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The aim of this book is to help people performing routine operations in Organic Synthesis in a laboratory. This book, the first one in a series, focuses on the oxidation of alcohols to aldehydes and ketones. Probably, this is the most important routine operation in Organic Synthesis.
The aim of this book is to help people performing routine operations in Organic Synthesis in a laboratory. This book, the first one in a series, focuses on the oxidation of alcohols to aldehydes and ketones. Probably, this is the most important routine operation in Organic Synthesis.
Marcos I. Fernandez, University of Santiago de Compostela, Spain / Gabriel Tojo, University of Santiago de Compostela, Spain
Inhaltsangabe
Chromium-based Reagents.- Activated Dimethyl Sulfoxide.- Hypervalent Iodine Compounds.- Ruthenium-based Oxidations.- Oxidations Mediated by TEMPO and Related Stable Nitroxide Radicals (Anelli Oxidation).- Oxidations by Hydride Transfer from Metallic Alkoxide.- Fétizon’s Reagent: Silver Carbonate on Celite®.- Selective Oxidations of Allylic and Benzylic Alcohols in the Presence of Saturated Alcohols.- Selective Oxidations of Primary Alcohols in Presence of Secondary Alcohols.- Selective Oxidations of Secondary Alcohols in Presence of Primary Alcohols.
Chromium-based Reagents.- Activated Dimethyl Sulfoxide.- Hypervalent Iodine Compounds.- Ruthenium-based Oxidations.- Oxidations Mediated by TEMPO and Related Stable Nitroxide Radicals (Anelli Oxidation).- Oxidations by Hydride Transfer from Metallic Alkoxide.- Fétizon's Reagent: Silver Carbonate on Celite®.- Selective Oxidations of Allylic and Benzylic Alcohols in the Presence of Saturated Alcohols.- Selective Oxidations of Primary Alcohols in Presence of Secondary Alcohols.- Selective Oxidations of Secondary Alcohols in Presence of Primary Alcohols.
Chromium-based Reagents.- Activated Dimethyl Sulfoxide.- Hypervalent Iodine Compounds.- Ruthenium-based Oxidations.- Oxidations Mediated by TEMPO and Related Stable Nitroxide Radicals (Anelli Oxidation).- Oxidations by Hydride Transfer from Metallic Alkoxide.- Fétizon’s Reagent: Silver Carbonate on Celite®.- Selective Oxidations of Allylic and Benzylic Alcohols in the Presence of Saturated Alcohols.- Selective Oxidations of Primary Alcohols in Presence of Secondary Alcohols.- Selective Oxidations of Secondary Alcohols in Presence of Primary Alcohols.
Chromium-based Reagents.- Activated Dimethyl Sulfoxide.- Hypervalent Iodine Compounds.- Ruthenium-based Oxidations.- Oxidations Mediated by TEMPO and Related Stable Nitroxide Radicals (Anelli Oxidation).- Oxidations by Hydride Transfer from Metallic Alkoxide.- Fétizon's Reagent: Silver Carbonate on Celite®.- Selective Oxidations of Allylic and Benzylic Alcohols in the Presence of Saturated Alcohols.- Selective Oxidations of Primary Alcohols in Presence of Secondary Alcohols.- Selective Oxidations of Secondary Alcohols in Presence of Primary Alcohols.
Rezensionen
From the reviews of the first edition: "'Oxidation of Alcohols to Aldehydes and Ketones' is dedicated to practical, working chemists. It contains reactions that work well, and covers reagents that are known as well as some novel ones. ... The list of reagents covers the range of available options quite well, and most synthetic problems will yield to an answer found in this book. ... The authors' approach has been to write a book that provides many practical tips ... . In this aim, Tojo and Fernandez have most certainly succeeded." (www.organische-chemie.ch, October, 2006)
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