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Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. Møller Plesset perturbation theory (MP) is one of several quantum chemistry post-Hartree Fock ab initio methods in the field of computational chemistry. It improves on the Hartree Fock method by adding electron correlation effects by means of Rayleigh Schrödinger perturbation theory (RS-PT), usually to second (MP2), third (MP3) or fourth (MP4) order. Its main idea was published as early as 1934 by Christian Møller and Milton S. Plesset.