Yingzhao Ma
Broschiertes Buch

The Reduction of Elemental Chalcogens and Their Derivatives by Divalent Lanthanide Complexes

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The main target of this thesis is to gain a deeper understanding of the reduction chemistry of group 16 elements (sulfur, selenium and tellurium) and their derivatives by using divalent lanthanide reagents as reduction agents. Different from cyclopentadienyl counterparts reported by Evans, the employed formidinate lanthanides in this work are supported by a sterically more demanding ligand and the reactivity of these complexes has been discussed by Junk and Deacon and proved by previous work of Roesky et al. The initial target of this project is the reduction of elemental chalcogens by [(DippF...