Electronic Structures and Bonding Interaction of Structurally Defined Gold/Silver Superatoms
Shun Ito
Gebundenes Buch

Electronic Structures and Bonding Interaction of Structurally Defined Gold/Silver Superatoms

Probed by Anion Photoelectron Spectroscopy

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This book focuses on ligand-protected gold clusters featuring their atomically precise compositions and unambiguous structures. They mimic electronic shell structures of atoms and are called structurally defined superatoms. The book describes the design principle of superatomic electronic structures and the bonding theory of superatoms as revealed by gas-phase anion photoelectron spectroscopy, which is conducted by using a state-of-the-art home-built apparatus and sheds light on fundamental electronic structures such as density of states and electron affinities otherwise elusive. This study re...