32
     
    2.6.2 Polyurethane(urea)-polysiloxanes 39
     
    2.6.3 Polyimide(amide)-polysiloxanes 42
     
    2.7 Conclusions 45
     
    References 46
     
    3 Polysilalkylenes 53
    Nikolay V. Ushakov, Stepan Guselnikov, and Eugene Finkelshtein
     
    Acknowledgement 65
     
    References 65
     
    4 Polyvinylorganosilanes: The Materials for Membrane Gas Separation 69
    Nikolay V. Ushakov
     
    4.1 Introduction: Historical background 69
     
    4.2 Syntheses and polymerization of vinyltriorganosilanes 71
     
    4.2.1 Syntheses of vinyltriorganosilanes 71
     
    4.2.2 Vinyltriorganosilane (VTOS) polymerization 73
     
    4.3 Physico-chemical and membrane properties of polymeric PVTOS materials 88
     
    4.4 Concluding remarks 94
     
    Acknowledgement 95
     
    References 95
     
    5 Substituted Polyacetylenes 107
    Toshikazu Sakaguchi, Yanming Hu, and Toshio Masuda
     
    5.1 Introduction 107
     
    5.2 Poly(1-trimethylsilyl-1-propyne) (PTMSP) and related polymers 110
     
    5.2.1 Synthesis and general properties 110
     
    5.2.2 Permeation of gases and liquids 112
     
    5.2.3 Aging effect and cross-linking 114
     
    5.2.4 Free volume 115
     
    5.2.5 Nanocomposites and hybrids 116
     
    5.3 Poly[1-phenyl-2-(p-trimethylsilylphenyl)acetylene] and related polymers 117
     
    5.3.1 Polymer synthesis 118
     
    5.3.2 Gas separation 121
     
    5.4 Desilylated polyacetylenes 124
     
    5.4.1 Desilylation of poly[1(p-trimethylsilylphenyl)-2-phenylacetylene] 124
     
    5.4.2 PDPAs from precursor polymers with various silyl groups 125
     
    5.4.3 Soluble poly(diphenylacetylene)s obtained by desilylation 127
     
    5.4.4 Poly(diarylacetylene)s 128
     
    5.5 Polar-group-containing polyacetylenes 130
     
    5.5.1 Hydroxy group 130
     
    5.5.2 Sulfonated and nitrated poly(diphenylacetylene)s 132
     
    5.5.3 Other polar groups 134
     
    5.6 Concluding remarks 135
     
    References 136
     
    6 Polynorbornenes 143
    Eugene Finkelshtein, Maria Gringolts, Maksim Bermeshev, Pavel Chapala, and Yulia Rogan
     
    6.1 Introduction 143
     
    6.2 Monomer synthesi