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  • Produktbild: Electrochemical Science and Technology
  • Produktbild: Electrochemical Science and Technology

Electrochemical Science and Technology

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Beschreibung

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

02.12.2011

Verlag

Wiley

Seitenzahl

418

Maße (L/B/H)

25/17,5/2,7 cm

Gewicht

899 g

Sprache

Englisch

ISBN

978-0-470-71085-2

Beschreibung

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

02.12.2011

Verlag

Wiley

Seitenzahl

418

Maße (L/B/H)

25/17,5/2,7 cm

Gewicht

899 g

Sprache

Englisch

ISBN

978-0-470-71085-2

Herstelleradresse

Libri GmbH
Europaallee 1
36244 Bad Hersfeld
DE

Email: gpsr@libri.de

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  • Produktbild: Electrochemical Science and Technology
  • Produktbild: Electrochemical Science and Technology
  • Preface xi

    1 Electricity 1

    Electric Charge 1

    Charges at Rest 3

    Capacitance and Conductance 8

    Mobilities 18

    Electrical Circuits 21

    Alternating Electricity 23

    Summary 28

    2 Chemistry 29

    Chemical Reactions 29

    Gibbs Energy 30

    Activity 33

    Ionic Solutions 38

    Ionic Activity Coefficients 41

    Chemical Kinetics 46

    Summary 52

    3 Electrochemical Cells 55

    Equilibrium Cells 55

    Cells not at Equilibrium 60

    Cells with Junctions 64

    Summary 69

    4 Electrosynthesis 71

    Metal Production 71

    The Chloralkali Industry 74

    Organic Electrosynthesis 75

    Electrolysis of Water 77

    Selective Membranes 79

    Summary 83

    5 Electrochemical Power 85

    Types of Electrochemical Power Source 85

    Battery Characteristics 86

    Primary Batteries 88

    Secondary Batteries 94

    Fuel Cells 100

    Summary 104

    6 Electrodes 105

    Electrode Potentials 105

    Standard Electrode Potentials 109

    The Nernst Equation 111

    Electrochemical Series 113

    Working Electrodes 117

    Summary 123

    7 Electrode Reactions 125

    Faraday's Law 125

    Kinetics of a Simple Electron Transfer 130

    Multi-step Electrode Reactions 137

    Summary 144

    8 Transport 145

    Flux Density 145

    Three Transport Modes 148

    Migration 149

    Diffusion 154

    Diffusion and Migration 158

    Convection 161

    Fluxes at Electrodes and in the Bulk 165

    Summary 170

    9 Green Electrochemistry 171

    Sensors for Pollution Control 171

    Stripping Analysis 177

    Electrochemical Purification of Water 182

    Electrochemistry of Biological Cells 186

    Summary 192

    10 Electrode Polarization 193

    Three Causes of Electrode Polarization 193

    Ohmic Polarization 197

    Kinetic Polarization 200

    Transport Polarization 202

    Multiple Polarizations 205

    Polarizations in Two- and Three-Electrode Cells 208

    Summary 212

    11 Corrosion 213

    Vulnerable Metals 213

    Corrosion Cells 215

    Electrochemical Studies 217

    Concentrated Corrosion 222

    Fighting Corrosion 224

    Extreme Corrosion 228

    Summary 229

    12 Steady-State Voltammetry 231

    Features of Voltammetry 232

    Microelectrodes and Macroelectrodes 234

    Steady-State Potential-Step Voltammetry 237

    The Disk Microelectrode 245

    Rotating Disk Voltammetry 248

    Shapes of Reversible Voltammograms 252

    Summary 258

    13 The Electrode Interface 259

    Double Layers 259

    Adsorption 266

    The Interface in Voltammetry 271

    Nucleation and Growth 281

    Summary 285

    14 Other Interfaces 287

    Semiconductor Electrodes 287

    Phenomena at Liquid*Liquid Interfaces 291

    Electrokinetic Phenomena 298

    Summary 302

    15 Electrochemistry With Periodic Signals 303

    Nonfaradaic Effects of A.C. 304

    Faradaic Effects of A.C. 305

    Equivalent Circuits 313

    A.C. Voltammetry 318

    Fourier-Transform Voltammetry 322

    Summary 328

    16 Transient Voltammetry 329

    Modeling Transient Voltammetry 329

    Potential-Step Voltammetry 334

    Pulse Voltammetries 339

    Ramped Potentials 346

    Multiple Electron Transfers 355

    Chemistry Combined with Electrochemistry 357

    Controlling Current Instead of Potential 362

    Summary 364

    Appendix 365

    Glossary 365

    Absolute and Relative Permittivities 382

    Properties of Liquid Water 383

    Contents ix

    Conductivities and Resistivities 384

    Elements with Major Importance in Electrochemistry 386

    Transport Properties 388

    Standard Gibbs Energies 390

    Standard Electrode Potentials 392

    Index 393