Ab Initio Calculations of Conformational Effects on 13C NMR Spectra of Amorphous Polymers (eBook, PDF)

Ab Initio Calculations of Conformational Effects on 13C NMR Spectra of Amorphous Polymers (eBook, PDF)

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The elucidation of the structure of amorphous systems is one of the most challenging problems of condensed-matter research. Our lack of knowledge about the detailed structure of disordered systems on the molecular level contrasts with the rapidly growing importance of such materials in science and technology. Solid state NMR is of key importance in this area, since it can provide detailed information about internuclear distances and torsional angles in crystals and glasses alike. Common examples of amorphous systems are glassy polymers. There, structural information is encoded in the chemical ...

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