Comprehensive Chiroptical Spectroscopy, Volume 2
Applications in Stereochemical Analysis of Synthetic Compounds, Natural Products, and Biomolecules
Ed. by Nina Berova, Prasad L. Polavarapu, Koji Nakanishi et al.
Comprehensive Chiroptical Spectroscopy, Volume 2
Applications in Stereochemical Analysis of Synthetic Compounds, Natural Products, and Biomolecules
Ed. by Nina Berova, Prasad L. Polavarapu, Koji Nakanishi et al.
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This book provides an introduction to the important methods of chiroptical spectroscopy in general, and circular dichroism (CD) in particular, which are increasingly important in all areas of chemistry, biochemistry, and structural biology. The book can be used as a text for undergraduate and graduate students and as a reference for researchers in academia and industry. Experimental methods and instrumentation are described with topics ranging from the most widely used methods (electronic and vibrational CD) to frontier areas such as nonlinear spectroscopy and photoelectron CD, as well as the…mehr
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- Produktdetails
- Verlag: Wiley & Sons
- Artikelnr. des Verlages: 1W118012920
- 1. Auflage
- Seitenzahl: 872
- Erscheinungstermin: Mai 2012
- Englisch
- Abmessung: 260mm x 187mm x 51mm
- Gewicht: 1640g
- ISBN-13: 9781118012925
- ISBN-10: 1118012925
- Artikelnr.: 34446930
- Verlag: Wiley & Sons
- Artikelnr. des Verlages: 1W118012920
- 1. Auflage
- Seitenzahl: 872
- Erscheinungstermin: Mai 2012
- Englisch
- Abmessung: 260mm x 187mm x 51mm
- Gewicht: 1640g
- ISBN-13: 9781118012925
- ISBN-10: 1118012925
- Artikelnr.: 34446930
xiii PART I A HISTORICAL OVERVIEW 1 1 THE FIRST DECADES AFTER THE DISCOVERY
OF CD AND ORD BY AIME COTTON IN 1895 3 Peter Laur PART II ORGANIC
STEREOCHEMISTRY 37 2 SOME INHERENTLY CHIRAL CHROMOPHORES--EMPIRICAL RULES
AND QUANTUM CHEMICAL CALCULATIONS 39 Marcin Kwit, Pawel Skowronek, Jacek
Gawronski, Jadwiga Frelek, Magdalena Woznica, and Aleksandra Butkiewicz 3
ELECTRONIC CD OF BENZENE AND OTHER AROMATIC CHROMOPHORES FOR DETERMINATION
OF ABSOLUTE CONFIGURATION 73 Tibor Kurtan, Sandor Antus, and Gennaro
Pescitelli 4 ELECTRONIC CD EXCITON CHIRALITY METHOD: PRINCIPLES AND
APPLICATIONS 115 Nobuyuki Harada, Koji Nakanishi, and Nina Berova 5 CD
SPECTRA OF CHIRAL EXTENDED p-ELECTRON COMPOUNDS: THEORETICAL DETERMINATION
OF THE ABSOLUTE STEREOCHEMISTRY AND EXPERIMENTAL VERIFICATION 167 Nobuyuki
Harada and Shunsuke Kuwahara 6 ASSIGNMENT OF THE ABSOLUTE CONFIGURATIONS OF
NATURAL PRODUCTS BY MEANS OF SOLID-STATE ELECTRONIC CIRCULAR DICHROISM AND
QUANTUM MECHANICAL CALCULATIONS 217 Gennaro Pescitelli, Tibor Kurtan, and
Karsten Krohn 7 DYNAMIC STEREOCHEMISTRY AND CHIROPTICAL SPECTROSCOPY OF
METALLO-ORGANIC COMPOUNDS 251 James W. Canary and Zhaohua Dai 8 CIRCULAR
DICHROISM OF DYNAMIC SYSTEMS: SWITCHING MOLECULAR AND SUPRAMOLECULAR
CHIRALITY 289 Angela Mammana, Gregory T. Carroll, and Ben L. Feringa 9
ELECTRONIC CIRCULAR DICHROISM OF SUPRAMOLECULAR SYSTEMS 317 Cheng Yang and
Yoshihisa Inoue 10 THE ONLINE STEREOCHEMICAL ANALYSIS OF CHIRAL COMPOUNDS
BY HPLC-ECD COUPLING IN COMBINATION WITH QUANTUM-CHEMICAL CALCULATIONS 355
Gerhard Bringmann, Daniel Gotz, and Torsten Bruhn 11 DETERMINATION OF THE
STRUCTURES OF CHIRAL NATURAL PRODUCTS USING VIBRATIONAL CIRCULAR DICHROISM
387 Prasad L. Polavarapu 12 DETERMINATION OF MOLECULAR ABSOLUTE
CONFIGURATION: GUIDELINES FOR SELECTING A SUITABLE CHIROPTICAL APPROACH 421
Stefano Superchi, Carlo Rosini, Giuseppe Mazzeo, and Egidio Giorgio PART
III INORGANIC STEREOCHEMISTRY 449 13 APPLICATIONS OF ELECTRONIC CIRCULAR
DICHROISM TO INORGANIC STEREOCHEMISTRY 451 Sumio Kaizaki PART IV
BIOMOLECULES 473 14 ELECTRONIC CIRCULAR DICHROISM OF PROTEINS 475 Robert W.
Woody 15 ELECTRONIC CIRCULAR DICHROISM OF PEPTIDES 499 Claudio Toniolo,
Fernando Formaggio, and Robert W. Woody 16 ELECTRONIC CIRCULAR DICHROISM OF
PEPTIDOMIMETICS 545 Claudio Toniolo and Fernando Formaggio 17 CIRCULAR
DICHROISM SPECTROSCOPY OF NUCLEIC ACIDS 575 Jaroslav Kypr, Iva Kejnovska,
Klara Bednarova, and Michaela Vorlickova 18 ELECTRONIC CIRCULAR DICHROISM
OF PEPTIDE NUCLEIC ACIDS AND THEIR ANALOGUES 587 Roberto Corradini, Tullia
Tedeschi, Stefano Sforza, and Rosangela Marchelli 19 CIRCULAR DICHROISM OF
PROTEIN-NUCLEIC ACID INTERACTIONS 615 Donald M. Gray 20 DRUG AND NATURAL
PRODUCT BINDING TO NUCLEIC ACIDS ANALYZED BY ELECTRONIC CIRCULAR DICHROISM
635 George A. Ellestad 21 PROBING HSA AND AGP DRUG-BINDING SITES BY
ELECTRONIC CIRCULAR DICHROISM 665 Miklos Simonyi 22 CONFORMATIONAL STUDIES
OF BIOPOLYMERS, PEPTIDES, PROTEINS, AND NUCLEIC ACIDS. A ROLE FOR
VIBRATIONAL CIRCULAR DICHROISM 707 Timothy A. Keiderling and Ahmed Lakhani
23 STRUCTURE AND BEHAVIOR OF BIOMOLECULES FROM RAMAN OPTICAL ACTIVITY 759
Laurence D. Barron and Lutz Hecht 24 OPTICAL ROTATION, ELECTRONIC CIRCULAR
DICHROISM, AND VIBRATIONAL CIRCULAR DICHROISM OF CARBOHYDRATES AND
GLYCOCONJUGATES 795 Tohru Taniguchi and Kenji Monde 25 ELECTRONIC CIRCULAR
DICHROISM IN DRUG DISCOVERY 819 Carlo Bertucci and Marco Pistolozzi INDEX
843
xiii PART I A HISTORICAL OVERVIEW 1 1 THE FIRST DECADES AFTER THE DISCOVERY
OF CD AND ORD BY AIME COTTON IN 1895 3 Peter Laur PART II ORGANIC
STEREOCHEMISTRY 37 2 SOME INHERENTLY CHIRAL CHROMOPHORES--EMPIRICAL RULES
AND QUANTUM CHEMICAL CALCULATIONS 39 Marcin Kwit, Pawel Skowronek, Jacek
Gawronski, Jadwiga Frelek, Magdalena Woznica, and Aleksandra Butkiewicz 3
ELECTRONIC CD OF BENZENE AND OTHER AROMATIC CHROMOPHORES FOR DETERMINATION
OF ABSOLUTE CONFIGURATION 73 Tibor Kurtan, Sandor Antus, and Gennaro
Pescitelli 4 ELECTRONIC CD EXCITON CHIRALITY METHOD: PRINCIPLES AND
APPLICATIONS 115 Nobuyuki Harada, Koji Nakanishi, and Nina Berova 5 CD
SPECTRA OF CHIRAL EXTENDED p-ELECTRON COMPOUNDS: THEORETICAL DETERMINATION
OF THE ABSOLUTE STEREOCHEMISTRY AND EXPERIMENTAL VERIFICATION 167 Nobuyuki
Harada and Shunsuke Kuwahara 6 ASSIGNMENT OF THE ABSOLUTE CONFIGURATIONS OF
NATURAL PRODUCTS BY MEANS OF SOLID-STATE ELECTRONIC CIRCULAR DICHROISM AND
QUANTUM MECHANICAL CALCULATIONS 217 Gennaro Pescitelli, Tibor Kurtan, and
Karsten Krohn 7 DYNAMIC STEREOCHEMISTRY AND CHIROPTICAL SPECTROSCOPY OF
METALLO-ORGANIC COMPOUNDS 251 James W. Canary and Zhaohua Dai 8 CIRCULAR
DICHROISM OF DYNAMIC SYSTEMS: SWITCHING MOLECULAR AND SUPRAMOLECULAR
CHIRALITY 289 Angela Mammana, Gregory T. Carroll, and Ben L. Feringa 9
ELECTRONIC CIRCULAR DICHROISM OF SUPRAMOLECULAR SYSTEMS 317 Cheng Yang and
Yoshihisa Inoue 10 THE ONLINE STEREOCHEMICAL ANALYSIS OF CHIRAL COMPOUNDS
BY HPLC-ECD COUPLING IN COMBINATION WITH QUANTUM-CHEMICAL CALCULATIONS 355
Gerhard Bringmann, Daniel Gotz, and Torsten Bruhn 11 DETERMINATION OF THE
STRUCTURES OF CHIRAL NATURAL PRODUCTS USING VIBRATIONAL CIRCULAR DICHROISM
387 Prasad L. Polavarapu 12 DETERMINATION OF MOLECULAR ABSOLUTE
CONFIGURATION: GUIDELINES FOR SELECTING A SUITABLE CHIROPTICAL APPROACH 421
Stefano Superchi, Carlo Rosini, Giuseppe Mazzeo, and Egidio Giorgio PART
III INORGANIC STEREOCHEMISTRY 449 13 APPLICATIONS OF ELECTRONIC CIRCULAR
DICHROISM TO INORGANIC STEREOCHEMISTRY 451 Sumio Kaizaki PART IV
BIOMOLECULES 473 14 ELECTRONIC CIRCULAR DICHROISM OF PROTEINS 475 Robert W.
Woody 15 ELECTRONIC CIRCULAR DICHROISM OF PEPTIDES 499 Claudio Toniolo,
Fernando Formaggio, and Robert W. Woody 16 ELECTRONIC CIRCULAR DICHROISM OF
PEPTIDOMIMETICS 545 Claudio Toniolo and Fernando Formaggio 17 CIRCULAR
DICHROISM SPECTROSCOPY OF NUCLEIC ACIDS 575 Jaroslav Kypr, Iva Kejnovska,
Klara Bednarova, and Michaela Vorlickova 18 ELECTRONIC CIRCULAR DICHROISM
OF PEPTIDE NUCLEIC ACIDS AND THEIR ANALOGUES 587 Roberto Corradini, Tullia
Tedeschi, Stefano Sforza, and Rosangela Marchelli 19 CIRCULAR DICHROISM OF
PROTEIN-NUCLEIC ACID INTERACTIONS 615 Donald M. Gray 20 DRUG AND NATURAL
PRODUCT BINDING TO NUCLEIC ACIDS ANALYZED BY ELECTRONIC CIRCULAR DICHROISM
635 George A. Ellestad 21 PROBING HSA AND AGP DRUG-BINDING SITES BY
ELECTRONIC CIRCULAR DICHROISM 665 Miklos Simonyi 22 CONFORMATIONAL STUDIES
OF BIOPOLYMERS, PEPTIDES, PROTEINS, AND NUCLEIC ACIDS. A ROLE FOR
VIBRATIONAL CIRCULAR DICHROISM 707 Timothy A. Keiderling and Ahmed Lakhani
23 STRUCTURE AND BEHAVIOR OF BIOMOLECULES FROM RAMAN OPTICAL ACTIVITY 759
Laurence D. Barron and Lutz Hecht 24 OPTICAL ROTATION, ELECTRONIC CIRCULAR
DICHROISM, AND VIBRATIONAL CIRCULAR DICHROISM OF CARBOHYDRATES AND
GLYCOCONJUGATES 795 Tohru Taniguchi and Kenji Monde 25 ELECTRONIC CIRCULAR
DICHROISM IN DRUG DISCOVERY 819 Carlo Bertucci and Marco Pistolozzi INDEX
843