Electrochemical Supercapacitors (eBook, PDF)
B. E. Conway
eBook, PDF

Electrochemical Supercapacitors (eBook, PDF)

Scientific Fundamentals and Technological Applications

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The first model for the distribution of ions near the surface of a metal electrode was devised by Helmholtz in 1874. He envisaged two parallel sheets of charges of opposite sign located one on the metal surface and the other on the solution side, a few nanometers away, exactly as in the case of a parallel plate capacitor. The rigidity of such a model was allowed for by Gouy and Chapman inde pendently, by considering that ions in solution are subject to thermal motion so that their distribution from the metal surface turns out diffuse. Stern recognized that ions in solution do not behave as poi...

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