Supramolecular Chemistry
Pounraj Thanasekaran
Broschiertes Buch

Supramolecular Chemistry

Rhenium(I) Metallacyclic Compounds

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Self-assembly of neutral Rhenium(I)-based supramolecules via orthogonal-bonding approach in an one-pot process under solvothermal condition is achieved in high yields. Various types of assemblies can be created based on the nuclearity of the luminophore including bimetallic, trimetallic materials, rectangles, cages and boxes. The structural characteristics of the ligands as well as the metal centers present in the neutral supramolecules allow easy tuning of their emission properties. The neutral supramolecular structures are unique in their well-defined shapes and sizes and would be expected t...