Sodium Amide
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Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. Sodium amide, commonly called sodamide, is the chemical compound with the formula NaNH2. This solid, which is dangerously reactive toward water, is white when pure, but commercial samples are typically gray due to the presence of small quantities of metallic iron from the manufacturing process. Such impurities do not usually affect the utility of the reagent. NaNH2 has been widely employed as a strong base in organic synthesis.Sodium amide can be prepared by the react...
Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. Sodium amide, commonly called sodamide, is the chemical compound with the formula NaNH2. This solid, which is dangerously reactive toward water, is white when pure, but commercial samples are typically gray due to the presence of small quantities of metallic iron from the manufacturing process. Such impurities do not usually affect the utility of the reagent. NaNH2 has been widely employed as a strong base in organic synthesis.Sodium amide can be prepared by the reaction of sodium with ammonia gas, but it is usually prepared by the reaction in liquid ammonia using iron(III) nitrate as a catalyst. The reaction is fastest at the boiling point of the ammonia, ca. -33 °C.
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