Spin-Transition in FeIIN6 Complexes

Spin-Transition in FeIIN6 Complexes

Effect of Counter-Anions on Spin-Transtion of FeII Complexes

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This book has been organized into four chapters. Introductory Chapter 1 presents a brief description of spin-state transition phenomenon in FeIIN6 complexes, followed by the effect of counter-anions on spin-crossover behavior. Chapter 2 describes the synthesis of three new FeIIN6 complexes with non-planar tridentate ligand (L4) with different counter-anions (CF3SO3-, PF6-, and BPh4-) in order to study the effect of counter-anions on spin-crossover system [FeII(L4)2]2+. Chapter 3 describes the synthesis and detailed characterization of three bis-ligand complexes of iron(II) with a noval non-pla...