
Tebbe's Reagent
Organometallic Chemistry, Carbonyl, Pyrophoricity
Herausgegeben: Cletus, Jody
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The Tebbe reagent is the organometallic compound with the formula (C5H5)2TiCH2ClAl(CH3)2. It used in the methylenation of carbonyl compounds, that is it converts organic compounds containing the R2C=O group into the related R2C=CH2 derivative. It is a red solid that is pyrophoric in the air, and thus is typically handled with air-free techniques. Tebbe's reagent contains two tetrahedral centers linked by a pair of bridging ligands. Titanium features two cyclopentadienyl ([C5H5] , or Cp) rings, and aluminium features two methyl ligands. The titanium and aluminium atoms are bridged by both CH2 a...
The Tebbe reagent is the organometallic compound with the formula (C5H5)2TiCH2ClAl(CH3)2. It used in the methylenation of carbonyl compounds, that is it converts organic compounds containing the R2C=O group into the related R2C=CH2 derivative. It is a red solid that is pyrophoric in the air, and thus is typically handled with air-free techniques. Tebbe's reagent contains two tetrahedral centers linked by a pair of bridging ligands. Titanium features two cyclopentadienyl ([C5H5] , or Cp) rings, and aluminium features two methyl ligands. The titanium and aluminium atoms are bridged by both CH2 and chloride ligands.