Zeshan Majeed
Broschiertes Buch

Employing Crystal Engineering Principles to Fabricate Zero to Three-Dimensional 4f-based Metal Aggregates using O-Donor Ligands

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Interest in lanthanide (Ln) coordination chemistry has increased significantly over the past few years, in particular as a result of their intriguing spectral and magnetic properties. LnIII ions are ¿hard acids¿ and generally prefer to coordinate with ¿hard bases¿ such as O- and F-donor ligands. Their coordination geometries are usually determined by ligand steric factors rather than crystal field effects. The research described in this dissertation mainly focuses on the interaction of LnIII ions with O-donor ligands such as carboxylates and polyols, while aiming to synthesize Ln-based pol...