Reagents for Silicon-Mediated Organic Synthesis
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Form:Einzelkauf Download
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Sprache:Englisch
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eBook Format:PDF
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Verlag:John Wiley & Sons Inc
- Wiley 138,99 €
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107,99 €
inkl. gesetzl. MwSt.Beschreibung
Produktdetails
Format
Kopierschutz
Ja
Family Sharing
Nein
Text-to-Speech
Nein
Erscheinungsdatum
30.05.2013
Herausgeber
Philip L. FuchsVerlag
John Wiley & Sons IncSeitenzahl
816 (Printausgabe)
Dateigröße
21013 KB
Auflage
1. Auflage
Sprache
Englisch
EAN
9781118636138
Over the last three decades the importance of organosilicon
chemistry has greatly increased because it has opened a number of
new synthetic strategies. Silicon reagents are usually low-cost,
versatile and allow a wide range of reactions. This is the first
Handbook to compile essential Silicon containing reagents and makes
use of the leading reagent database e-EROS. Another hot
volume in the series Handbooks of Reagents for Organic
Synthesis, this is a must-have resource for all synthetic
chemists working in drug development and medicinal chemistry.
For the selection the Editor focussed on three key synthetic
approaches with the greatest impact:
1. Use of silicon as a 'temporary tether' by unifying a reactive
pair of functional groups and taking advantage of their
template-biased intramolecular cyclization.
2. The specific use of the silane functionality as a hetero
t-butyl group, often colloquially referred to as the use of
silicon as a 'fat proton'.
3. The use of the Brook rearrangement as an 'anion relay
stratagem'.
A new feature in this Handbook is the reagent finder, an
alphabetically organized lookup table arranged by organic
functionality and specific structure of the silicon atom to which
it is bound.
chemistry has greatly increased because it has opened a number of
new synthetic strategies. Silicon reagents are usually low-cost,
versatile and allow a wide range of reactions. This is the first
Handbook to compile essential Silicon containing reagents and makes
use of the leading reagent database e-EROS. Another hot
volume in the series Handbooks of Reagents for Organic
Synthesis, this is a must-have resource for all synthetic
chemists working in drug development and medicinal chemistry.
For the selection the Editor focussed on three key synthetic
approaches with the greatest impact:
1. Use of silicon as a 'temporary tether' by unifying a reactive
pair of functional groups and taking advantage of their
template-biased intramolecular cyclization.
2. The specific use of the silane functionality as a hetero
t-butyl group, often colloquially referred to as the use of
silicon as a 'fat proton'.
3. The use of the Brook rearrangement as an 'anion relay
stratagem'.
A new feature in this Handbook is the reagent finder, an
alphabetically organized lookup table arranged by organic
functionality and specific structure of the silicon atom to which
it is bound.
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