Broschiertes Buch

Vinylcyclopropane Rearrangement

Ring Expansion and Ring Contraction, Cyclopropane

Herausgegeben: Stacy Jerrik, Ben

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The vinylcyclopropane rearrangement or vinylcyclopropane-cyclopentene rearrangement is a ring expansion reaction, converting a vinyl-substituted cyclopropane ring into a cyclopentene ring. The general scope is extended by introducing heteroatoms in any of the 5 framework positions or by replacing the vinyl group by an allene or an alkyne. A closely related reaction is the divinylcyclopropane-cycloheptadiene rearrangement.