Metals in Carbohydrate Synthesis
Christopher Albler
Broschiertes Buch

Metals in Carbohydrate Synthesis

Indium and Titanium mediated Chain Elongations of Chiral Pool Building Blocks

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This book describes two different projects associated with the chemical (de novo) synthesis of rare and unnatural carbohydrates from readily available starting materials. After a comprehensive introduction to indium chemistry and stereoselective aldol reactions, two new methodologies are presented which complement the synthetic arsenal available to the carbohydrate chemist. The indium mediated allylation of unprotected carbohydrates was applied in the synthesis of acetamido-heptoses and octoses which are constituents of the aminoglycoside antibiotics Apramycin and Destomycin. Furthermore, a ne...