Transition Metal-Catalyzed Carbonylative Coupling Reactions
Johannes Schranck
Broschiertes Buch

Transition Metal-Catalyzed Carbonylative Coupling Reactions

Synthesis of Aromatic Carbonyl Compounds

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Novel transition metal-catalyzed carbonylative C C bond-forming reactions have been developed with a focus on the employment of (activated) arenes in combination with simple unfunctionalized carbon nucleophiles in order to prevent stoichiometric amounts of metal waste. This concept is realized in two examples of new palladium-catalyzed carbonylative Heck-type reactions between aryl halides and vinyl ethers or terminal olefins producing 3-alkoxyalkenones or 5-arylfuranones, respectively. Furthermore, three protocols have been developed for the palladium-catalyzed carbonylative coupling of aryl ...