Self-Assembled Coatings of Stimuli Responsive Polymeric Materials

Self-Assembled Coatings of Stimuli Responsive Polymeric Materials

Smart Polymer Coatings

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Switchable control of the interfacial properties of a solid surface, such as surface energy, would be of great significance that is responsive to external stimuli of light, pH or salt. A series of novel amphiphilic polymers, functionalized with azobenzene chromophores monomer for optical applications, and acrylic acid monomer for introducing the self assembly character, were synthesized by preparing a 4-[2-(4-nitrophenyl)diazenyl]phenol dye (NDP) to yield 4-[2-(4-nitrophenyl)diazenyl]phenyl ester (NDP monomer). The NDP monomer and acrylic acid monomer (AA) were polymerized by free radical meth...