Surface Science studies of Tartaric Acid on Ni(110): Chiral Footprints
Vincent Humblot
Broschiertes Buch

Surface Science studies of Tartaric Acid on Ni(110): Chiral Footprints

Complexities and dynamics of the enantioselective site in heterogeneous catalysis: Tartaric Acid on Ni(110)

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Enantioselective surface reactions represent the ultimate expression of selectivity in catalysis, involving stereodirecting processes where only one optical component of a product is formed. At present, however, the technique of catalyst modification is imperfect and the knowledge of the surface structure of the solid insufficient. The purpose of this thesis is to provide an understanding of the various phenomena occurring on solid enantioselective catalyst surfaces. For this purpose, model stereodirecting surfaces have been created by the adsorption of the chiral modifier, (R,R)-tartaric acid...