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Synthesis: Carbon with No Attached Heteroatoms
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Main description:This Volume covers the formation of carbon-carbon single-, double- and triple bonds by substitution and addition reactions as well as by various rearrangements. The formation of carbon-carbon multiple bonds by elimination and condensation procedures is fully documented. In addition the synthesis of carbon-hydrogen bonds principally by substitution and addition reactions is featured as is the preparation of a wide variety of carbon-centred anions, cations and radicals.Table of contents:One or more CH bond(s) by substitution: reduction of C-halogen and C-chalcogenbonds (A.G. Sut...
Main description:
This Volume covers the formation of carbon-carbon single-, double- and triple bonds by substitution and addition reactions as well as by various rearrangements. The formation of carbon-carbon multiple bonds by elimination and condensation procedures is fully documented. In addition the synthesis of carbon-hydrogen bonds principally by substitution and addition reactions is featured as is the preparation of a wide variety of carbon-centred anions, cations and radicals.
Table of contents:
One or more CH bond(s) by substitution: reduction of C-halogen and C-chalcogen
bonds (A.G. Sutherland). One or more CH bond(s) by substitution: reduction of C-nitrogen, -phosphorus, -arsenic, -antimony, -bismuth, -carbon, -silicon, -germanium, -boron and -metal bonds (J. Howarth). Two or more CH bond(s) by addition to C-C multiple bonds (K. Jones). One or more CC bond(s) by substitution: substitution of halogen (G. Edwards). One or more CC bond(s) by substitution: substitution of chalcogen (T.N. Birkinshaw). One or more CC bond(s) by substitution: substitution of C-nitrogen -phosphorus,
-arsenic, -antimony, -bismuth, -carbon, -silicon, -germanium, -boron and -metal functions (P.C.B. Page). One or more CC bond(s) by addition: addition of carbon electrophiles nucleophiles to multiple bonds (A. Armstrong). One or more CC bond(s) by addition: addition of carbon radicals electrocyclic additions to CC multiple bonds (A. Clark, P. Taylor). One or more CH and/or CX bond(s) by rearrangement (I. Coldham). One or more = CH bond(s) by substitution or addition (M. Hayes). One or more =CC bond(s) by substitution or addition (P.G. Steel). One or more C=C bond(s) by addition (A.C. Regan). One or more C=C bond(s) by elimination of hydrogen, carbon, halogen, or oxygen functions (J.M. Percy). One or more C=C bond(s) by elimination of sulphur, selenium, tellurium, nitrogen, phosphorus, arsenic, antimony, bismuth, silicon, germanium, boron or metal functions (A.R. Maguire). One or more C=C Bond(s) by condensation: condensation of non-heteroatom linked functions, halides, chalcogen, or nitrogen functions (C.M. Rayner). One or more C=C bond(s) by condensation: condensation of phosphorus, arsenic, antimony, bismuth, silicon, germanium, boron or metal functions (I. Gosney, D. Lloyd). One or more C=C bond(s) by electrocyclic processes (H. McNab). One or more =CH, =CC and/or C=C bond(s) by rearrangement (P.J. Murphy). Tricoordinate anions, cations and radicals (J.O. Williams, M. Kelly). Allenes and cumulenes (P.H. Dixneuf, C. Bruneau). Acetylenes (M. Furber). Ions, radicals and carbenes and of other monocoordinated systems (J. Dickinson).
This Volume covers the formation of carbon-carbon single-, double- and triple bonds by substitution and addition reactions as well as by various rearrangements. The formation of carbon-carbon multiple bonds by elimination and condensation procedures is fully documented. In addition the synthesis of carbon-hydrogen bonds principally by substitution and addition reactions is featured as is the preparation of a wide variety of carbon-centred anions, cations and radicals.
Table of contents:
One or more CH bond(s) by substitution: reduction of C-halogen and C-chalcogen
bonds (A.G. Sutherland). One or more CH bond(s) by substitution: reduction of C-nitrogen, -phosphorus, -arsenic, -antimony, -bismuth, -carbon, -silicon, -germanium, -boron and -metal bonds (J. Howarth). Two or more CH bond(s) by addition to C-C multiple bonds (K. Jones). One or more CC bond(s) by substitution: substitution of halogen (G. Edwards). One or more CC bond(s) by substitution: substitution of chalcogen (T.N. Birkinshaw). One or more CC bond(s) by substitution: substitution of C-nitrogen -phosphorus,
-arsenic, -antimony, -bismuth, -carbon, -silicon, -germanium, -boron and -metal functions (P.C.B. Page). One or more CC bond(s) by addition: addition of carbon electrophiles nucleophiles to multiple bonds (A. Armstrong). One or more CC bond(s) by addition: addition of carbon radicals electrocyclic additions to CC multiple bonds (A. Clark, P. Taylor). One or more CH and/or CX bond(s) by rearrangement (I. Coldham). One or more = CH bond(s) by substitution or addition (M. Hayes). One or more =CC bond(s) by substitution or addition (P.G. Steel). One or more C=C bond(s) by addition (A.C. Regan). One or more C=C bond(s) by elimination of hydrogen, carbon, halogen, or oxygen functions (J.M. Percy). One or more C=C bond(s) by elimination of sulphur, selenium, tellurium, nitrogen, phosphorus, arsenic, antimony, bismuth, silicon, germanium, boron or metal functions (A.R. Maguire). One or more C=C Bond(s) by condensation: condensation of non-heteroatom linked functions, halides, chalcogen, or nitrogen functions (C.M. Rayner). One or more C=C bond(s) by condensation: condensation of phosphorus, arsenic, antimony, bismuth, silicon, germanium, boron or metal functions (I. Gosney, D. Lloyd). One or more C=C bond(s) by electrocyclic processes (H. McNab). One or more =CH, =CC and/or C=C bond(s) by rearrangement (P.J. Murphy). Tricoordinate anions, cations and radicals (J.O. Williams, M. Kelly). Allenes and cumulenes (P.H. Dixneuf, C. Bruneau). Acetylenes (M. Furber). Ions, radicals and carbenes and of other monocoordinated systems (J. Dickinson).