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New Subtrate Classes in Iridium-Catalyzed Asymmetric Hydrogenation (eBook, PDF)

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The main aim of the research presented in this thesis was to expand the substrate scope of the iridium-catalyzed asymmetric hydrogenation, which represents an extremely useful methodology for the enantioselective synthesis of chiral molecules.While this chemistry has been developed and investigated mainly for the hydrogenation of unfunctionalized olefins, so far only little attention has been given to functionalized olefins. Therefore, the different research projects presented in this thesis dealt with the application of iridium catalysts to the reduction of particularly valuable substrates th...

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