Spin Crossover
Ligand Field Theory
Herausgegeben: Koios, Eloi Rylan
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Spin Crossover (SCO), sometimes referred to as spin transition or spin equilibrium behavior, is a phenomenon that occurs in some metal complexes wherein the spin state of the complex changes due to external stimuli such as a variation of temperature, pressure, light irradiation or an influence of a magnetic field. With regards to a ligand field and ligand field theory, the change in spin state is a transition from a low spin (LS) ground state electron configuration to a high spin (HS) ground state electron configuration of the metal s d atomic orbitals (AOs), or vice versa.
