Pyrite and PHBV Combined as Substrates for Groundwater Denitrification
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Facing the growing threat of nitrate contamination in groundwater, this study presents an innovative approach to in-situ denitrification using a novel combination of pyrite and polyhydroxybutyrate-co-valerate (PHBV) as solid-phase electron donors. By evaluating two mass ratios (1:1 and 1:2) of PHBV to pyrite in lab-scale permeable reactive barrier systems, the research reveals high nitrate removal efficiencies of up to 97.65%, with minimal dissolved organic carbon in the effluent. Microbial analysis indicates that pyrite content significantly influences microbial community structure and functi...
Facing the growing threat of nitrate contamination in groundwater, this study presents an innovative approach to in-situ denitrification using a novel combination of pyrite and polyhydroxybutyrate-co-valerate (PHBV) as solid-phase electron donors. By evaluating two mass ratios (1:1 and 1:2) of PHBV to pyrite in lab-scale permeable reactive barrier systems, the research reveals high nitrate removal efficiencies of up to 97.65%, with minimal dissolved organic carbon in the effluent. Microbial analysis indicates that pyrite content significantly influences microbial community structure and functional gene expression, with the 1:2 ratio favoring aerobic denitrifiers and a broader functional gene profile. The findings highlight a promising, cost-effective mixtrophic denitrification strategy for sustainable groundwater remediation.
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